The application discloses a method for recovering
tin from silver separation residue by using
sulfur concentrate, and comprises the following steps: S1, uniformly mixing
copper anode slime silver separation residue, an additive and
sulfur concentrate to form spherical materials; S2,
roasting the spherical materials under a protective
atmosphere at a temperature of 300-800 DEG C to generate soluble
sulfur-
tin compounds, and obtaining
roasting residue; S3,
grinding the
roasting residue into roasting residue
powder, mixing the roasting residue
powder with
alkali metal salt water to carry out
tin leaching reaction in an alkaline environment, and obtaining tin leaching liquid; and S4, mixing the tin leaching liquid, an
oxidizing agent and a
calcium-containing
reagent to carry out tin
precipitation reaction, filtering and
drying, and obtaining tin concentrate. The application has the advantages of low cost.