Electrolyte salt of lithium/thionyl chloride battery and preparation method thereof
A technology of thionyl chloride battery and electrolyte salt, which is applied in the direction of secondary batteries, circuits, electrical components, etc., can solve the problems of low pulse discharge voltage, etc., and achieve the effects of easy-to-obtain raw materials, improve discharge performance, and simple synthesis methods
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[0012] According to the molar ratio of anhydrous lithium chloride:anhydrous gallium trichloride=1:1, weigh 42.4g of lithium chloride and 176.07g of gallium trichloride respectively, put them into a closed container, then put them into an oven, and heat at 200°C 3h, the obtained transparent solution was cooled to room temperature to obtain the synthesized lithium tetrachlorogallate.
[0013] Lithium tetrachlorogallate and thionyl chloride (SOCl 2 ) together to prepare an electrolyte solution, the molar concentration of lithium tetrachlorogallate is 0.5mol / L.
[0014] 1.5M LiAlCl 4 / SOCl 2 Electrolyte and 0.5M LiGaCl 4 / SOCl 2 The electrolyte solution is injected into the square lithium / thionyl chloride battery respectively, the battery is welded and sealed, and then the battery is pulse-discharged, and the battery using the electrolyte salt of lithium tetrachlorogallate: the working voltage of the 0.1C rate constant value discharge is changed from 3.51V Increased to 3.54V,...
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