Multilayer ceramic capacitor
A technology of ceramic capacitors and laminates, applied in the direction of laminate capacitors, capacitors, fixed capacitors, etc., can solve the problems of shortening the life time of the dielectric layer and reducing the reliability of the laminate ceramic capacitor, and achieve excellent life characteristics and bias characteristics. Effect
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Embodiment 1
[0058] In ion-exchanged water with dispersant added, BaCO 3 (specific surface area 30m 2 / g) and TiO 2 (specific surface area 50m 2 / g) was added so that the Ba / Ti molar ratio = 1 to prepare a slurry, which was mixed and dispersed using a bead mill. The above slurry was dried to remove water, and calcined at 935°C to synthesize BaTiO with an average particle diameter of 100 nm obtained from the SEM photograph. 3 .
[0059] Then, compared to BaTiO 3 100mol, as MoO 3 =0.2mol, (Ho 2 o 3 ) / 2=0.5mol, MnCO 3 =0.1mol, SiO 2 Various additives were added at a ratio of =1.0 mol (all are conversion values of each compound), and a solvent was added to prepare a slurry. A PVB binder was added to this slurry, and a green sheet was coated on a PET film in a thickness of 1.0 μm.
[0060] Next, a Ni conductive paste was printed on the green sheet as an internal electrode, and a 1005-shaped multilayer ceramic capacitor with 400 layers was produced using this. After performing bind...
Embodiment 2
[0068] In addition to using MnO 3 =0.1mol (conversion value), (Ho 2 o 3 ) / 2=1.0 mol (converted value), a multilayer ceramic capacitor was produced in the same manner as in Example 1. As a result, the average valency of Mo was 4.20. The result of the high-temperature accelerated life test of the multilayer ceramic capacitor was 120 minutes, and the measurement result of the DC bias characteristic was -50%.
Embodiment 3
[0070] In addition to using (Ho 2 o 3 ) / 2=1.0 mol (converted value), a multilayer ceramic capacitor was produced in the same manner as in Example 1. As a result, the average valence number of Mo was 4.22. The result of the high-temperature accelerated life test of the multilayer ceramic capacitor was 775 minutes, and the measurement result of the DC bias characteristic was -50%.
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