A kind of electrolytic solution and lithium ion battery containing the electrolytic solution
An electrolyte and lithium salt technology, applied in the field of lithium-ion batteries, can solve the problems of poor low-temperature charge-discharge performance, poor cycle life, and difficulty in ensuring low-temperature charge-discharge rate performance of batteries.
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Embodiment 1
[0122] The preparation of embodiment 1 lithium ion battery
[0123] In Comparative Examples 1# to 10# and Examples 1 to 36, lithium-ion batteries (hereinafter referred to as batteries) were prepared according to the following method:
[0124] (1) Preparation of electrolyte
[0125] In an argon atmosphere glove box with a water content <10ppm, ethylene carbonate (EC) and ethyl methyl carbonate (EMC) that have been rectified, dehydrated and purified are mixed in a volume ratio of 30:70, and the fully dried lithium salt Dissolve in the above-mentioned mixed organic solvent, then add additives into the organic solvent, and mix uniformly to obtain an electrolyte solution. Wherein, the concentration of the lithium salt is 1 mol / L.
[0126] (2) Preparation of positive pole piece
[0127] Lithium cobalt oxide (LiCoO 2 ) positive electrode active material, binder (PVDF), and conductive agent (acetylene black) are mixed according to the mass ratio of 98:1:1, N-methylpyrrolidone (NMP...
Embodiment 2
[0160] The electrolyte is prepared by the method in Example 1, the difference is that the formula of the electrolyte is as shown in Table 4; wherein, the lithium salt is 1M LiPF 6 , the content of the additive is the percentage by weight calculated based on the total weight of the electrolyte;
[0161] Table 4: Electrolyte formulation
[0162]
[0163]
[0164] The lithium-ion battery was prepared by using the electrolyte in Table 4, and the properties of the prepared lithium-ion battery were similar to those of Example 1, and will not be repeated due to space limitations.
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