Preparation method of flaky Cu9Fe9S16 nanoflowers

A technology of cu9fe9s16 and nanoflowers, which is applied in the preparation and application of light-to-heat conversion materials, can solve the problems of high temperature in pyrolysis, and achieve the effect of easy availability of raw materials, low price and environmental friendliness

Inactive Publication Date: 2017-03-22
DONGHUA UNIV
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  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

However, the temperature of the pyrolysis method used in the synthesis is relatively h

Method used

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  • Preparation method of flaky Cu9Fe9S16 nanoflowers
  • Preparation method of flaky Cu9Fe9S16 nanoflowers
  • Preparation method of flaky Cu9Fe9S16 nanoflowers

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0033] Take 0.67mmol FeCl 3 ·6H 2 O and 0.33 mmol MnCl 2 4H 2 Disperse O in 10mL of diethylene glycol, stir at 80°C, add 0.4mmol trisodium citrate dihydrate, stir for 1h, add 3mmol sodium acetate, after 30min, transfer to a polytetrafluoroethylene reactor, 200°C Under the reaction 6h. Centrifuged and washed 3 times with deionized water to obtain Fe 2 MnO 4 Nanocrystalline. like figure 1 Shown is the scanning electron microscope image of the sample, the particle size is 200–400nm. figure 2 is the XRD picture of the sample, with Fe 2 MnO 4 (PDFno.10-0319) standard XRD peak one-to-one correspondence, indicating that the prepared sample is Fe 2 MnO 4 .

[0034] Fe obtained by taking 2.5mg 2 MnO 4 Nanocrystals, dispersed in 10mL water, add 10μL (NH 4 ) 2 S solution (22wt%), ultrasonically dispersed for 5min. Centrifuge, wash with deionized water 3 times, and disperse in 10 mL of water.

[0035] Take 2mL CuCl 2 The dispersion liquid (5.425mmol / L) was added to th...

Embodiment 2

[0038] Take 0.67mmol FeCl 3 ·6H 2 O and 0.33 mmol MnCl 2 4H 2 Disperse O in 20mL diethylene glycol, stir at 80°C, add 0.4mmol trisodium citrate dihydrate, stir for 1h, add 3mmol sodium acetate, after 30min, transfer to a polytetrafluoroethylene reactor, 240°C Under the reaction 6h. Centrifuged and washed 3 times with deionized water to obtain Fe 2 MnO 4 Nanocrystalline.

[0039] Fe obtained by taking 2.5mg 2 MnO 4 Nanocrystals, dispersed in 10mL water, add 10μL (NH 4 ) 2 S solution (22wt%), ultrasonically dispersed for 8min. Centrifuge, wash with deionized water 3 times, and disperse in 10 mL of water.

[0040] Take 2mL CuCl 2 The dispersion liquid (5.425mmol / L) was added to the dispersion liquid obtained above, and ultrasonically dispersed for 8min. Centrifuged and washed 3 times with deionized water to obtain flake Cu 9 Fe 9 S 16 nanoflowers.

Embodiment 3

[0042] Take 0.67mmol FeCl 3 ·6H 2 O and 0.33 mmol MnCl 2 4H 2 Disperse O in 10mL of diethylene glycol, stir at 80°C, add 0.4mmol trisodium citrate dihydrate, stir for 1h, add 3mmol sodium acetate, after 30min, transfer to a polytetrafluoroethylene reactor, 200°C Under the reaction 6h. Centrifuged and washed 3 times with deionized water to obtain Fe 2 MnO 4 Nanocrystalline.

[0043] Fe obtained by taking 2.5mg 2 MnO 4 Nanocrystals, dispersed in 10mL water, add 20μL (NH 4 ) 2 S solution (22wt%), ultrasonically dispersed for 10 minutes. Centrifuge, wash with deionized water 3 times, and disperse in 10 mL of water.

[0044] Take 2mL CuCl 2 The dispersion liquid (5.425mmol / L) was added to the dispersion liquid obtained above, and ultrasonically dispersed for 5min. Centrifuged and washed 3 times with deionized water to obtain flake Cu 9 Fe 9 S 16 nanoflowers.

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Abstract

The invention relates to a preparation method of flaky Cu9Fe9S16 nanoflowers. The preparation method includes dispersing a ferric salt and a manganese salt into a solvent with stirring, adding trisodium citrate dihydrate with stirring, adding sodium acetate with mixing uniformly, performing solvothermal reaction for 6-8 hours at 180-240 DEG C prior to centrifuging and washing so as to obtain Fe2MnO4 nanocrystalline; dispersing the Fe2MnO4 nanocrystalline into water, adding a (NH4)2S solution, conducting ultrasonic dispersion and centrifugal washing, and dispersing a product into water so as to obtain dispersion liquid; adding a copper salt solution into the dispersion liquid, and conducting ultrasonic dispersion and centrifugal washing so as to obtain the flaky Cu9Fe9S16 nanoflowers. The preparation method has the advantages of simplicity, safety, environment friendliness, low cost and easiness in operation. The flaky Cu9Fe9S16 nanoflowers are capable of effectively converting near-infrared light into heat and have a nuclear magnetic imaging effect, thereby being quite promising in application prospect for photothermal therapy and diagnosis of cancers.

Description

technical field [0001] The invention belongs to the field of preparation and application of photothermal conversion materials, in particular to a flaky Cu 9 Fe 9 S 16 Preparation method of nanoflowers. Background technique [0002] Photothermal ablation therapy, as an emerging method for the treatment of cancer, has received extensive attention in recent years. It is particularly important to choose a suitable light-to-heat conversion material. At present, there are four main categories of light-to-heat conversion materials: metal-based light-to-heat conversion materials, carbon-based light-to-heat conversion materials, organic compound light-to-heat conversion materials, and semiconductor light-to-heat conversion materials. Semiconductor light-to-heat conversion materials have been greatly developed due to their low price, good stability, high light-to-heat conversion efficiency, and adjustable absorption spectrum. [0003] Especially a class of ternary compounds based...

Claims

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Application Information

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IPC IPC(8): C01G49/12B82Y40/00A61K41/00A61K49/18A61P35/00
CPCA61K41/0052A61K49/18C01G49/12C01P2002/72C01P2002/84C01P2004/03C01P2004/30C01P2004/62
Inventor 胡俊青黄小娟廖丽军邹儒佳关国强张文龙张剑华彭宇璇徐超霆方竹
Owner DONGHUA UNIV
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