Preparation method of positive electrode of lithium-ion secondary battery for electric toothbrush or electric shaver
A technology for electric shavers and electric toothbrushes, applied in the direction of secondary batteries, electrode manufacturing, battery electrodes, etc., can solve the problems of short use time, prolong the use time of lithium batteries, and long storage time, so as to avoid decomposition and reduce auto Discharge phenomenon, the effect of reducing side reactions
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Embodiment 1
[0030] (1) Preparation of LiMPO doped with Ir on the surface of positive active material 4 , M is Co 1 / 3 Ni 1 / 3 mn 1 / 3 , the core of the positive active material is LiMPO 4 , the shell is LiM 1-x wxya 4 , x=0.02,
[0031] Step 1, after preparing cobalt nitrate, nickel nitrate, manganese nitrate and phosphoric acid according to the ratio of 1 / 3:1 / 3:1 / 3:1, add ethylene glycol, put it into a ball mill tank, and use zirconium balls as the ball mill medium Carry out ball milling and mix, ball milling speed is 200r / min, and ball milling time is 4 hours, then alternately wash with deionized water and ethanol, dry, obtain mixture A, with cobalt nitrate, nickel nitrate, manganese nitrate, iridium nitrate and phosphoric acid press (1 / 3-x):1 / 3:1 / 3:x:1 After the ratio is prepared, add ethylene glycol, put it into a ball mill tank, and use zirconium balls as the ball milling medium for ball milling and mixing, and the ball milling speed is 300r / min. The ball milling time was 3 hour...
Embodiment 2
[0040] (1) Preparation of LiMPO doped with Ir on the surface of positive active material 4 , M is Co 1 / 3 Ni1 / 3 mn 1 / 3 , the core of the positive active material is LiMPO 4 , the shell is LiM 1-x wxya 4 , x=0.03,
[0041] Step 1, after preparing cobalt chloride, nickel chloride, manganese chloride and phosphoric acid according to the ratio of 1 / 3:1 / 3:1 / 3:1, add ethylene glycol, put it into a ball mill jar, and use zirconium balls Carry out ball milling mixing for ball milling medium, ball milling speed is 300r / min, ball milling time is 3 hours, then alternately wash with deionized water and ethanol, dry, obtain mixture A, cobalt chloride, nickel chloride, manganese chloride, chlorine After preparing iridium and phosphoric acid according to the ratio of 1 / 3: (1 / 3-x): 1 / 3: x:1, add ethylene glycol, put it into a ball mill jar, and use zirconium balls as the ball milling medium for ball milling and mixing. The ball milling speed was 350r / min, and the ball milling time was 2 ...
Embodiment 3
[0050] (1) Preparation of LiMPO doped with Ir on the surface of positive active material 4 , M is Co 1 / 3 Ni 1 / 3 mn 1 / 3 , the core of the positive active material is LiMPO 4 , the shell is LiM 1-x wxya 4 , x=0.04,
[0051] Step 1, after preparing cobalt chloride, nickel chloride, manganese chloride and phosphoric acid according to the ratio of 1 / 3:1 / 3:1 / 3:1, add ethylene glycol, put it into a ball mill jar, and use zirconium balls Carry out ball milling mixing for ball milling medium, ball milling speed is 300r / min, ball milling time is 3 hours, then alternately wash with deionized water and ethanol, dry, obtain mixture A, cobalt chloride, nickel chloride, manganese chloride, chlorine After preparing iridium and phosphoric acid according to the ratio of 1 / 3: 1 / 3: (1 / 3-x): x: 1, add ethylene glycol, put it into a ball mill jar, and use zirconium balls as the ball milling medium for ball milling and mixing. The ball milling speed was 350r / min, and the ball milling time was...
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