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Adhesive, bonded body and method for producing bonded body

An adhesive and bonding technology, applied in the direction of bonding methods, adhesives, adhesive types, etc., can solve the problems of difficult evaporation of adhesive moisture, time required for curing, low bonding strength, etc., to achieve bonding strength Excellent, excellent curing speed, high bonding strength effect

Active Publication Date: 2021-01-08
KURARAY CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, these films have low moisture permeability, so when using the above-mentioned adhesives containing aqueous solvents, etc., there are disadvantages: the moisture in the adhesives is difficult to evaporate, the curing of the adhesives takes time, and after curing, The adhesive strength is also low
[0005] For the above disadvantages, active energy ray-curable compositions such as ultraviolet rays containing urethane (meth)acrylates obtained from polyisocyanate compounds and hydroxyl-containing (meth)acrylate compounds have been developed (for example, refer to International Publication No. 2010 / 123082, etc.), but there is room for improvement in terms of bonding strength

Method used

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  • Adhesive, bonded body and method for producing bonded body
  • Adhesive, bonded body and method for producing bonded body
  • Adhesive, bonded body and method for producing bonded body

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0371]

[0372] 14 parts by mass of the above-mentioned (meth)acrylic polymer (P-1), 43 parts by mass of (M-1) as the compound (Y), and 33 parts by mass of (M-2) were put into a container that can be sealed and equipped with a stirring device. parts by mass and 5 parts by mass of (L-1), 3 parts by mass of (R-1) as a radical polymerization initiator (R), and 2 parts by mass of (C-1) as a cationic polymerization initiator (C), and stirred for 24 hours to prepare the adhesive (A-1).

[0373]

[0374] A polymethyl methacrylate film (manufactured by Kuraray Co., Ltd.) with a thickness of 50 μm was used as the substrate, and the above-mentioned adhesive was applied to one surface of the polymethyl methacrylate film to a thickness of 2 μm using a bar coater. agent (A-1). Next, a polarizing film (manufactured by dyeing and stretching a PVA film with an iodine-based dye) with a thickness of 10 μm was laminated on the base material through the adhesive. Thereafter, the above-menti...

Embodiment 2~6

[0386] [Examples 2 to 6 and Comparative Examples 1 to 4]

[0387] Except for using the types and amounts of the compounds shown in the following Table 1, the same operations as in Example 1 were performed to prepare adhesives (A-2)~(A-6) and (CA-1)~(CA- 4). In the adhesive (A-6), an acrylic resin acrylate (“KRAD-3611” manufactured by Negami Industry Co., Ltd.) (P-2) was used instead of the (meth)acrylic polymer (P-1). In addition, in adhesives (CA-1) and (CA-2), polyether-based urethane acrylate ("Upimar AU-2300" manufactured by Mitsubishi Chemical Corporation) (P-3) was used instead of ( Meth)acrylic polymer (P-1). It should be noted that "-" in Table 1 indicates that the compound was not used.

[0388] In addition, it carried out similarly to Example 1 except having used adhesive agent (A-2)-(A-6) and (CA-1)-(CA-4) instead of adhesive agent (A-1) respectively The bonded body (polarizing plate) was produced, and the same evaluations as in Example 1 were performed. These ...

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Abstract

An object of the present invention is to provide an adhesive capable of obtaining a bonded body having high adhesive strength, excellent curing speed, and reduced warpage in bonding a film containing polyvinyl alcohol to a substrate. The present invention is an adhesive for bonding a film containing polyvinyl alcohol to a substrate, comprising: a (meth)acrylic polymer (X) having an active energy ray-curable group; and ( A compound (Y) having an active energy ray-curable group other than the meth)acrylic polymer (X). In addition, another present invention is an adhesive for bonding a film containing polyvinyl alcohol to a substrate, comprising: a polymer (X') having an active energy ray-curable group; and For the compound (Y') having an active energy ray-curable group other than (X'), the crosslink density obtained from the storage elastic modulus of the rubber-like flat region obtained by measuring the dynamic viscoelasticity after curing is More than 0.4mol / L and less than 2mol / L.

Description

technical field [0001] The present invention relates to an adhesive, an adherend and a method for producing the adherend. Background technique [0002] Films containing polyvinyl alcohol (hereinafter sometimes referred to as "PVA films") are excellent in moisture permeability, heat retention, and the like, and are used in various fields such as food packaging fields, agricultural fields, and medical fields. In particular, stretched PVA films are reused as optical films such as polarizing films and retardation films. [0003] The said polarizing film is normally affixed with the protective film on the one side or both sides via the adhesive agent etc. which contain an aqueous solvent. As the protective film, for example, a transparent film such as a triacetyl cellulose (TAC) film having high moisture permeability is used. [0004] In recent years, in order to improve the strength and durability of the above-mentioned protective film, it has been proposed to use (meth)acryli...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C09J4/02B32B27/00B32B27/30C09J5/00C09J11/06C09J133/04C09J133/14C09J153/00G02B5/30
CPCB32B27/00B32B27/30C09J5/00C09J11/06C09J133/04C09J133/14C09J153/00G02B5/30B32B27/306B32B27/08B32B7/12C09J2301/312
Inventor 内野真由美风藤修前川一彦久保敬次井田大嗣清水星哉
Owner KURARAY CO LTD