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A polymer dispersed bistable smectic a-phase liquid crystal film and preparation method thereof

A liquid crystal film, bistable technology, used in liquid crystal materials, chemical instruments and methods, instruments, etc.

Active Publication Date: 2019-10-22
PEKING UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

At present, there is no SmA phase liquid crystal material with bistable properties dispersed in a polymer matrix to make a bistable PDLC film material in the market.

Method used

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  • A polymer dispersed bistable smectic a-phase liquid crystal film and preparation method thereof
  • A polymer dispersed bistable smectic a-phase liquid crystal film and preparation method thereof
  • A polymer dispersed bistable smectic a-phase liquid crystal film and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0035] Prepare samples according to the sample proportions in Table 1, heat them in an oven at 80°C until clear, take them out and mix them evenly, drop them between two indium tin oxide-coated films, and roll them to form a 40 μm film. The intensity of ultraviolet light (365nm) is 3.0mW / cm 2 Irradiate under light intensity for 10 minutes at a temperature of 30°C. The obtained samples were tested for electro-optic properties. The test method was to test the light transmittance of the samples at a wavelength of 632 nm by using an ultraviolet-visible-near-infrared spectrophotometer, and the reference was an empty liquid crystal cell. The method of testing the transmittance in the transmission state is to apply a voltage of 5KHz, 20V to 160V in sequence with a step size of 20V. After each test, a voltage of 0.01Hz and 160V needs to be applied to restore it to the scattering state; the method of testing the transmittance in the scattering state For, 0.01Hz, 20V to 160V voltage is...

Embodiment 2

[0039]Prepare samples according to the sample proportions in Table 2, heat them in an oven at 80°C until clear, take them out and mix them evenly, drop them between two films coated with indium tin oxide, and roll them to form a film of 20 μm. The intensity of ultraviolet light (365nm) is 20mW / cm 2 Irradiate under light intensity for 1 minute, and the temperature is 100°C. The obtained samples were tested for electro-optic properties. The test method was to test the light transmittance of the samples at a wavelength of 632 nm by using an ultraviolet-visible-near-infrared spectrophotometer, and the reference was an empty liquid crystal cell. The method of testing the transmittance in the transmission state is to apply a voltage of 5KHz, 20V to 160V in sequence with a step size of 20V. After each test, a voltage of 0.01Hz and 160V needs to be applied to restore it to the scattering state; the method of testing the transmittance in the scattering state For, 0.01Hz, 20V to 160V v...

Embodiment 3

[0044] Prepare samples according to the sample proportions in Table 3, heat them in an oven at 80°C until they are clear, take them out and mix them evenly, drop them between two films coated with indium tin oxide, and roll them to form a film of 0.5 μm. The intensity of ultraviolet light (365nm) is 1mW / cm 2 Irradiate for 30 minutes under light intensity, and the temperature is 0°C. The obtained samples were tested for electro-optic properties. The test method was to test the light transmittance of the samples at a wavelength of 632 nm by using an ultraviolet-visible-near-infrared spectrophotometer, and the reference was an empty liquid crystal cell. The method of testing the transmittance in the transmission state is to apply a voltage of 5KHz, 20V to 160V in sequence with a step size of 20V. After each test, a voltage of 0.01Hz and 160V needs to be applied to restore it to the scattering state; the method of testing the transmittance in the scattering state In order to appl...

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Abstract

The invention discloses a polymer-dispersion bi-stable-smectic-A-phase-liquid-crystal film and a preparing method thereof. The preparing method includes the following steps that an ultraviolet light polymerizable monomer, a mectic A-phase liquid crystal with positive dielectric anisotropy, ionic liquid, a photoinitiator and glass beads are mixed to be even in proportion, the mixture is put between two films plated with tin indium oxide and prepared into the film, ultraviolet light irradiation polymerization is carried out, and the polymer-dispersion bi-stable-smectic-A-phase-liquid-crystal film is obtained. The film prepared with the method has the advantages of being excellent in stability, simple in response mode and high in contrast ratio at the same time, is a good energy-saving and environmental-friendly material, and has broad application prospects in the building aspect, the automobile door and window aspect and the flexible electronic paper aspect.

Description

technical field [0001] The invention belongs to the technical field of liquid crystal applications. Specifically, the invention provides a polymer-dispersed bistable smectic A-phase liquid crystal film and a preparation method thereof. The prepared film material can be widely used in the fields of building film and the like. Background technique [0002] Polymer dispersed liquid crystal (PDLC) material is a composite material of polymer and liquid crystal, which can realize multiple functions and has high application value. The current PDLC thin film materials on the market generally have two states, the scattering state and the transmission state. Of these two states, one is usually the normal state, that is, the state that does not need to be powered on, and the other is the energized state, that is, Need to continue to power on to maintain. Usually, when a positive liquid crystal PDLC film is applied with a voltage, the liquid crystal droplets dispersed in the polymer ma...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): G02F1/1334C09K19/54
Inventor 杨槐郭姝萌张兰英张翠红胡威
Owner PEKING UNIV