Preparation method of novel nano carbon material and electrocatalytic hydrogen production application of novel nano carbon material

A nano-carbon material and electrocatalysis technology, applied in chemical instruments and methods, catalyst activation/preparation, physical/chemical process catalysts, etc., can solve the problems of difficult industrialization, low platinum abundance, high price, etc., and reach the range of raw materials The effect of wide, fast response and simple method

Inactive Publication Date: 2017-05-31
CHINA UNIV OF PETROLEUM (EAST CHINA)
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Problems solved by technology

At present, the electrodes used in production are mainly platinum-carbon materials, but because platinum is a precious

Method used

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  • Preparation method of novel nano carbon material and electrocatalytic hydrogen production application of novel nano carbon material
  • Preparation method of novel nano carbon material and electrocatalytic hydrogen production application of novel nano carbon material
  • Preparation method of novel nano carbon material and electrocatalytic hydrogen production application of novel nano carbon material

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Embodiment Construction

[0044] The technical characteristics of the present invention will be described below in conjunction with specific experimental schemes and accompanying drawings, but the present invention is not limited thereto. The test methods described in the following examples, unless otherwise specified, are conventional methods; the instruments and materials, unless otherwise specified, can be obtained from commercial sources.

[0045] The preparation method of the novel nano-carbon material mentioned in the present invention comprises the following steps:

[0046] A. Zeolite imidazole framework material Ni x co 1-x -ZIFs were synthesized as follows: 1.3686 g of 2-methylimidazole and 1.6868 g of triethylamine were dissolved in 15 ml of ice-water mixture, 0.4152 g of cobalt acetate and nickel acetate were dissolved in 15 ml of ice-water mixture in an ice-water mixing bath , the two solutions were stirred on a magnetic stirrer at 800 r / min for 30 min, and then the two solutions were mix...

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Abstract

The invention relates to a preparation method of a novel nano carbon material and an electrocatalytic hydrogen production application of the novel nano carbon material. The preparation method comprises the following steps that (1), a second or multiple metal synthesized bimetal or multiple metal base ZIFs material is introduced into a monometal ZIFs skeleton structure at a special temperature; (2), the ZIFs material is carbonized in an inert atmosphere at a temperature higher than a decomposition temperature of an organic ligand of the ZIFs material to obtain a carbon material; (3), the carbon material is modified on the surface of an electrode and linear sweep voltammetry response is performed in an electrolyte solution with certain PH (potential of hydrogen) and certain concentration; (4), alternating current impedance is performed in the electrolyte solution with the certain PH and the certain concentration; (5), cyclic voltammetry response is performed in an alkaline solution and then linear sweep voltammetry response is measured. The preparation method has the benefits that a raw metal salt material is wide in range, so that the cost is saved and industrial production and preparation is facilitated; the method has important significances and wide application prospects in the aspect of the prepared nano carbon material, in an application extending the ZIFs material and in the field of electrocatalysis.

Description

technical field [0001] The invention relates to the preparation and application of a carbon nanometer material, in particular to a preparation method of a novel nanometer carbon material and its electrocatalytic hydrogen production application. Background technique [0002] Since the 20th century, the global human society has developed at an alarming rate. With the increase of population and the improvement of people's living standards, human demand for energy is also increasing. People's heavy dependence on traditional non-renewable fossil energy has led to serious environmental pollution problems facing the development of today's society. Therefore, research and exploration of various clean and renewable energy sources have attracted more and more attention from countries all over the world. As a secondary energy source, hydrogen energy not only has the advantages of being clean, non-polluting, efficient, storable, easy to transport, and rich in resources, but also the com...

Claims

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Application Information

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IPC IPC(8): B01J23/755B01J35/02B01J37/08C25B1/04C25B11/06B22F1/02
CPCC25B1/04B01J23/755B01J35/0033B01J35/023B01J37/086C25B11/051C25B11/091B22F1/16Y02E60/36
Inventor 郭海玲努尔古丽·尤力瓦斯赵蕾刘俊娟焦丰刘晨光
Owner CHINA UNIV OF PETROLEUM (EAST CHINA)
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