High-damp-heat-resistant marine atmosphere high-strength weathering resistant steel

A marine atmosphere, high-strength technology, applied in the field of weathering steel, can solve problems such as peeling off of corrosion products, thinning of steel surface, and inability to form a stable rust layer

Inactive Publication Date: 2017-05-31
CENT IRON & STEEL RES INST
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Under some severe corrosive environmental conditions, such as the climate environment of three highs and one strong "high temperature, high humidity, high salt spray, and strong sunshine" in the South China Sea, due to Cl - The strong penetration of the corrosion product causes

Method used

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  • High-damp-heat-resistant marine atmosphere high-strength weathering resistant steel
  • High-damp-heat-resistant marine atmosphere high-strength weathering resistant steel
  • High-damp-heat-resistant marine atmosphere high-strength weathering resistant steel

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0036] Example 1 Effects of different Ni contents on the high humidity and heat marine atmospheric corrosion resistance of weathering steel

[0037] Ni is one of the most effective corrosion-resistant elements, but due to the high cost of Ni, it is of great significance to select an appropriate Ni content to obtain weathering steel with good comprehensive performance and reasonable cost. Based on the composition of traditional weathering steel Q450NQR1 (0#), only the Ni content is changed to obtain weathering steels with different Ni contents. Then 5 kinds of Ni-containing weathering steels (respectively numbered 1#~5#) with Ni content in the range of 1% to 5% were smelted in a 25kg vacuum induction furnace. The chemical composition is shown in Table 2. According to the periodic infiltration corrosion test method of weathering steel for railways (TB / T2375-93) and the corrosion test method of steel bars in a chloride ion environment (YB / T4367-2014), the test parameters are set ...

Embodiment 2

[0040] Example 2 The actual exposure test of weathering steel with different Ni content in Xisha, South China Sea

[0041] The test steel was the same as that in Example 1, and the actual exposure test was carried out in Xisha, South China Sea for 2 years, and the exposure time period was from October 2014 to October 2016. figure 2 It is the macroscopic corrosion photo of the test steel actually exposed to the sun.

[0042] Table 3 embodiment 1 and 2 corrosion test results

[0043]

[0044] Table 3 is the corrosion rate and relative corrosion rate data of Examples 1 and 2. From the two test conditions, it can be seen that the increase of Ni helps to improve the corrosion resistance of the test steel to high humidity and heat, marine atmosphere. When the Ni content exceeds 3%, the corrosion rate has a significant downward trend, which is 40% lower than that of the traditional Q450NQR1 weathering steel. , It is more than 50% lower than that of Q345 carbon steel, and the co...

Embodiment 3

[0046] On the basis of Examples 1 and 2, select 3# test steel and add microalloying elements Mo, Sn, Sb and RE to obtain the steel of the present invention. The steel of the present invention and the comparison steel Q345 carbon steel and Q450NQR1 traditional weathering steel were subjected to laboratory periodic infiltration corrosion test. The test condition parameters were the same as those in Example 1, and the test cycle nodes were set to 24h, 48h, 72h, and 96h. Table 4 is the chemical composition of the inventive steel in this example, and Table 5 is the results of the corrosion test data. Table 6 is the test results of the mechanical properties of the steel of the present invention.

[0047] Chemical composition (wt%) of steel of the present invention of table 4

[0048]

[0049] The corrosion test data of table 5 steel of the present invention and contrast steel

[0050]

[0051] The mechanical performance test result of table 6 steel of the present invention ...

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Abstract

The invention provides high-damp-heat-resistant marine atmosphere high-strength weathering-resistant steel and belongs to the technical field of weathering-resistant steel. The weathering resistant steel comprises chemical ingredients of, in percentage by weight, 0.01-0.03 wt% of C, 0.30-0.50 wt% of Si, less than or equal to 0.01 wt% of P, less than or equal to 0.007 wt% of S, 0.30-0.50 wt% of Mn, 0.80-1.00 wt% of Cu, 2.90-3.10 wt% of Ni, 0.10-0.30 wt% of Mo, 0.20-0.30 wt% of Sn, 0.05-0.10 wt% of Sb, 0.40-0.60 wt% of Cr, less than or equal to 0.02 wt% of Nb, 0.01-0.03% of RE and the balance Fe and other inevitable impurity elements. Ultra-low carbon is adopted for ingredient design, the Sn, Sb and RE corrosion-inhibition alloy elements are added on the basis of a Cu-Ni-Cr-Mo alloy system in a compounded manner, and a great number of thin and small needle-shaped ferrite tissues are obtained supplemented by the microalloyed element Nb. The high-damp-heat-resistant marine atmosphere high-strength weathering resistant steel has the advantages that the steel has excellent weathering resistance and is particularly resistant to the high-damp-heat-resistant marine atmosphere environment, and corrosion resistance of the steel is increased by about three times that of plain carbon steel Q345 and is increased by about two times that of traditional weathering resistant steel Q450NQR1; and meanwhile, the steel has strength of 700 MPa level, the yield strength ratio is less than or equal to 0.80, and the extension rate is larger than or equal to 15%.

Description

technical field [0001] The invention belongs to the technical field of weather-resistant steel, and in particular relates to a high-strength weather-resistant steel resistant to high humidity and heat. Marine Atmospheric Environmental Performance. Background technique [0002] Weathering steel has a history of more than 80 years from its birth to the present. The original weathering steel only added Cu elements to plain carbon steel. American scholar Buck published the results of the exposure test on the atmosphere in 1913, clarifying that the atmosphere contains Cu. Corrosion resistance of steel. Inspired by the initial report of the United States, Germany matched test steels with different Cu and P contents to carry out exposure tests in rural atmosphere, industrial atmosphere and North Sea coastal atmosphere. The results show that the coexistence of Cu and P in industrial areas has obvious effects. In 1928, the Corrosion Committee of the British Iron and Steel Associati...

Claims

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Application Information

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IPC IPC(8): C22C38/42C22C38/02C22C38/04C22C38/44C22C38/48C22C38/60
CPCC22C38/42C21D2211/005C22C38/002C22C38/005C22C38/008C22C38/02C22C38/04C22C38/44C22C38/48C22C38/60
Inventor 黄涛刘清友陈小平汪兵贾书君
Owner CENT IRON & STEEL RES INST
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