496 results about "Weathering steel" patented technology

The invention discloses a method for improving the performance of 700 MPa grade V-N microalloyed high strength weathering steel. The method is specific to the characteristics of the sheet billet continuous casting and tandem rolling technology and metallurgy component, and adopts an electric furnace or a revolving furnace to smelt, refine, continuously cast sheet billet which directly enters into a roller hearth to heat after a casting blank concretes, or soaking furnace, hot rolling, laminar flow cooling and wind-up process flow. The chemical composition of molten steel is :C occupies less than or equal to 0.08Wt. percent, Si occupies from 0.25 to 0.75Wt. percent, Mn occupies from 0.2 to 2.0Wt.percent, P occupies less than or equal to 0.025Wt. percent, S occupies less than or equal to 0.040Wt. percent, Cu occupies from 0.25 to 0.60Wt. percent, Cr occupies from 0.30 to 1.25 Wt.percent, Ni occupies less than or equal to 0.65Wt. percent, V occupies from 0.02 to 0.20Wt. percent and N occupies from 0.015 to 0.030 Wt. percent. The invention takes full advantages of the characteristics of the sheet billet continuous casting and tandem rolling short flow process and adopts the V-N microalloyed technique to produce 700 MPa grade high strength weathering steel under the thinning function of VN and V (C, N) nanometer scale precipitate on crystal grain in casting blank of the sheet billet continuous casting and tandem rolling flow and the theory of precipitation strength. By the optimization design of the metallurgy component of V-N microalloyed 700MPa grade high strength weathering steel, the invention increases the low temperature impact ductility of coil of strip and improves the shaping property.

The invention relates to weathering steel with the yield strength of 550MPa level and the advantages of excellent toughness and high corrosion resistance, and a manufacturing method thereof. The weathering steel comprises the following components: 0.02 to 0.08wt% of C, 0.15 to 0.55wt% of Si, 0.2 to 1.0wt% of Mn, less than or equal to 0.01wt% of P, less than or equal to 0.006wt% of S, 0.2 to 0.5wt% of Cu, 2.5 to 7.0wt% of Cr, 0.2 to 1.2wt% of Ni, 0.02 to 0.06wt% of Nb, 0.01 to 0.05wt% of Al, less than or equal to 0.05wt% of N, 0.01 to 0.10wt% of Ti and the balance of Fe and the unavoidable impurities. The steel plate made of the steel has the yield strength more than 550MPa and excellent toughness, and the relative corrosion rate is simultaneously reduced by one time on the basis of the traditional weathering steel so as to satisfy the requirement of enhancing the corrosion resistance of the steel for railway vehicles and reach the purposes of prolonging the service duration and reducing the maintenance cost.

The invention discloses a high-strength weatherabile steel and manufacturing method in the low-alloy steel making domain, which is characterized by the following: adding low-carbon and Cu-Cr-Ni-Mo-Nb into two or more composite additives; controlling carbon content with maximum solubility in the alpha-Fe at 0.0218% under normal temperature; reducing carbon-permeating evolution; affirming main control tissue evenly.

The invention relates to high-strength weathering steel and a method for producing same. The high-strength weathering steel comprises the following components by weight percent (wt%): 0.001-0.004 percent of C, 0.10-0.30 percent of Si, 0.40-0.70 percent of Mn, 0.020 percent of P or less, 0.008 percent of S or less, 2.50-3.50 percent of Cr, 0.20-0.40 percent of Ni, 0.25-0.50 percent of Cu, 0.01-0.03 percent of Re, 0.02-0.06 percent of Al, 0.001-0.004 percent of Ca, 0.001-0.005 percent of N, 0.01-0.03 percent of Ti, 0.01-0.03 percent of Nb and the balance of Fe and other inevitable impurities. After the molten iron is fully deoxidized and before the refining of the molten iron is finished, ferrotitanium is added to steel ladle, a Ca wire is fed to the steel ladle, a Re wire is fed into a continuous casting crystallizer, and a slab is reheated at 1180-1300 DEG C; the two-stage controlled rolling is adopted; the ratio of the thickness of the intermediate slab to the thickness of the finished product is controlled at 3.0; the refining outlet temperature is controlled at 890-1050 DEG C; the finishing rolling temperature is controlled at 800-860 DEG C; the rate of cooling after finishing rolling is controlled at 10-15 DEG C per second; and the winding temperature is controlled at 580-640 DEG C. The invention has the advantages that the relative corrosion rate of the weathering steel subjected to the 72h periodic infiltration is less than 30 percent compared with that of the steel Q345B, the weathering performance of the weathering steel is obviously better than the traditional high-strength weathering steel, and the weathering steel of the invention has the yielding strength of more than 550 Mpa and the elongation rate of more than 24 percent. The high-strength weathering steel of the invention can be applied to the fields of the railway truck, the container, the bridge, the communication, the power tower and the like.

The invention provides high-strength weathering resistant steel and its preparation method. The high-strength weathering resistant steel is characterized by comprising the following chemical components: by weight, C being less than or equals to 0.06% and greater than or equals to 0.05%, Cu being less than or equals to 0.35% and greater than or equals to 0.25%, Si being less than or equals to 0.45% and greater than or equals to 0.36%, Mn being less than or equals to 1.00% and greater than or equals to 0.80%, Al being less than or equals to 0.065% and greater than or equals to 0.055%, Ni being less than or equals to 0.19% and greater than or equals to 0.10%, Cr being less than or equals to 0.50% and greater than or equals to 0.41%, Mo being less than or equals to 0.15% and greater than or equals to 0.05%, Ti being less than or equals to 0.02% and greater than or equals to 0.01%, V being less than or equals to 0.030% and greater than or equals to 0.016%, Nb being less than or equals to 0.010% and greater than or equals to 0.005%, B being less than or equals to 0.008% and greater than or equals to 0.005%, S being less than or equals to 0.010%, P being less than or equals to 0.025%, N being less than or equals to 0.005%, and the balance being Fe. According to the invention, a plurality of microalloy elements such as Al, Mo, V, Nb, B and the like are added into components of traditional weathering resistant steel so as to carry out combination alloying. Thus, contents of Cu and P in weathering resistant steel are reduced, copper brittleness and phosphorus brittleness hazards caused by Cu and P in weathering resistant steel are eliminated, and strength and weatherability of the steel are raised.

The invention provides low-cost non-quenched and tempered high-strength weathering steel with yield strength level of 700MPa for containers and a manufacturing method thereof. Based on the carbon manganese structural steel composition, the reinforcement effect is enhanced by adding a proper amount of micro-alloy elements such as Nb, Ti, Cu, Cr, Ni and the like, adopting a controlled rolling and controlled cooling technique, taking production characteristics of a normal hot continuous rolling machine into consideration and using a high-Ti component design. Meanwhile, Si content is reduced and high cold forming performance is ensured. The weathering steel for the containers comprises the following components in percentage by weight: 0.05 to 0.10 percent of C, less than or equal to 0.15 percent of Si, 1.5 to 2.0 percent of Mn, less than or equal to 0.015 percent of P, less than or equal to 0.01 percent of S, 0.3 to 0.8 percent o Cr, 0.2 to 0.4 percent of Cu, 0.15 to 0.4 percent of Ni, 0.09 to 0.15 percent of Ti, 0.02 to 0.08 percent of Nb, less than or equal to 0.005 percent of N, less than or equal to 0.002 percent of O and the balance of Fe and inevitable impurities. The yield strength is over 700MPa, the tensile strength is over 800MPa and the elongation is over 18 percent.

A conticasting and tandem rolling technology for manufacturing the high-strength and-weatherability Ti-microalloyed steel plate includes such steps as smelting, refining, conticasting, solidifying, heating, hot rolling, laminar flow cooling and coiling. Its advantages are high strength, high shaping performance, high weatherability and high weldability.

The invention discloses weathering steel, which comprises the following chemical compositions in percentage by weight: 0.06 to 0.12 percent of C, 0.20 to 0.40 percent of Si, less than or equal to 1.6 percent of Mn, 0.08 to 0.22 percent of P, less than or equal to 0.008 percent of S, 0.01 to 0.06 percent of Al, 0.20 to 0.80 percent of Cu, 0.40 to 0.75 percent of Cr, 0.12 to 0.40 percent of Ni, 0.001 to 0.006 percent of Ca and the balance of iron and inevitable impurity elements. The weathering steel is manufactured by a thin strip continuous casting process. The manufacturing process comprises the following steps of: performing deep desulfurization on molten steel, performing composite blowing on the top and bottom of a converter, performing RH vacuum circular degassing process, and simultaneously performing calcium treatment; performing twin-roll continuous casting, and making the temperature of the molten steel in a molten bath not lower than 1,535DEG C; controlling rolling in the reduction ratio of not less than 30 percent; controlling cooling at the speed 30 to 50 DEG C/s; and coiling at the temperature of between 600 and 650 DEG C. The weathering steel of which the texture is acicular ferrite has good weatherability and can be widely applied to structural materials.

The invention relates to a hydrojet pretreatment method for accelerating the stabilization of a rust layer on the surface of weathering resistant steel, belonging to the technical field of steel material corrosion prevention. 0.1-3 percent by weight of NaCl, 0.3-3 percent by weight of FeSO4, 0.1-3 percent by weight of CuSO4 and 0.3-3 percent by weight of NaHSO3 are mixed with water uniformly to obtain a surface treating agent of the weathering resistant steel, wherein the surface treating agent is sprayed on the surface of the weathering resistance steel. Chemical materials in a solution react with a steel base to generate a uniform and compact protective rust layer, so that the weathering resistant steel is more attractive in a use process, and rust liquid loss is prevented and the environment can be protected from being polluted. The hydrojet pretreatment method is convenient to operate and short in period, and can be widely applied to weathering resistant steel engineering structures of bridges, buildings and traffics.

The invention provides ultra-low carbon hot rolling weathering steel whose yield strength is more than 450MPa aiming at the defects of existing weathering steel that the mechanical property and the atmospheric corrosion resistance are bad and the C content is over high, which is composed of components with following weight percent: C 0.01-0.05%, Si 0.10-0.40%, Mn 1.50-1.90%, P<=0.02%, S<=0.010%, Cu 0.15-0.55%, Cr 0.20-0.80%, Ni 0.10-0.50%, Mo 0.05-0.50, Nb 0.01-0.05% and Ca 0.0010-0.0020, and allowance is Fe and unavoidable impurity. The strength grade of the steel of the invention is higher than that of traditional steel and the steel has excellent low temperature impact toughness, welding performance and atmospheric corrosion resistance, and adopts ultra-low carbon design, which is beneficial for extending and applying.

The invention discloses a high-toughness weather-resistant steel plate with the yield strength of 550MPa and a preparation method of the high-toughness weather-resistant steel plate. The high-toughness weather-resistant steel plate is prepared from the following chemical components by weight percent: 0.05 to 0.10 percent of C, 0.10 to 0.40 percent of Si, 1.20 to 1.70 percent of Mn, less than or equal to 0.012 percent of P, less than or equal to 0.008 percent of S, 0.40 to 0.80 percent of Cr, 0.15 to 0.40 percent of Ni, 0.25 to 0.40 percent of Cu, 0.015 to 0.040 percent of Als, 0.030 to 0.070 percent of Nb, and 0.010 to 0.040 percent of Ti, and the balance of Fe and unavoidable impurities, wherein Pcm is equal to C+Si/30+(Mn+Cu+Cr)/20+Mo/15+Ni/60+V/10+5B and less than or equal to 0.20 percent. The microscopic tissue of the weather-resistant steel plate obtained according to the method disclosed in the invention is composite-phase tissue of ferrite, granular bainite and little pearlite,the ReL is 560 to 650MPa, Rm is 680 to 780MPa, A is 22.0 to 26.0 percent, and the longitudinal Charpy V-type impact power KV2 is greater than 70J at the temperature of -40 DEG C, and the high-toughness weather-resistant steel plate has excellent welding performance, cold bending forming performance and atmospheric corrosion resistance.

The invention discloses a 600MPa high strength weathering steel and the manufacturing method, which is characterized in that: the 600MPa high strength weathering steel adopts electric stove-thin slab continuous casting and rolling process for preparation; the main chemical components of the refined molten steel for preparing the high strength weathering steel are: C: 0.045 wt % to 0.07wt%, Si: 0.10 wt % to 0.29wt%, Mn: 0.8 wt % to 1.5wt%, P: 0.005 wt% to 0.030wt%, S: 0.002 wt% to 0.008 wt%, Cu: 0.20 wt% to 0.5wt%, Cr: 0.3 wt% to 0.7wt%,Ni: 0.15 wt % to 0.35wt%, Ti: 0.06 wt% to 0.079wt%, Nb: 0.035 wt% to 0.050wt%, Alt: 0.025 wt% to 0.050wt%. The 600MPa high strength weathering steel has the advantages of low cost, strong competitiveness, cold formability, good welding performance and application to tower frame, heavy duty automobile, bridge, container, railway vehicle manufacture.

The invention belongs to the technical field of high-strength weathering steel production, in particular discloses a Ti microalloyed ultra-fine grain hot rolled steel of 700MPa class and a production method thereof. The method utilizes the thin-slab continuous casting and rolling process to further perfect rolling and cooling control aspects by the readjustment of chemical compositions, is combined with the suitable control of grain ultrafining and TiC precipitation strengthening action, comprehensively improves the impact property and particularly improves the low-temperature impact toughness. The invention truly and reasonably matches with the strength and the toughness of the prior high-strength steel of 700MPa class, and the combination properties comprise: the yield strength is larger than or equal to 700 MPa, the tensile strength is larger than or equal to 750 MPa, the specific elongation is larger than or equal to 14 percent, and the impact absorbing energy Akv of a semi-size specimen (5*10*55mm) at 20 DEG C below zero is larger than or equal to 33 J. The production method enables the hot rolled steel to have high strength and high toughness and widens the range of practical application of the high-strength steel of 700MPa class.

The invention discloses an ultra low carbon hot rolling weathering steel with the yield strength of more than the grade of 550MPa and belongs to the manufacturing field of low alloy steel. The steel consists of the compositions with the following weight percentages: 0.01 to 0.05 percent of C, 0.10 to 0.40 percent of Si, 1.20 to 1.70 percent of Mn, equal to or less than 0.02 percent of P, equal to or less than 0.010 percent of S, 0.15 to 0.80 percent of Cu, 0.40 to 1.25 percent of Cr, 0.10 to 0.50 percent of Ni, equal to or less than 0.40 percent of Mo, 0.03 to 0.06 percent of Nb, equal to or less than 0.050 percent of Ti, 0.0010 to 0.0020 percent of Ca and the residual quantity of Fe and unavoidable impurities. The steel has good mechanical properties, the yield strength of equal to or more than 550MPa and the tensile strength of equal to or more than 650MPa which are both higher than that of traditional weathering steel. Besides, Ti is included in the compositions of the steel.

The invention discloses a novel weathering resistant steel microalloying compound core-spun yarn comprising a steel sheath and a powdery inner core, wherein the powdery inner core is composed of the following chemical ingredients in percentage by weight: 20% of Ca, 0.5% of Mg, 38% of Si, 1.2% of Ba, 1.9% of rare-earth metal, 3.2% of Zr, 1.6% of Ti, 0.5% of B, 0.9% of Mo, 0.5% of Mn, 0.9% of Nb, 0.6% of V and the balance of Fe and inevitable impurity. The invention can obviously refine steel microstructure, improves the decay resistance of steel and lowers C, P and S content in steel by reasonably designing the chemical ingredients; and meanwhile the invention can reduce the amount of parts of alloy elements in steel so as to lower cost.

The invention discloses a Q460-grade fire-resistant weathering steel which comprises the following chemical components in percentage by weight: 0.01-0.20% of C, 0.1-0.4% of Si, 0.5-1.5% of Mn, 0.1-1.0% of Cr, at most 1.0% of Ni, at most 1.0% of Cu, 0.01-0.05% of Nb, 0.01-0.05% of Ti, at most 0.015% of P, at most 0.0020% of S, and the balance of Fe and inevitable impurities, wherein the total amount of the impurity elements does not exceed 0.05%. The steel is subjected to smelting and two-stage rolling, so the prepared steel has excellent fire resistance and weather resistance. The method cancels the component of the precious metal Mo, and enhances the grade of the finished steel.

The present invention relates to a flux cored wire for the gas shielded welding of weathering steel. The wire consists of a steel strip and a core. The steel strip is a carbon steel strip. The core comprises components of the following percentages by weight: 34 to 38% of TiO2, 2.0% of NaF2, 3 to 5% of SiO2, 11 to 12% of Mn, 3 to 5% of Ti-Fe, 5 to 6% of Si-Fe, 3 to 5% of Mg, 2 to 3% of Ni, 3.0 to 4.0% of Cr, 2.0 to 2.5% of Cu, 0.1 to 0.3% of Zr and the balance of ferrous powder. The flux cored wire has excellent welding technical performance, mechanical properties and anti-corrosion properties. The chemical compositions, the mechanical properties and the anti-corrosion properties of deposited metal all meet the welding requirements of weathering steel Q450NQR1. The present invention provides a flux cored wire suitable for weathering steel Q450NQR1.

The invention discloses an argon-rich gas-shielded welding wire of high-strength weathering steel used in railway cars, which is prepared by the following chemical components according to mass percentage: 0.2-0.35 percent of Cu, 0.3-0.7 percent of Cr, 0.2-to 0.6 percent of Ni, 0.05-0.1 percent of C, 0.3-0.5 percent of Si, 1.2-1.45 percent of Mn, P which is less than or equal to 0.015 percent, S which is less than or equal to 0.015 percent, the rest of Fe and unavoidable impurities. The welding wire is characterized by high weatherability, high strength, good flexibility, good resistance to welding cold crack, and the like, and the tensile strength thereof is more than 600MPa and the low-temperature impact property Axv is equal to or more than 146J at minus 40 DEG C. The welding wire adopts argon-rich gas as shield gas and has stabilized arcs, little splash, no air hole and good welding appearance when in welding. Furthermore, weld joints have an excellent matching effect with the high-strength weathering wheel used in the railway cars.

The invention discloses a weathering steel hot-rolled thin belt without P segregation and a manufacturing method thereof. The weathering steel hot-rolled thin belt comprises the following chemical components in percentage by mass: C: 0.07-0.12%; Si: 0.30-0.50%; Mn: 0.4-0.55%; P: 0.06-0.15%; S: not more than 0.02 % and more than 0; Cr: 0.6-0.8%; Ni: 0.03-0.11%; Cu: 0.2-0.5%; Al: not more than 0.046% and more than 0; B: not more than 0.003% and more than 0, and the balance of iron and impurity elements. The weathering steel hot-rolled thin belt disclosed by the invention is low in cost and free from central P segregation and flaky MnS inclusions.

The invention discloses low-cost 550MPa hot-rolled container weathering steel and a manufacturing method thereof. Steel contains C 0.049%~0.069%, Si 0.20%~0.30%, Mn 0.51%~0.79%, P≤0.020%, S≤0.006%, Als 0.015%~0.045%, Cr 0.31%~0.41%, Ni 0.079 %~0.099%, Cu 0.21%~0.29%, Ti 0.057%~0.077%, N≤0.006%, and the rest are Fe and unavoidable impurities. The thickness of the slab is 200-230mm, the heating temperature of the slab is ≥1250°C, the starting temperature of the finishing rolling is 1080-1100°C, the finishing rolling temperature is 921-949°C, laminar cooling is adopted after rolling, and the cooling rate is >20°C /s, the coiling temperature is 619~649℃, after coiling, enter the slow cooling hood for slow cooling, if the thickness of the finished product is ≤2.0mm, it needs to be leveled. The thickness of the steel plate is 1.5~5.0mm, which is used in the container industry.

The present invention relates to steel with high intensity and weatherability used for low alloy power rods and the preparation method thereof. The weathering steel has the chemical composition and the weight percentage content that C is 0.06-0.12 percent, Si is 0.15-0.35 percent, Mn is 1.0-1.40 percent, S is less than or equal to 0.030 percent, P is less than or equal to 0.030 percent, Cu is 0.15-0.30 percent, Al is less than 0.04 percent, Nb is 0.01-0.03 percent, and the residual is Fe and microimpurity. The present invention performs combined blown converter smelting, LF ladle refining, soft argon blowing, and sheet billet continuous casting by using the prior equipment and the conventional process production, and performs microalloying treatment through adjusting the content of partial elements. By accurately controlling the processing condition, the economic weathering steel with good atmospheric corrosion resistant performance and comprehensive mechanical performance can be produced.

A welding method of Q420qENH coating-free weather-resistant steel for steel bridges, the Q420qENH coating-free weather-resistant steel has an atmospheric corrosion resistance index I≥6.5, a welding sensitivity index Pcm≤0.23, and when the welded joint form is a butt weld, The combined welding process of solid wire gas-shielded welding for backing and submerged arc automatic welding for filling and covering is adopted; when the welding joint form is T-shaped penetration fillet weld, the gas-shielded welding process of flux-cored welding wire is adopted; the welding joint form is single-sided bridge deck When welding double-sided formed joint welds, a combined welding process of solid wire gas shielded welding for bottoming and submerged arc automatic welding for filling and covering is used. The atmospheric corrosion resistance index I of the welding wire in the present invention is ≥ 6.5, and the relative corrosion rate of the deposited metal is ≤ 8%, which ensures that the welding seam matches the composition of the steel plate, and solves the weather resistance of the welding seam of the coating-free weather-resistant steel. Coating the weather-resistant steel bridge solved the technical bottleneck.

The invention relates to a high-strength weathering steel thin strip and a production method thereof. The method comprises the following steps of smelting, specifically, a steel ladle correspondinglycomprises the ingredients of, in percentage by weight, less than or equal to 0.03% of C, 0.10-0.40% of Si, 1.50-2.00% of Mn, less than or equal to 0.015% of P, less than or equal to 0.003% of S, lessthan or equal to 0.50% of Cr, 0.20-1.00% of Cu, 0.05-0.50% of Nb and the balance ferrum and unavoidable impurities; thin strip continuous casting, specifically, liquid steel qualified by the smeltingis subjected to the continuous casting to from a cast strip with the thickness being 1.4-2.5 mm through a pair of casting rollers rotating in opposite directions, and the liquid steel overheating temperature is controlled to be 100 DEG C or below; cast strip online hot rolling, specifically, the first-pass hot rolling press-down quantity is 15-65%, and the temperature of strip steel before entering a rolling mill is 950 DEG C or above; and cooling and coiling, the hot-rolled strip steel is cooled to 450-650 DEG C through aerial fog, acicular ferrite and a small amount of pearlite tissue are obtained, and then the steel thin strip is coiled into rolls by a coiler. The high-strength weathering steel thin strip has the advantages of being short in production procedure, low in production cost,easy to weld, good in strip steel plate shape, high in strength and the like and can be widely used in the fields of bridges, buildings, containers, railway carriages and the like.

The invention relates to weather-resistant bridge steel with yield strength not less than 345 MPa and a preparation method thereof. The weather-resistant bridge steel with the yield strength not lessthan 345 MPa comprises the following components of, in percentage by weight, 0.07%-0.11% of C, 0.15%-0.30% of Si, 0.80-1.20% of Mn, less than or equal to 0.015% of P, less than or equal to 0.005% of S, 0.01-0.04% of Al, 0.20-0.40% of Cr, 0.20-0.40% of Cu, 0.20-0.50% of Ni, 0.020-0.050% of Nb, 0.010-0.040% of Ti and the balance Fe and inevitable impurities; and the preparation method comprises thefollowing steps of smelting, slow cooling, heating, rolling, cooling and stacking and cooling. According to the weather-resistant bridge steel with the yield strength not less than 345 MPa and the preparation method thereof, the low-cost micro-alloying design is adopted, the production period is short, the cost is low, popularization and application are facilitated, the weather-resistant bridge steel has excellent welding performance, strong toughness and strong plasticity matching performance, low yield ratio, corrosion resistance, weather resistance, welding performance and anti-fatigue performance, compared with traditional weather-resistant steel, the weather resistance is improved by one time or above, the weather-resistant bridge steel can replace the traditional high-strength weathering steel, and can be applied to the fields of bridges, outdoor tower frames and the like without coating, so that the use cost and the maintenance cost are reduced.

The invention discloses a protective slag for beam blank continuous casting mould of weathering steel. The protective slag contains pre-melted slag, cement clinker, lithium carbonate, borax, fluorite, carbon black, graphite and bentonite. Compared with the prior art, the protective slag has the advantages of good surface quality of the casting blank and non-risk of binding steel leakage.