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Method for measuring glycol ether substance in package paper for cigarette

A technology of glycol ether and determination method, which is applied in the direction of measuring devices, instruments, scientific instruments, etc., and can solve the problems of lack of qualitative and quantitative detection

Active Publication Date: 2017-06-20
SHANGHAI TOBACCO GRP CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] In view of the above-mentioned shortcomings of the prior art, the purpose of the present invention is to provide a method for the determination of glycol ethers in cigarette wrapping paper, which is used to solve the lack of using headspace-gas chromatography / mass spectrometry in the prior art. Qualitative and quantitative detection of glycol ethers in cigarette wrapping paper by technology

Method used

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  • Method for measuring glycol ether substance in package paper for cigarette
  • Method for measuring glycol ether substance in package paper for cigarette
  • Method for measuring glycol ether substance in package paper for cigarette

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0061] 1. Sample preparation

[0062] Take the cigarette wrapping paper sample and cut it into a certain area, and the cut area should include the main packaging surface. When the cigarette wrapping paper is hard box wrapping paper or strip wrapping paper, the cutting area is length×width=22cm×5.5cm; when the cigarette wrapping paper is soft box wrapping paper, the cutting area is length×width=15.5cm× 10cm. Roll the cut cigarette wrapping paper sample with the printing side inward into a tube and put it into a headspace bottle, add 100-2000 μL of triacetin, preferably 1000 μL, as a test sample, and seal it for testing.

[0063] 2. Preparation of standard samples

[0064] Take the base paper corresponding to the cigarette wrapping paper sample and cut it into a certain area. The cutting area of ​​the base paper of the hard box wrapping paper or the strip wrapping paper is length × width = 22cm × 5.5cm; the cutting area of ​​the base paper of the soft box wrapping paper is len...

Embodiment 2

[0074] As shown in step 2 of embodiment 1, prepare the base paper standard sample of hard box packaging paper, carry out headspace-gas chromatography / mass spectrometry (HS-GC / MS) detection according to step 3 of embodiment 1, glycol ethers in the standard sample Headspace-Gas Chromatography / Mass Spectrometry of a substance such as figure 1 shown. Take the quantitative ion peak area of ​​glycol ethers as the ordinate (Y axis), and its corresponding content (in terms of the mass number of the target compound contained in the hard box wrapping paper per unit area, mg / m 2 ) is the abscissa (X axis), perform linear fitting to establish a standard working curve, and the standard working curve is not forced to pass through the origin. Retention time, standard working curve equation and coefficient (R 2 ), the linear concentration range is shown in Table 2. It can be seen from Table 2 that the coefficient R of the standard working curve 2 ≥0.995, good linearity.

[0075] Table 2...

Embodiment 3

[0078]Take a certain brand of hard box wrapping paper sample and cut it according to step 1 in Example 1 to obtain two parallel samples. Roll the printed side of the cut hard box wrapping paper sample into a tube and put it into a headspace bottle. Add the same volume of glycerol triacetate and seal it for testing. The sample prepared above is carried out headspace-gas chromatography / mass spectrometry according to step 3 in embodiment 1, gets the mean value of two parallel determinations as the analysis result of glycol ether substance in the hard box wrapping paper sample of this brand, retains Two digits after the decimal point, see the specific test results figure 2 . Depend on figure 2 As shown, the carton wrapper sample contained 2-ethoxyethanol and 2-butoxyethanol.

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Abstract

The invention provides a method for measuring a glycol ether substance in package paper for a cigarette. The method specifically comprises the following steps of 1), preparation of a test sample; 2), preparation of a standard sample; 3), sample detection: subjecting the test sample and the standard sample to head space-gas chromatographic / mass spectrometric measurement respectively, so as to obtain total ion current chromatograms and selected ion chromatograms of the test sample and the standard sample; 4), qualitative analysis: by using retention time and a fragment ion peak of the glycol ether substance in the total ion current chromatogram of the standard sample as references, determining the glycol ether substance existing in the test sample; 5), quantitative analysis: establishing a standard working curve through the content of glycol ether in the standard sample and the selected ion monitoring chromatogram of the standard sample, and carrying out quantification by an external standard method, so as to obtain the content of the glycol ether substance in the test sample. The method for measuring the glycol ether substance in the package paper for the cigarette, which is provided by the invention, is high in sensitivity and good in repetitiveness and recovery rate; an effective technical means is provided for the qualitative and quantitative analysis of the glycol ether substance in the package paper for the cigarette.

Description

technical field [0001] The invention belongs to the technical field of tobacco detection, and relates to a method for measuring glycol ether substances in cigarette packaging paper. Background technique [0002] Ethylene glycol ether is an important derivative of ethylene oxide, which is widely used. It is often used as a cosolvent for inks and adhesives, and can also be used as a stabilizer, thinner, paint remover, cleaner, antifreeze, etc. Glycol ether has certain toxicity, water solubility and volatility, which can cause environmental pollution and is listed as a substance of very high concern. Cigarette wrapping paper includes cigarette box wrapping paper (hard box, soft box) and strip wrapping paper. In the production and printing process, ink, thinner, stabilizer, etc. are commonly used. If there is glycol ether residue, it will adversely affect product quality and safety. [0003] At present, the analysis of glycol ether substances in cigarette sticks and box wrappi...

Claims

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Application Information

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IPC IPC(8): G01N30/06G01N30/88
CPCG01N30/06G01N30/88
Inventor 孙文梁周亦辰王晔周宛虹曹昌清王源王颖周懿华
Owner SHANGHAI TOBACCO GRP CO LTD
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