Fluorescent carbon dot with dual functions of catalysis and indication, its preparation method and application
A fluorescent carbon dots, dual-function technology, applied in chemical instruments and methods, fluorescence/phosphorescence, physical/chemical process catalysts, etc., can solve the problems of poor water solubility of carbon sources, poor fluorescence properties, and short fluorescence lifetime.
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[0030] In the present invention, a method for preparing fluorescent carbon dots with dual functions of catalysis and process indication is provided. The preparation method includes: first mixing a paramagnetic phthalocyanine material with excellent water solubility and a solvent, then performing heat treatment, and finally performing Fluorescent carbon dots with dual functions of catalysis and process indication were obtained after purification.
[0031] In the above preparation method, the selected paramagnetic phthalocyanine materials have no fluorescent properties, and all have peroxide-mimicking enzyme properties. Its type can be selected in a wide range, but in order to select a carbon source with excellent water solubility and greatly improve the quantum yield of carbon dot fluorescence, preferably, the paramagnetic phthalocyanine material is cobalt phthalocyanine, Iron phthalocyanine, manganese phthalocyanine or sulfonated cobalt phthalocyanine.
[0032] However, in or...
Embodiment 1
[0044]Add 0.01g of sulfonated cobalt phthalocyanine to 40ml of water, react at 140°C for 36h, then filter, centrifuge, and dialyze in a dialysis bag with a cut-off of 1000 for 24h to obtain a fluorescent carbon with dual functions of catalysis and indication Point, denoted as A1.
Embodiment 2
[0046] Add 0.03g of sulfonated cobalt phthalocyanine to 40ml of water, react at 200°C for 20h, then filter, centrifuge, and dialyze in a dialysis bag with a cut-off of 1000 for 24h to obtain fluorescent carbon dots with dual functions of catalysis and indication , denoted as A2.
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