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ABS two-layer composite plate and preparation method thereof, liner and preparation method thereof as well as refrigeration equipment

A double-layer composite, ABS material technology, used in chemical instruments and methods, layered products, synthetic resin layered products, etc., can solve the problems of intolerance and high risk of cracking in the refrigerator liner, and achieve cost reduction and beautiful appearance. , high gloss effect

Inactive Publication Date: 2017-08-18
NANJING CHUANGWEI HOUSEHOLD ELECTRONICS APPLIANCES LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

At present, ABS (acrylonitrile-butadiene-styrene copolymer) resin is widely used as a refrigerator liner material, and it is not resistant to the mixed blowing agent HFC-245fa (1,1,1,3,3-pentafluoro propane) and LBA (1-chloro, 3,3,3-trifluoropropene), resulting in a higher risk of cracking of the refrigerator liner

Method used

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Examples

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preparation example Construction

[0041] The present invention also proposes a preparation method of the ABS double-layer composite board, the preparation method comprising the following steps:

[0042] The mixture is prepared by mixing special ABS material with high-grade rubber powder, wherein the number average molecular weight of the acrylonitrile component in the special ABS material is greater than or equal to 180,000;

[0043] Extrusion-grade ABS material is provided, and the mixture and extrusion-grade ABS material are subjected to double-layer co-extrusion treatment to obtain the ABS double-layer composite sheet. The ABS double-layer composite sheet includes a substrate layer and a substrate layer formed on the substrate. The surface layer on the surface of the layer contains extrusion-grade ABS material, and the substrate layer contains ABS special material and high rubber powder.

[0044]Further, pigments and auxiliary agents are added to the above mixture; before the double-layer co-extrusion treat...

Embodiment 1

[0053] The parts by weight of each component in the first mixed material of table 1

[0054] components Parts by weight / % ABS special material 67.5 High rubber powder 30 pigment 2 Auxiliary 0.5

[0055] Step 1: According to Table 1, weigh each component. Among them, the melt index of the ABS special material is 5g / 10min at 200°C and 5kg; the number average molecular weight of the acrylonitrile component is 180,000; the particle size of the rubber particles is 1μm. The mass fraction of polybutadiene rubber in the high rubber powder is 55%, and the particle size of polybutadiene rubber is 1 μm; the pigment is titanium dioxide; the auxiliary agent is antioxidant and lubricant. Fully mix the above-mentioned components in a stirring mixer to obtain a first mixed material.

[0056] The second step: transport the first mixed material to the hopper of the twin-screw extruder, set the heating temperature to 180° C., extrude, pelletize, and dry t...

Embodiment 2

[0064] Step 1: According to Table 1, weigh each component. Among them, the melt index of the ABS special material is 3g / 10min at 200°C and 5kg; the number average molecular weight of the acrylonitrile component is 300,000; the particle size of the rubber particles is 2μm. The mass fraction of polybutadiene rubber in the high rubber powder is 70%, and the particle size of polybutadiene rubber is 2 μm; the pigment is titanium dioxide; the auxiliary agent is antioxidant and lubricant. Fully mix the above-mentioned components in a stirring mixer to obtain a first mixed material.

[0065] The second step: transport the first mixed material to the hopper of the twin-screw extruder, set the heating temperature to 235° C., extrude, pelletize, and dry to obtain the modified ABS material.

[0066] Step 3: Weigh each component according to Table 2, wherein the melt index of extrusion-grade ABS material at 200°C and 5kg is 4g / 10min; the gloss at 60°reflection angle is 100°. The componen...

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Abstract

The invention provides an ABS two-layer composite plate which comprises a base material layer and a surface layer formed on the base material layer, wherein the surface layer contains an extrusion-grade ABS material; the base material layer contains an ABS special material and high glue powder; the number-average molecular weight of an acrylonitrile component in the ABS special material is greater than or equal to 180,000. The ABS two-layer composite plate provided by the invention has high gloss and is resistant to the corrosion of a foaming agent. The invention also provides a preparation method of the ABS two-layer composite plate, a liner using the ABS two-layer composite plate, a preparation method of the liner and refrigeration equipment using the liner.

Description

technical field [0001] The invention relates to the technical field of refrigeration equipment, in particular to an ABS double-layer composite board and a preparation method thereof, an inner tank using the ABS double-layer composite board, a preparation method of the inner tank, and a refrigeration equipment using the inner tank. Background technique [0002] With the upgrading of refrigerator foaming technology, the types of foaming agents are becoming more and more diverse, and the requirements for the corrosion resistance of refrigerator liner materials are getting higher and higher. One side of the refrigerator liner faces the interior of the refrigerator, which needs to meet the high-gloss aesthetic requirements; the other side is in direct contact with the foaming agent, which needs to meet the corrosion resistance requirements. At present, ABS (acrylonitrile-butadiene-styrene copolymer) resin is widely used as a refrigerator liner material, and it is not resistant to...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): B32B27/06B32B27/30B32B27/20B32B27/18C08L55/02B29C47/06
CPCB32B27/08B32B27/18B32B27/20B32B27/302B32B27/308B32B2307/714B32B2509/10B29C48/022B29C48/21C08L55/02C08L2205/025
Inventor 李志文坚
Owner NANJING CHUANGWEI HOUSEHOLD ELECTRONICS APPLIANCES LTD
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