Oxide crystal, its preparation method and conductive paint containing oxide crystal
A technology of conductive coatings and oxides, applied in conductive coatings, conductive materials dispersed in non-conductive inorganic materials, circuits, etc., can solve the problem of reduced reliability and durability of solar cells, reduced conductive metal content, and reduced physical properties. question
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[0047] Another aspect of the present application is to provide a method for preparing oxide crystals, especially the preparation of lead-tellurium-bismuth-oxide crystals. In one embodiment, the application provides a lead-tellurium-bismuth-oxide crystal preparation method comprising the following steps: (i) providing PbO-TeO 2 -Bi 2 o 3 For the substrate glass, (ii) subjecting the glass to its crystallization temperature for about 3 to 24 hours. In step (i) PbO-TeO 2 -Bi 2 o 3 The glass as the base will be in the form of powder, block, powder, etc., but preferably in the form of glass powder. In (i) step, the glass may be placed at its crystallization temperature for 6, 8, 9, 12, 15, 18, 21 hours. According to this application, for PbO-TeO 2 -Bi 2 o 3 The crystallization temperature of the glass used as the substrate for heat treatment in step (ii) must be higher than its Tg glass transition temperature (glass transition temperature). In one embodiment, for PbO-TeO i...
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[0073] Preparation of lead-tellurium-bismuth-oxide crystals
[0074] First, the differential scanning calorimetry (DSC) was used to examine the PbO-TeO 2 -BiO 2 is the crystallization temperature of the glass powder of the substrate. To measure the crystallization temperature, 20 mg of PbO-TeO 2 -BiO 2 The glass powder used as the substrate was heated from room temperature to 600°C at a heating rate of 20°C per minute, and then cooled using nitrogen as a carrier gas. The analysis results of the differential calorimetry scanning method are shown in Fig. 1 .
[0075] According to the analysis result of differential calorimetry, PbO-TeO 2 -BiO 2 The glass transition temperature of the glass as the substrate is about 266 degrees Celsius, and at least two crystal phases exist, because there are two crystallization temperature peaks (ie about 320 degrees Celsius and 400 degrees Celsius).
[0076] Then, the PbO-TeO 2 -BiO 2 The glass powder used as the base is heat-treated...
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