Composition for corrosion and scale inhibition and sterilization and application thereof

A technology of corrosion inhibition, scale inhibition and composition, which is applied in the field of corrosion inhibition, scale inhibition and sterilization composition, which can solve the problems of low dosage, difficulty in having good corrosion inhibition, scale inhibition and sterilization performance at the same time, and achieve optimal mitigation Eclipse effect

Active Publication Date: 2017-10-31
CHINA PETROLEUM & CHEM CORP +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0006] The purpose of the present invention is to overcome the shortcomings of the existing water treatment chemicals that are difficult to have good corrosion inhibition, scale inhibition and bactericidal perf

Method used

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  • Composition for corrosion and scale inhibition and sterilization and application thereof
  • Composition for corrosion and scale inhibition and sterilization and application thereof
  • Composition for corrosion and scale inhibition and sterilization and application thereof

Examples

Experimental program
Comparison scheme
Effect test

Example Embodiment

[0047] Example 1-4

[0048] Add chemicals to the test water as shown in Table 3 and perform scale inhibition, corrosion inhibition and sterilization performance tests. The specific test methods are as follows. *Mg / L described in Table 3 represents the effective (dry basis) content, and the tin salt is calculated as tin ion.

[0049] Evaluation of scale inhibition performance

[0050] Add the reagent to the test water, evaporate and concentrate in a constant temperature water bath at 80±1℃, to a concentration of 5 times, sample and analyze the remaining Ca in the water 2+ At the same time, make a blank sample and calculate the scale inhibition rate. The calculation formula of scale inhibition rate is: scale inhibition rate=(C-C 0 ) / (nC 1 -C 0 )×100%, where,

[0051] C: remaining Ca in the water 2+ Concentration (mg / L)

[0052] C 0 : Blank Ca 2+ Concentration (mg / L)

[0053] C 1 :Ca in raw water 2+ Concentration (mg / L)

[0054] n: concentration factor

[0055] Evaluation of corrosion inhib...

Example Embodiment

[0072] Example 5

[0073] In order to simulate the scene, a dynamic simulation test was carried out. The dynamic simulation test method is carried out according to the chemical industry standard HG / T2160-91 of the People's Republic of China, and the control parameters are as follows.

[0074] Water quality: test raw water 1, see Table 1.

[0075] Concentration factor: A tower 4.0±0.2 B tower 4.0±0.2

[0076] pH: Tower A control 8.0±0.2 Tower B control 8.0±0.2

[0077] Velocity: 1.0m / s

[0078] Pharmacy:

[0079] Tower A: Weigh 4g of PBTCA with an effective content of 50% by weight, 8g of HEDP with an effective content of 50% by weight, 2g of sodium gluconate, 26.7g of copolymer 1 with a solid content of 30% by weight, and dissolve it in 57.8g of water. Add 1.5 g of tin tetrachloride pentahydrate to fully dissolve it and shake it up to obtain 100 g of the required medicine. When the prepared agent is added to water at a concentration of 100 mg / L, the effective concentrations of PBTCA, H...

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Abstract

The invention relates to the field of water treatment and discloses a composition for corrosion and scale inhibition and sterilization and an application thereof. The composition contains a water-soluble tin salt, an organic phosphonic acid, hydroxy carboxylate and a copolymer, wherein the copolymer comprises a structural unit provided by 2-acrylamide-2-methyl propane sulfonic acid; on the basis of the gross of the copolymer, the weight percent of the structural unit provided by the 2-acrylamide-2-methyl propane sulfonic acid is greater than or equal to 20%, wherein the weight ratio of the water-soluble tin salt to the organic phosphonic acid to the hydroxy carboxylate to the copolymer is 1:(1-20):(1-12):(1-20); and the weight of the water-soluble tin salt is calculated according to tin ions. The composition for corrosion and scale inhibition and sterilization has relatively good corrosion inhibition property, scale inhibition property and sterilization property and is relatively low in dosage in use.

Description

technical field [0001] The invention relates to the field of water treatment, in particular to a composition for corrosion inhibition, scale inhibition and sterilization and its application in the treatment of circulating cooling water. Background technique [0002] Long-term operation of circulating cooling water will cause problems of corrosion, scaling and bacterial growth, so corrosion inhibitors, scale inhibitors and bactericides need to be added separately. Research on non-toxic, highly efficient multifunctional water treatment agents is the direction of pharmaceutical research and development. Most petrochemical enterprises use composite corrosion and scale inhibitors. The more widely used formulas include phosphorus-based (composed of polyphosphate, polycarboxylic acid and copolymer, zinc salt, etc.), all-organic system (composed of organic phosphonic acid, polycarboxylic acid and copolymer, azole compounds with or without Zinc salt composition), etc. In the proce...

Claims

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Application Information

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IPC IPC(8): C02F5/14C02F5/10
CPCC02F5/105C02F5/145C02F2303/04C02F2303/08C02F2303/22
Inventor 魏新郦和生张化冰张春原
Owner CHINA PETROLEUM & CHEM CORP
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