Polydopamine-coated silica gel modified by polyethylene polyamine, method for preparing polydopamine-coated silica gel modified by polyethylene polyamine and application of polydopamine-coated silica gel modified by polyethylene polyamine
A polyvinylpolyamine and polydopamine technology, applied in chemical instruments and methods, other chemical processes, water/sludge/sewage treatment, etc., to achieve the effects of firm bonding, large adsorption capacity and good stability
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Embodiment 1
[0018] Example 1 Preparation of polydopamine-coated silica gel SG@DETA / PDA modified by diethylenetriamine
[0019] (1) Activation of silica gel: place the silica gel in a nitric acid solution with a volume concentration of 50% for 12 h, wash it with deionized water until it is neutral, and dry it; After washing with deionized water until neutral, vacuum-dry at 60°C for 12 h, and set aside;
[0020] (2) Synthesis of polyethylene polyamine-modified polydopamine-coated silica gel: disperse 0.2 g of activated silica gel in 200 mL of Tirs-HCl buffer solution with pH=8.5, stir for 5 min, then add 0.4 g of dopamine hydrochloride and 6 mmol Diethylenetriamine (DETA) was slowly stirred at 25 °C for 24 h, and the product was centrifuged and washed with distilled water, then dried in vacuum at 55 °C to obtain SG@DETA / PDA.
Embodiment 2
[0021] Example 2 Preparation of triethylenetetramine-modified polydopamine-coated silica gel SG@TETA / PDA
[0022] The diethylenetriamine added in step (2) of Example 1 was replaced with triethylenetetramine (TETA), and other operations were carried out as in Example 1 to obtain SG@TETA / PDA.
Embodiment 3
[0023] Example 3 Preparation of tetraethylenepentamine-modified polydopamine-coated silica gel SG@TEPA / PDA
[0024] The diethylenetriamine added in step (2) of Example 1 was replaced with tetraethylenepentamine (TEPA), and other operations were carried out according to Example 1 to obtain SG@TEPA / PDA.
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