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Graphene coordinated continuous glass fiber reinforced halogen-free flame-retardant weather-resistant PPO/HIPS alloy material and preparation method thereof

A continuous glass fiber and alloy material technology, applied in the field of polymer materials, can solve the problems of not meeting the design requirements of high-strength parts and limited mechanical strength, so as to improve rigidity, impact toughness and weather resistance, and improve interface compatibility , Improve the effect of processability

Active Publication Date: 2018-01-05
HEFEI GENIUS NEW MATERIALS
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The material has limited mechanical strength and cannot meet the design requirements of high-strength parts

Method used

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  • Graphene coordinated continuous glass fiber reinforced halogen-free flame-retardant weather-resistant PPO/HIPS alloy material and preparation method thereof
  • Graphene coordinated continuous glass fiber reinforced halogen-free flame-retardant weather-resistant PPO/HIPS alloy material and preparation method thereof
  • Graphene coordinated continuous glass fiber reinforced halogen-free flame-retardant weather-resistant PPO/HIPS alloy material and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0038] (1), a graphene synergistic continuous glass fiber reinforced halogen-free flame-retardant and weather-resistant PPO / HIPS alloy material, the cutting length of the material is 6-25mm, the particle size is 4.0mm, and it includes the following components by weight: PPO 480 320 parts of HIPS, 200 parts of continuous glass fiber, 5 parts of graphene, 10 parts of compatibilizer, 80 parts of toughening agent, 80 parts of flame retardant, 6 parts of antioxidant, 5 parts of compound light stabilizer, lubrication Agent PETS 6 parts, zinc oxide 5 parts;

[0039] (2), a method for preparing graphene synergistic continuous glass fiber reinforced halogen-free flame-retardant and weather-resistant PPO / HIPS alloy material, comprising the following steps:

[0040] a. Drying preparation: the preheating and drying conditions of PPO are dried at 100-110°C for 3-4 hours, and the preheated drying conditions of HIPS are dried at 80-90°C for 1-2 hours;

[0041] B, mixing preparation: the sil...

Embodiment 2

[0054] (1), a graphene synergistic continuous glass fiber reinforced halogen-free flame-retardant and weather-resistant PPO / HIPS alloy material, the cutting length of the material is 6-25mm, the particle size is 4.0mm, and it includes the following components by weight: PPO 420 280 parts of HIPS, 300 parts of continuous glass fiber, 10 parts of graphene, 15 parts of compatibilizer, 65 parts of toughening agent, 100 parts of flame retardant, 8 parts of antioxidant, 4 parts of compound light stabilizer, lubricating Agent A-C540A 6 parts, calcium oxide 10 parts;

[0055] (2), a method for preparing graphene synergistic continuous glass fiber reinforced halogen-free flame-retardant and weather-resistant PPO / HIPS alloy material, comprising the following steps:

[0056] a. Drying preparation: the preheating and drying conditions of PPO are dried at 100-110°C for 3-4 hours, and the preheated drying conditions of HIPS are dried at 80-90°C for 1-2 hours;

[0057] B, mixing preparation...

Embodiment 3

[0065] (1), a graphene synergistic continuous glass fiber reinforced halogen-free flame-retardant and weather-resistant PPO / HIPS alloy material, the material has a cutting length of 6-25mm and a particle size of 3.0mm, including the following components by weight: PPO:360 parts, HIPS: 240 parts, continuous glass fiber: 400 parts, graphene 15 parts, compatibilizer 20 parts, toughening agent 50 parts, flame retardant 120 parts, antioxidant: 10 parts, compound light stabilizer: 3 parts, lubricant GM-100: 8 parts, zinc oxide 15 parts;

[0066] (2), a method for preparing graphene synergistic continuous glass fiber reinforced halogen-free flame-retardant and weather-resistant PPO / HIPS alloy material, comprising the following steps:

[0067] a. Drying preparation: the preheating and drying conditions of PPO are dried at 100-110°C for 3-4 hours, and the preheated drying conditions of HIPS are dried at 80-90°C for 1-2 hours;

[0068]B, mixing preparation: the silane coupling agent KH...

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Abstract

The invention discloses a graphene coordinated continuous glass fiber reinforced halogen-free flame-retardant weather-resistant PPO / HIPS alloy material. The material is prepared from the following components in parts by weight: 360 to 480 parts of PPO, 240 to 320 parts of HIPS, 200 to 400 parts of continuous glass fiber, 5 to 15 parts of graphene, 10 to 20 parts of a compatibilizing agent, 50 to 80 parts of a toughening agent, 80 to 120 parts of a flame retardant, 6 to 10 parts of an antioxidant, 3 to 5 parts of a composite light stabilizer, 4 to 8 parts of a lubricant and 5 to 15 parts of metal oxide. According to the invention, through addition of predispersed graphene coordinated continuous glass fiber reinforced PPO / HIPS alloy, and compounding with a variety of functional additives, the material provided by the invention has excellent rigidity, impact toughness, weather resistance and flame-retardant performance; meanwhile, no glass fiber is exposed on the surface of an injection-molded workpiece, so application of glass fiber reinforced PPO / HIPS alloy in different fields can be satisfied; the material can be directly molded through injection molding, so the production efficiency is high; and a used workpiece can be recycled after crushing.

Description

technical field [0001] The invention relates to the technical field of polymer materials, in particular to a graphene synergistic continuous glass fiber reinforced halogen-free flame-retardant and weather-resistant PPO / HIPS alloy material and a preparation method thereof. Background technique [0002] Polyphenylene oxide (PPO) is an excellent thermoplastic engineering plastic. It has good mechanical properties, thermal properties and electrical properties, but has the disadvantages of high melting temperature, high melt viscosity, poor thermoplastic formability and poor resistance to organic solvents (such as halogenated aliphatic hydrocarbons), which limit its application range. In order to improve the performance of PPO and expand its application field, it is necessary to modify PPO, and the modified PPO is called MPPO. The modified polyphenylene ether alloy has excellent comprehensive performance and many varieties, and is widely used in various fields, such as: automobi...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L71/12C08L51/04C08L51/08C08K13/06C08K9/06C08K3/04C08K7/14C08K3/22
Inventor 杨桂生蒋超杰姚晨光
Owner HEFEI GENIUS NEW MATERIALS
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