Method and material for preparing polylactic acid-natural rubber porous material by micropore injection molding foaming

A natural rubber, injection foaming technology, applied in the direction of coating, etc., can solve the problems of poor toughness of polylactic acid, and achieve the effect of increasing compatibility, cell size and distribution, and good toughness
CN107599296AActive Publication Date: 2018-01-19贵州黔城黔测检测技术有限公司

Patent Information

Authority / Receiving Office
CN · China
Patent Type
Applications(China)
Current Assignee / Owner
贵州黔城黔测检测技术有限公司
Publication Date
2018-01-19

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Abstract

The invention belongs to the technical field of micropore injection molding foaming, and discloses a method and a material for preparing a polylactic acid-natural rubber porous material by micropore injection molding foaming. Grafts are prepared through emulsion polymerization; dried polylactic acid particles and glycidyl methacrylate-natural rubber grafts are mixed in proportion, and are molten and mixed by adopting a double-screw extruder for extrusion and granulation; the micropore injection molding foaming is performed on the mixed particles by adopting an injection molding machine with agas compression unit; and with a supercritical CO2 fluid as a foaming agent, a polylactic acid / natural rubber porous material is obtained. Polylactic acid is roughened and modified by adopting naturalrubber; and the method of grafting glycidyl methacrylate on the natural rubber is used for improving polarity of the natural rubber and compatibility with the polylactic acid. The foaming process issimple; the obtained foaming material is more uniform in bubble size and distribution; and meanwhile, the foaming material is better in toughness.
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Description

technical field

[0001] The invention belongs to the technical field of microporous injection foaming, in particular to a method and material for preparing polylactic acid-natural rubber porous material by microporous injection foaming. Background technique

[0002] The development of microcellular injection foaming technology began in 1970 and 1980. The foaming process of microcellular injection molding is divided into three steps: nucleation, cell enlargement and cell stabilization. First, a supercritical fluid (usually nitrogen or carbon dioxide) is dissolved in the polymer melt as a blowing agent to form a polymer-gas homogeneous solution, that is, the polymer melt is supersaturated with gas. Then, the gas pressure suddenly drops below the saturation pressure, resulting in thermodynamic instability leading to the nucleation of cells. Cell growth is controlled by the diffusion rate of the gas and the strength of the polymer-gas melt. The cell density of microcellular in...

Claims

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