Organic compound containing triazine as core and application of organic compound
A technology of organic compounds and compounds, which is applied in the field of OLEDs and compound materials, can solve problems such as differences, and achieve the effects of avoiding aggregation, improving recombination rate, and good film-forming properties
- Summary
- Abstract
- Description
- Claims
- Application Information
AI Technical Summary
Problems solved by technology
Method used
Image
Examples
Embodiment 1
[0040]Embodiment 1: the synthesis of compound 2
[0041]
[0042] Dissolve 0.03mol of raw material A-1 and 0.06mol of raw material B-1 in a mixed solvent of toluene / water (250mL / 50mL), and add 0.003mol of Pd(PPh 3 ) 4 React with 0.08mol potassium carbonate at 100°C for 24 hours. Return to room temperature after the reaction, separate, dry, and column chromatography to obtain intermediate D-1;
[0043] Dissolve 0.02mol of raw material D-1 and 0.02mol of bis(pinacol radical) diboron in a mixed solvent of toluene / water (250mL / 50mL), and add 0.002mol of Pd(PPh 3 ) 4 React with 0.03mol potassium carbonate at 100°C for 24 hours. Return to room temperature after the reaction, separate, dry, and column chromatography to obtain intermediate E-1;
[0044] Dissolve 0.01mol of raw material E-1 and 0.01mol of raw material F-1 in a mixed solvent of toluene / water (250mL / 50mL), and add 0.0015mol of Pd(PPh 3 ) 4 React with 0.015mol potassium carbonate at 100°C for 24 hours. Return t...
Embodiment 2
[0046] Embodiment 2: the synthesis of compound 11
[0047]
[0048] Compound 11 and its synthetic procedure are similar to those of compound 2, except that starting material A-2 and starting material B-2 are used instead of starting material A-1 and starting material B-1.
[0049] Elemental analysis structure (molecular formula C 48 h 29 N 7 ): theoretical value C, 81.92; H, 4.15; N, 13.93; test value: C, 81.95; H, 4.14; N, 13.92. ESI-MS(m / z)(M + ): The theoretical value is 703.81, and the measured value is 703.84.
Embodiment 3
[0050] Embodiment 3: the synthesis of compound 21
[0051]
[0052] Dissolve 0.03 mol of raw material A-2 and 0.06 mol of raw material B-3 in toluene (500 mL), and add 0.003 mol of Pd after fully deoxygenating with nitrogen 2 (dba) 3 React with 0.08mol potassium tert-butoxide at 100°C for 24 hours. Return to room temperature after the reaction, separate, dry, and column chromatography to obtain intermediate D-3;
[0053] Dissolve 0.02mol of raw material D-3 and 0.02mol of bis(pinacol radical) diboron in a mixed solvent of toluene / water (250mL / 50mL), and add 0.002mol of Pd(PPh 3 ) 4 React with 0.03mol potassium carbonate at 100°C for 24 hours. Return to room temperature after the reaction, separate, dry, and column chromatography to obtain intermediate E-3;
[0054] Dissolve 0.01mol of raw material E-3 and 0.01mol of raw material F-1 in a mixed solvent of toluene / water (250mL / 50mL), and add 0.0015mol of Pd(PPh 3 ) 4 React with 0.015mol potassium carbonate at 100°C for...
PUM
| Property | Measurement | Unit |
|---|---|---|
| Thickness | aaaaa | aaaaa |
| Glass transition temperature | aaaaa | aaaaa |
Abstract
Description
Claims
Application Information
Login to View More