Preparation method of carbon nano-tube graphene inorganic zinc-enriched anti-corrosion coating

A carbon nanotube, inorganic zinc-rich technology, used in anti-corrosion coatings, conductive coatings, coatings, etc., can solve problems such as endangering the life and health of workers and differences in the passivation of steel substrates, reducing zinc oxide fog, time-consuming Short, the effect of reducing the content of zinc powder

Inactive Publication Date: 2018-02-02
TIANJIN MEISHIBANG PAINT CHEM IND
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Problems solved by technology

[0003] However, in the process of general coating film formation, with the evaporation of water, the pH value of the coating changes, and the electrode potential of the steel substrate is not always in the state of electrochemical protection, so the passivation effect of the coating on the steel substrate is also different.
[0004] In addition, although epoxy zinc-rich primer coatings have shielding, electrochemical protection, coating self-repairing and passivation functions, the anti-corrosion performance is at the expense of zinc powder, and a large amount of zinc oxide mist will be generated during welding. Hazard to the life and health of workers

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  • Preparation method of carbon nano-tube graphene inorganic zinc-enriched anti-corrosion coating

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[0025] Unless otherwise defined, the technical terms used in the following embodiments have the same meaning as commonly understood by those skilled in the art to which the present invention belongs. The test reagents used in the following examples, unless otherwise specified, are conventional biochemical reagents; the experimental methods, unless otherwise specified, are conventional methods.

[0026] The present invention will be described in detail below in conjunction with examples.

[0027] 1, a kind of preparation method of carbon nanotube graphene inorganic zinc-rich anticorrosion coating, comprises the steps:

[0028] (1) Preparation of component A: add solvent, slowly add anti-settling agent under stirring condition, add polyvinyl butyral after high-speed dispersion, the dispersion speed of the disperser is 600r / min, and the dispersion time is 30min. After the carbon nanotubes are uniformly dispersed, they are ground with grinding sand, the grinding temperature is 50...

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Abstract

The invention provides a preparation method of carbon nano-tube graphene inorganic zinc-enriched anti-corrosion coating. The preparation method of the carbon nano-tube graphene inorganic zinc-enrichedanti-corrosion coating comprises the following steps: (1) preparing a component A: adding a solvent, slowly adding anti-settling agent under the stirring condition, dispersing at high speed, adding polyvinyl butyral and the carbon nano-tube, dispersing uniformly, grinding with grinding sand, filtering to remove the grinding sand, adding zinc powder and graphene, adjusting by the solvent, and packaging; (2) preparing a component B: dropwise adding water into resin and the solvent under the stirring state, stirring for 10 to 30 minutes, dropwise adding hydrochloric acid, stirring for 10 to 30 minutes, heating to 40 to 50 DEG C, stirring and heating for a period of time, adding the solvent, adjusting and packaging. The preparation method of the carbon nano-tube graphene inorganic zinc-enriched anti-corrosion coating and the preparation method of a novel formula are cooperatively used, so the corrosion effect is improved, the use amount of the zinc powder is reduced, fog generated by zincoxide is reduced and environmental friendliness is achieved.

Description

technical field [0001] The invention belongs to the field of paint manufacturing, in particular to a carbon nanotube graphene inorganic zinc-rich anticorrosion paint. Background technique [0002] The zinc-rich primer with polyethylsilicate hydrolyzate as a film-forming substance is a very important one in antirust and anticorrosion coatings, because it achieves the protection of zinc powder on steel through -Si-O-Si-semiconductor. Electrochemical protection, also known as electrochemical antirust paint, is an inorganic zinc-rich primer. The shielding effect of zinc-rich coatings mainly depends on the formation of refractory salts and corrosion products. Zinc-rich coatings contain a large amount of zinc powder. The zinc particles are in close contact with the steel surface. The zinc potential is more negative than that of iron. Therefore, in the electrolyte solution, zinc atoms tend to lose electrons and become anodes, while iron is a cathode. In the anode area, zinc is co...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C09D183/02C09D5/10C09D5/24C09D7/61
CPCC09D183/02C08K2003/0893C08K2003/265C08K2003/3045C08K2201/011C09D5/106C09D5/24C08L29/14C08K13/04C08K3/26C08K3/30C08K3/08C08K3/04C08K7/24
Inventor 马翔宇王新征
Owner TIANJIN MEISHIBANG PAINT CHEM IND
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