Excited light regulated red-green emitting rare earth up-conversion nanoparticle and preparation method thereof

A technology of rare earth up-conversion and nano-particles, applied in the field of nano-particles

Active Publication Date: 2018-02-27
HEFEI UNIV OF TECH
View PDF3 Cites 33 Cited by
  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, there are no reports of rare-earth upconversion nanoparticles

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
View more

Image

Smart Image Click on the blue labels to locate them in the text.
Viewing Examples
Smart Image
  • Excited light regulated red-green emitting rare earth up-conversion nanoparticle and preparation method thereof
  • Excited light regulated red-green emitting rare earth up-conversion nanoparticle and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0038] The rare earth up-conversion nanoparticles in this embodiment have a four-layer core-shell structure, which are successively an activator layer, an energy transfer agent layer, a sensitizer layer and a passivator layer from the inside to the outside, and its chemical expression is: NaErF 4 :Yb,Tm@NaYF 4 :Yb@NaNdF 4 :Yb@NaYF 4 , that is, NaErF co-doped with Yb and Tm 4 Nanoparticle Core NaErF 4 : Yb, Tm is the activator layer, and the outer core is sequentially coated with Yb-doped NaYF as the energy transfer agent layer 4 First shell NaYF 4 : Yb, Yb-doped NaNdF as sensitizer layer 4 Second shell NaNdF 4 : Yb, and NaYF as a passivation layer 4 third shell NaYF 4 .

[0039] where: in the activator layer, Er 3+ 、Tm 3+ , Yb 3+ The molar percentage is 50%: 0.5%: 49.5%; in the energy transfer agent layer Y 3+ with Yb 3+ The molar percentage of is 90%: 10%; in the sensitizer layer, Nd 3+ with Yb 3+ The molar percentage is 90%: 10%.

[0040] In this embodiment,...

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to view more

PUM

No PUM Login to view more

Abstract

The invention discloses an excited light regulated red-green emitting rare earth up-conversion nanoparticle and a preparation method thereof. The excited light regulated red-green emitting rare earthup-conversion nanoparticle emits red fluorescence under excitation of a 980 nm laser and emits green fluorescence under excitation of a 800 nm laser; the nanoparticle is a four-layer core-shell structure and comprises, from the inside to the outside, an activator layer, an energy transfer agent layer, a sensitizer layer, and a passivation layer; and chemical expression is NaErF4:Yb, Tm@NaYF4:Yb@NaNdF4:Yb@NaYF4. By adjusting doping concentration of different ions in the core-shell structure of the rare earth up conversion nanoparticle, the rare earth up-conversion nanoparticle emits different colors of fluorescence along with change of wavelength of the excited light; the rare earth up-conversion nanoparticle prepared by the invention has the characteristics of simple preparation, easy availability of raw materials, excellent optical properties and the like, and has broad application prospects.

Description

technical field [0001] The invention relates to the field of nanoparticles, in particular to a preparation method of rare earth up-conversion nanoparticles, the nanoparticles of which can emit red and green light under the excitation of adjustable excitation light. Background technique [0002] Rare-earth upconversion nanoparticles (UCNPs) are a new class of fluorescent probe materials that absorb long-wavelength low-energy photons and emit short-wavelength high-energy photons, and have many unique advantages, such as excellent optical stability, high chemical stability, low In addition, under the excitation of near-infrared light, it has many advantages such as deep tissue penetration ability, no damage to biological tissues, almost zero background fluorescence interference, and high imaging sensitivity. It has broad application prospects in biomedicine. Zhao Yuliang et al. applied the upconversion nanoparticles prepared by the hydrothermal method. By adjusting the doping a...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to view more

Application Information

Patent Timeline
no application Login to view more
IPC IPC(8): C09K11/02C09K11/85
CPCC09K11/02C09K11/7773
Inventor 梅青松陈健张翠兰凌枭张勇
Owner HEFEI UNIV OF TECH
Who we serve
  • R&D Engineer
  • R&D Manager
  • IP Professional
Why Eureka
  • Industry Leading Data Capabilities
  • Powerful AI technology
  • Patent DNA Extraction
Social media
Try Eureka
PatSnap group products