Protein markers of coronary heart disease in urine and its use
A technology for coronary heart disease and its application, which is applied in the field of protein markers of coronary heart disease in urine, and can solve the problems of abnormal expression level, unclear mechanism of action, and no clear report on the correlation of coronary heart disease
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Embodiment 1
[0039] Example 1 Screening of Coronary Heart Disease Related Proteins in Urine
[0040] Urine was screened for coronary heart disease-related proteins using isotope-labeled relative and absolute quantification (iTRAQ) labeling differential proteomics.
[0041] Materials and Reagents
[0042] 1) Instrument: ultra-high performance liquid chromatography (Waters Company), model ACQUITY UPLC H-Class. TripleTOF mass spectrometer (AB sciex company), model 5600.
[0043] 2) Main reagents: Pierce BCA Protein Quantitative Analysis Kit (Thermo Scientific); trypsin (Promega); C18 solid-phase extraction cartridge (3CC, 60 mg, Waters); 4 standard iTRAQ reagents (AB sciex); C18 reverse-phase chromatographic column (4.6mm × 250mm, C18, 3μm, Waters Company).
[0044] 3) Sample: obtained from Peking Union Medical College Hospital.
[0045] 1.1 Preparation of urine protein
[0046] Urine samples were centrifuged at 5000 g for 30 min at 4 °C to remove cell debris. Take the supernatant, add ...
Embodiment 2
[0053] Example 2 Mass Spectrometry Detection of Urinary Protein TFF1 and APOD
[0054] In order to better carry out the application detection of these differential proteomic analysis results in further larger-scale clinical samples, the inventors used the target mass spectrometry analysis method to monitor the differential proteins identified. Multiple reaction monitoring (Multiple Reaction Monitor, MRM) is a target mass spectrometry quantitative analysis technology based on the signal of secondary mass spectrometry. It does not require special chemical labeling assistance, and can simultaneously perform absolute and relative quantitative determination of multiple proteins.
[0055] Materials and Reagents
[0056] 1) Instrument: ultra-high performance liquid chromatography (Waters Company), model ACQUITY UPLC H-Class. TripleTOF mass spectrometer (AB sciex company), model 5600.
[0057] 2) Main reagents: Pierce BCA Protein Quantitative Analysis Kit (Thermo Scientific); trypsi...
Embodiment 3
[0077] Example 3 Analysis of mass spectrometry detection results based on urine protein TFF1 and APOD combined with other urine proteins
[0078] In addition to urine TFF1 and APOD, 17 other proteins were also detected by mass spectrometry at the same time. Taking AMPE as an example, ROC curve analysis was performed on the protein combination, and the results showed the AUC analysis results of the combination of TFF1, APOD and AMPE. was 0.95, its specificity was 0.92, and its sensitivity was 0.82. Compared with only using TFF1 and APOD, there was no significant improvement, but this operation showed that integrated analysis could be performed based on the combination of TFF1 and APOD with other urine proteins. For specific ROC curves, see Figure 5 .
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