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Recycling method of aluminum ash

A resourceful, aluminum ash technology, applied in the field of aluminum ash treatment, can solve problems such as soluble salt environmental pollution, complex secondary aluminum ash components, water and air pollution, etc., achieve physical and chemical properties, promote the formation of glass network structure, Achieve the effect of harmless discharge

Inactive Publication Date: 2018-04-17
NORTH CHINA UNIVERSITY OF TECHNOLOGY
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The composition of the secondary aluminum ash is very complex, and the metal aluminum (3-9wt.%) is tiny aluminum particles mixed in the ash residue after frying ash. It is difficult to use chemical methods or physical methods under the premise of considering the recovery cost. Methods to realize further recycling of resources
Among them, metal aluminum particles, AlN, Al 4 C 3 Substances such as fluorocarbons are highly active, and will produce flammable and toxic gases when in contact with water or in humid air, which is highly environmentally harmful; fluorine-containing compounds and a small amount of heavy metals have leachable toxicity, which may cause serious pollution to water bodies and air; soluble salts It is also very easy to enter the river and cause environmental pollution; therefore, it is difficult to dispose of aluminum ash through traditional landfill methods, otherwise it will cause serious harm to the environment

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment approach

[0025] (1) The industrial secondary aluminum ash refers to the secondary aluminum ash containing F, As or / and Pb, Cr, Cd heavy metal elements produced in industrial production and having the property of hazardous solid waste. After these industrial secondary aluminum ash are ground for 0.5-5 hours, the active tiny aluminum particles in the aluminum ash can be extended into flakes, which increases the diameter of the aluminum particles, so that the aluminum flakes and aluminum The ash powder is separated so that the aluminum flakes can be recycled, and the aluminum ash powder can be used to prepare glass-ceramic materials.

[0026] (2) According to the characteristics of the composition of aluminum ash micropowder, after mixing aluminum ash micropowder with silicon-containing minerals, calcium-containing minerals, magnesium-containing minerals, and nucleating agents according to a certain ratio, it can be processed by melting, mold cooling and heat treatment made of glass-ceram...

Embodiment 1

[0033] A resource utilization method of aluminum ash, comprising the following steps:

[0034] Step a1. Grinding the industrial secondary aluminum ash for 3 hours, the grinding medium is zirconia beads of Φ=15mm, and passing through a 40-mesh sieve after grinding, so as to obtain aluminum flakes and aluminum ash micropowder.

[0035] Step b1, by weight, with 50 parts of aluminum ash micropowder, 31 parts of SiO 2 , 10 parts of CaO, 4 parts of TiO 2 Mix evenly with 5 parts of MgO, then place in a melting furnace and heat to 1500°C for melting treatment, so as to obtain a melted solution.

[0036] Step c1: Pour the melted solution into a mold for cooling and molding to obtain a glass block, then heat-treat the glass block at 780°C for 4 hours, and then at 950°C for 3 hours, Thus, a high-alumina glass-ceramic material is obtained.

[0037] Specifically, the glass-ceramic material prepared in Example 1 of the present invention has albite and anorthite as the main crystal phases...

Embodiment 2

[0039] A resource utilization method of aluminum ash, comprising the following steps:

[0040] Step a2: Grinding the industrial secondary aluminum ash for 3 hours, the grinding medium is zirconia beads of Φ=15mm, and passing through a 40-mesh sieve after grinding, so as to obtain aluminum flakes and aluminum ash micropowder.

[0041] Step b2, by weight, with 50 parts of aluminum ash micropowder, 31 parts of SiO 2 , 10 parts of CaO, 4 parts of TiO 2 , 5 parts of MgO and 0.1 part of Co 2 o 3 Mix evenly, then place in a melting furnace and heat to 1500°C for melting treatment, so as to obtain a melted solution.

[0042] Step c2: Pour the melted solution into a mold for cooling and molding to obtain a glass block, then heat-treat the glass block at 780°C for 4 hours, and then at 880°C for 3 hours, Thus, a high-alumina glass-ceramic material is obtained.

[0043] Specifically, the glass-ceramic material prepared in Example 2 of the present invention has a uniform overall cryst...

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Abstract

The invention discloses a recycling method of aluminum ash. The recycling method includes: grinding industrial secondary aluminum ash for 0.5-5h, and sieving with a 40-mesh screen to obtain aluminum ash micropowder; well mixing, by weight, 25-65 parts of aluminum ash micropowder, 20-35 parts of SiO2, 10-30 parts of CaO, 4-12 parts of TiO2, 5-12 parts of MgO and 0-5 parts of colorant; and putting in a melting furnace for melting treatment to obtain melt after melting; pouring the melt into a die, cooling-molding to obtain a glassy-state block, and thermally treating the glassy-state block to obtain a microcrystalline glass material. By the recycling method, the microcrystalline glass material stable in structure can be made of the aluminum ash, so that the defect of being prone to generating toxic and harmful volatile matters when existing wet methods are used to extract useful ingredients in the aluminum ash is overcome effectively, and harmless treatment and recycling of the aluminumash are realized.

Description

technical field [0001] The invention relates to the technical field of aluminum ash treatment, in particular to a resource utilization method of aluminum ash. Background technique [0002] Aluminum products have important applications in aerospace, building materials, high-speed rail, automobiles and other fields. In recent years, the domestic aluminum industry has developed rapidly, but a large amount of solid hazardous waste aluminum ash will be produced in the process of aluminum smelting. The composition of the secondary aluminum ash is very complex, and the metal aluminum (3-9wt.%) is tiny aluminum particles mixed in the ash residue after frying ash. It is difficult to use chemical methods or physical methods under the premise of considering the recovery cost. The method realizes further recycling of resources. It has been determined that industrial secondary aluminum ash contains 3-9wt.% metal aluminum particles, 40-70wt.% alumina, 10-20wt.% NaCl, KCl and other solub...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C03C10/06C03C10/04C03C6/10C03C1/04C03B32/02
CPCC03B32/02C03C1/002C03C1/04C03C10/0018C03C10/0036
Inventor 焦志伟周伟梁锐刘伟崔岩刘峰斌刘茵杨越
Owner NORTH CHINA UNIVERSITY OF TECHNOLOGY
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