Unlock instant, AI-driven research and patent intelligence for your innovation.

High processing temperature flame-retardant long glass fiber-reinforced polypropylene material and preparation method thereof

A polypropylene material and processing temperature technology, applied in the field of high processing temperature flame-retardant long glass fiber reinforced polypropylene material and its preparation, can solve the problem of high flame retardant addition, uneven dispersion of flame retardant, combustion and mechanical properties Low-level problems, to achieve excellent flame retardancy and thermal properties, good dispersion, and mechanical properties are not affected

Inactive Publication Date: 2018-04-27
江苏万纳普新材料科技有限公司
View PDF2 Cites 4 Cited by
  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

This manufacturing method has the defects of uneven dispersion of flame retardants, high addition of flame retardants, low combustion and mechanical properties and large fluctuations

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
View more

Image

Smart Image Click on the blue labels to locate them in the text.
Viewing Examples
Smart Image
  • High processing temperature flame-retardant long glass fiber-reinforced polypropylene material and preparation method thereof
  • High processing temperature flame-retardant long glass fiber-reinforced polypropylene material and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0023] 1) Production of functional flame retardant masterbatch

[0024] 13 parts of polypropylene grafted with maleic anhydride, 67.44 parts of ethyl-bis(tetrabromophthalimide), 16.86 parts of antimony trioxide, 0.1 part of antioxidant AT-10 and 0.1 part of AT-168 , 0.5 parts of anti-dripping agent AD-541 and 2 parts of lubricant montan wax were poured into a high-speed mixing mixer and mixed for 10 minutes, and the aforementioned mixed materials were added to the internal mixer for banburying, and the banburying processing temperature was 160°C. Pour the banbury-mixed material into the forced feeder, the speed of the feeder is 5rpm, the material enters the single screw from the feeder, the extrusion temperature is 200°C, the screw speed is 275rpm, the product is hot-cut into pellets, and air-dried Let cool and set aside.

[0025] 2) Preparation of high processing temperature flame retardant long glass fiber reinforced polypropylene material:

[0026] Pass 20 parts of long g...

Embodiment 2

[0028] 1) Production of functional flame retardant masterbatch

[0029] 16.10 parts of polypropylene grafted with maleic anhydride, 50.5 parts of ethyl-bis(tetrabromophthalimide) and 13.84 parts of decabromodiphenylethane, 16.86 parts of antimony trioxide, 0.1 part of antioxidant Pour AT-10 and 0.1 part of AT-168, 0.5 part of anti-dripping agent AD-541 and 2 parts of lubricant montan wax into a high-speed mixing mixer and mix for 10 minutes, then add the above-mentioned mixed materials into the internal mixer for banburying , the banburying processing temperature is 160°C, the banburying good material is poured into the forced feeder, the speed of the feeder is 5rpm, the material enters the single screw from the feeder, the extrusion temperature is 200°C, the screw speed The temperature is 275rpm, and the product is hot-cut into pellets, air-dried and cooled for later use.

[0030] 2) Preparation of high processing temperature flame retardant LFT-PP material:

[0031] Pass 2...

Embodiment 3

[0033] 1) 12.63 parts of polypropylene grafted with maleic anhydride, 52 parts of ethyl-bis(tetrabromophthalimide), 16 parts of brominated polystyrene, 16.67 parts of antimony trioxide, 0.1 part of antioxidant Put agent AT-10 and 0.1 part of AT-168, 0.5 part of anti-dripping agent AD-541 and 2 parts of lubricant montan wax into a high-speed mixing mixer and mix for 10 minutes, and put the aforementioned mixed materials into the internal mixer Mixing, the banburying processing temperature is 160°C, pour the mixed materials into the forced feeder, the speed of the feeder is 5rpm, the material enters the feeder into the single screw, the extrusion temperature is 200°C, the screw The rotating speed is 275rpm, and the product is hot-cut into pellets, air-dried and cooled for later use.

[0034] 2) Preparation of high processing temperature flame retardant LFT-PP material:

[0035] Pass 20 parts of long glass fiber, 30 parts of functional flame retardant masterbatch and 50 parts of...

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More

PUM

PropertyMeasurementUnit
lengthaaaaaaaaaa
Login to View More

Abstract

The invention relates to the field of high processing temperature functional flame retardant materials and particularly relates to a high processing temperature flame-retardant long glass fiber-reinforced polypropylene material and a preparation method thereof. The high processing temperature flame-retardant long glass fiber-reinforced polypropylene material is prepared from 15 to 35 parts by massof functional flame retardant master batches, 10 to 40 parts by mass of long glass fibers and 20 to 60 parts by mass of polypropylene resin. The functional flame retardant master batches are preparedfrom 5 to 25 parts by mass of a carrier resin, 60 to 80 parts by mass of a flame retardant, 10 to 30 parts by mass of a flame retardant synergist, 0.05 to 2 parts by mass of an antioxidant, 0.05 to 2parts by mass of an anti-dripping agent and 0.5 to 3 parts by mass of a lubricant. The high processing temperature flame-retardant long glass fiber-reinforced polypropylene material has excellent flame retardant performances and a high thermal deformation temperature. The ultra-high heat-resistant ethyl-bis(tetrabromophthalimide) flame retardant has excellent thermal stability, is not decomposedat a processing temperature of 280 to 320 DEG C, can be well dispersed, has excellent flame retardant and thermal properties and retains the mechanical properties.

Description

technical field [0001] The invention relates to the field of high processing temperature functional flame retardant materials, in particular to a high processing temperature flame retardant long glass fiber reinforced polypropylene material and a preparation method thereof. Background technique [0002] Long glass fiber reinforced thermoplastic materials refer to long, continuous glass fibers that are fully infiltrated with resin through a special process to obtain long strips, then cut into glass fiber reinforced rubber particles of specific sizes or long glass fibers coated with resin impregnation Strips are directly molded or injection molded. The length of the glass fiber in the long glass fiber reinforced material is generally more than 3mm. Among them, long glass fiber-reinforced composite materials based on polypropylene PP have the advantages of light specific gravity, small molding shrinkage, excellent fatigue resistance, good fluidity, and recyclability. As an eme...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More

Application Information

Patent Timeline
no application Login to View More
Patent Type & Authority Applications(China)
IPC IPC(8): C08L23/12C08L51/06C08L91/00C08L25/06C08L23/06C08K13/04C08K7/14C08K3/22C08K5/03C08K5/3417C08J3/22C08J5/04
CPCC08J3/226C08J5/043C08J2323/12C08J2423/06C08J2423/12C08J2425/06C08J2451/06C08K3/2279C08K5/03C08K5/3417C08K7/14C08K13/04
Inventor 王同海岳子玉宋洪祥李翰卿
Owner 江苏万纳普新材料科技有限公司