The invention relates to the technical field of
lithium secondary battery additives and particularly relates to a
lithium secondary battery additive, a preparation method thereof and application thereof. The additive is LibMaXc, M is B, Al, Ga, In, Y, Sc, Sb, Bi, Nb, Ta, Ti, Zr, V, Cr, Mo, W, Mn, Tc, Re, Fe, Co, Ni, Cu, Ag, Zn, Cd, La, Ce, Pr, Nd, Pm, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb or Lu, X isF, Cl, Br or I, b is larger than or equal to 0.2 and smaller than or equal to 6, a is larger than or equal to 0.1 and smaller than or equal to 3, and c is larger than or equal to 1 and smaller than or equal to 9. The
lithium secondary battery additive has the advantages of high
ionic conductivity and air stability, the rapid transmission of
electrode ions can be improved, the
electrode loading capacity and thickness are improved, and the
energy density of the battery is improved.