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130results about How to "Mechanical properties are not affected" patented technology

Preparation method for fluorine silicon phosphorus-containing anti-dropping flame-retardant polyethylene terephthalate

The invention discloses a preparation method for fluorine silicon phosphorus-containing anti-dropping flame-retardant polyethylene terephthalate. The preparation method is characterized by comprising the following steps of: performing prepolymerization on a phosphorus-containing copolymerization flame retardant to synthesize phosphorus-containing copolymerization flame retardant prepolymer; performing dehydration reaction on trifluoalkyl siloxane and octaalkylcyclotetrasiloxane; adding dihydroxy siloxane and a catalyst, and reacting to synthesize dihydroxy fluorosiloxane; performing esterification on terephthalic acid and glycol; adding a catalyst B and a stabilizing agent; adding the phosphorus-containing copolymerization flame retardant prepolymer and the dihydroxy fluorosiloxane for polycondensation; and after the reaction is finished, cooling by using water and granulating to prepare the fluorine silicon phosphorus-containing anti-dropping flame-retardant polyethylene terephthalate. The product prepared by the method has high flame-retardant and anti-dropping properties and can serve as a raw material for producing films with the flame-retardant property of 94ULV-0 level or VTM-0 level, flame-retardant fibers and textiles with the flame-retardant level I and higher level, and V0-level flame-retardant plastic products.
Owner:四川东方绝缘材料股份有限公司

Quaternary phosphonium salt pillared layered zirconium phosphate material, and preparation method and application thereof

The invention discloses a quaternary phosphonium salt pillared layered zirconium phosphate material, and a preparation method and an application thereof. The chemical formula of the quaternary phosphonium salt pillared layered zirconium phosphate material is as follows, R is methyl, butyl, phenyl or alkane with the length of a carbon chain of 8-20; X is Cl or Br; and m is 1, and n is 0.00288-0.174462. The preparation method comprises the steps of utilizing methylamine to prop up an interlayer spacing interval of zirconium phosphate, obtaining a methylamine-zirconium phosphate precursor, then adding a quaternary phosphonium salt into the methylamine-zirconium phosphate precursor for continuously carrying out reaction for a certain time, replacing the methylamine in the precursor and obtaining the quaternary phosphonium salt pillared layered zirconium phosphate material with white or light gray external appearance, and the quaternary phosphonium salt pillared layered zirconium phosphate material can be added into plastics, rubber, fibers, coatings, adhesives, paper and other materials for preparing an antibacterial or flame-retardant functional material, and be also used for removing algae in water and governing large-area red tide and water blooms in fresh water.
Owner:JINAN UNIVERSITY

Low-smoke-density low-heat-release halogen-free flame-retardant PC material and preparation method and application thereof

ActiveCN112409770AImproved smoke density and heat release propertiesDesign sciencePolycarbonateOrganosilicon
The invention belongs to the technical field of polymer composite materials, and discloses a low-smoke-density low-heat-release halogen-free flame-retardant PC material and a preparation method and application thereof. The low-smoke-density low-heat-release halogen-free flame-retardant PC material is prepared from the following raw materials in percentage by weight: 10-80wt% of polycarbonate, 10-60wt% of polycarbonate siloxane copolymer, 4-20wt% of organic silicon / poly(bis(phenoxy)phosphazene) copolymer, 5-30wt% of mineral powder and 0.1-5 wt% of processing aid. The structural formula of the organosilicon / poly(bis(phenoxy)phosphazene) copolymer is shown as a formula I in the specification. The balance of mechanical properties, flame retardancy and processability of the PC material is fullyconsidered, the organic silicon / poly(bis(phenoxy)phosphazene) copolymer is creatively adopted as the flame retardant and smoke suppressant, and the smoke suppression and heat absorption effects of the inorganic mineral powder are assisted, so that the smoke density and heat release amount of the material during combustion are effectively reduced.
Owner:SICHUAN COREMER CO LTD

Quaternary ammonium cation and quaternary phosphonium cation-containing modified clay, its preparation and application

Belonging to the field of organic-inorganic hybrid materials, the invention provides a quaternary ammonium cation and quaternary phosphonium cation-containing organic cation modified clay, its preparation method and application. The preparation method comprises: reacting a suspending solution of a sodium base treated clay mineral with quaternary ammonium cations and quaternary phosphonium cations, conducting filtering, washing, drying and crushing, thus obtaining the quaternary ammonium cation and quaternary phosphonium cation-containing organic cation modified clay with a synergistic effect. The organic cation modified clay provided in the invention has good stability, excellent weather resistance, and no toxicity. The organic cation modified clay contains quaternary ammonium cation modified clay and quaternary phosphonium cation modified clay simultaneously, and shows a synergistic antibacterial activity, so that it can be applied to plastics, rubber, fibers, coatings, adhesives, paper, wood-plastic composite materials and a variety of polymer materials to improve the antibacterial property, the flame retardance and the barrier property of polymers, and has no influence on the mechanical properties of the polymers.
Owner:JINAN UNIVERSITY

Manufacturing method of composite board seal head made from high-strength austenite nickel-iron-chromium alloy and austenite stainless steel

The invention discloses a manufacturing method of composite board seal head made from high-strength austenite nickel-iron-chromium alloy and austenite stainless steel. The manufacturing method comprises the following steps of: medium-temperature heat forming; after heat forming, carrying out a solution treatment process; and carrying out a pressing process, wherein the pressing process satisfies technological conditions as follows: a empty furnace is heated to 1000+/-75 DEG C, a seal head circular plate is placed in the furnace at a temperature greater than or equal to 800 DEG C, and is then heated to 1100+/-15 DEG C along with the furnace; the seal head circular plate is maintained at the temperature for 2-4h, and is then discharged from the furnace to be pressed for more than 2 times while the seal head circular plate is hot; the temperature of the seal head is measured at any time during the pressing process; and when the temperature of the seal head is lower than 850 DEG C, the seal head circular plate is put back into the furnace against to be heated, and the final pressing temperature of the seal head circular plate is no less than 850 DEG C. The manufacturing method disclosed by the invention employs processes of radial finishing polishing treatment before the composite board seal head is pressed, middle-temperature heat forming, and solution treatment after heat forming.
Owner:NANJING DUBLE METAL EQUIP ENG

Acicular hydroxyapatite micro-nanostructure coating on magnesium alloy surface and preparation method thereof

The invention belongs to the technical field of surface modification of degradable magnesium alloy implants, and particularly relates to an acicular hydroxyapatite micro-nanostructure coating on the magnesium alloy surface and a preparation method thereof. The preparation method comprises the following steps of immersing a pretreated magnesium alloy substrate in an electrolyte solution for electrochemical deposition, using a platinum electrode as a cathode and magnesium alloy as an anode, turning on a DC stabilized power supply, performing electrochemical deposition and then performing alkaliheat treatment to obtain the hydroxyapatite coating on the magnesium alloy surface. The electrolyte solution for the electrochemical deposition has simple formula, has no accelerator or oxidant, and does not need to adjust the pH value. The electrochemical deposition method with low temperature and low current density is easy to control and low in cost. The prepared hydroxyapatite coating is uniform and dense, has high purity and good corrosion resistance and has the acicular micro-nano structure, which is beneficial to adhesion and growth of the cells on the surface of the coating. The implantation success rate of the magnesium alloy implants can be improved.
Owner:QINGDAO UNIV OF SCI & TECH

Preparation method for ammonium polyphosphate/kaolin composite flame retardant

InactiveCN105061811AImprove anti-dialysis performanceGood compatibilityAmmonium polyphosphateChemistry
The invention discloses a preparation method for an ammonium polyphosphate/kaolin composite flame retardant. The preparation method specifically comprises the following process steps: (1) calcining superfine water-washed kaolin for 1 to 2 hours at 600 to 900 DEG C to obtain calcined kaolin; (2) performing surface modification on ammonium polyphosphate by using cyanurtriamide to obtained modified ammonium polyphosphate, wherein the modifying temperature is 100 to 250 DEG C, the modifying time is 1 to 2 hours, and the using amount of the cyanurtriamide is 5 to 25 percent of the mass of the ammonium polyphosphate; (3) mixing the calcined kaolin and the modified ammonium polyphosphate in a mass ratio of 1:2-6, and performing compounded surface modification by using a modifier to obtain the ammonium polyphosphate/kaolin composite flame retardant, wherein the modifying temperature is 60 to 120 DEG C, the modifying time is 15 to 60 minutes, and the using amount of the modifier is 0.5 to 3 percent of the total mass of the calcined kaolin and the modified ammonium polyphosphate. According to the preparation method for the ammonium polyphosphate/kaolin composite flame retardant, the water solubility and the hygroscopicity of the ammonium polyphosphate can be reduced obviously; the dialysis resistance of an ammonium polyphosphate filled polymer product can be improved.
Owner:CHINA UNIV OF MINING & TECH (BEIJING)

Structural flame-retardant functional composite material and preparation method thereof

The invention provides a structural flame-retardant functional composite material which comprises a flame-retardant fireproof fiber felt and a composite material, and the surface of the composite material body is coated with the flame-retardant fireproof fiber felt. The invention further provides a preparation method of the structural flame-retardant functional composite material. The preparationmethod comprises the following steps: (1) preparing the flame-retardant fireproof fiber felt; (2) pre-impregnating the fiber felt; and (3) preparing the flame-retardant composite material. Compared with the prior art, a surface flame-retardant structure is adopted, the flame-retardant functional structure layer with the functions of flame retardance, heat insulation, smoke suppression and the likeis concentrated on the surface of the composite material based on the combustion behavior that the composite material expands from outside to inside after being ignited, and in the process that the composite material is on fire, the structure can be used as a fireproofing suit to isolate flame and heat outside the composite material so that the internal structure of the material is protected, andthe damage of a flame retardant to the composite material matrix is avoided.
Owner:NINGBO NOTTINGHAM NEW MATERIALS INST CO LTD +1

Heat-resisting oxygen aging polypropylene composition with low dispersity and preparation method of heat-resisting oxygen aging polypropylene composition

The invention discloses a heat-resisting oxygen aging polypropylene composition with low dispersity and a preparation method of the heat-resisting oxygen aging polypropylene composition. The composition is prepared from the following raw materials by weight: 46-97% of polypropylene, 0-40% of inorganic filler, 0-10% of toughening agent, 1-3% of absorbent, 0.1-1% of antioxidant, 0.1-2% of other additives. The preparation method comprises the following steps: weighing the raw materials according to weight percentage, putting the raw materials into a high-speed mixer to dry-blend for 5-15 minutes, adding the mixed raw materials into a double-screw rod extruder, smelting and extruding, subsequently cooling and pelleting so as to prepare the polypropylene composition, wherein a first zone is 190-200 DEG C, a second zone is 200-210 DEG C, a third zone is 210-220 DEG C and a fourth zone is 205-215 DEG C, the retaining time in the whole extrusion process is 1-2 minutes, and the pressure is 12-18Mpa. The heat-resisting oxygen aging polypropylene composition has the advantages that low molecular weight compounds are effectively adsorbed and the dispersity is reduced as the additives are added into the polypropylene composition, acid substances, residual catalyst and the like in the composition are adsorbed and cleaned, so that the heat-resisting oxygen aging property is improved.
Owner:ZHEJIANG PRET NEW MATERIALS +2
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