Low-dielectric laser direct structuring composite material suitable for 5G communication and preparation method thereof

A composite material, low-dielectric technology, applied in the field of 5G communication low-dielectric laser direct structuring composite materials and their preparation, can solve the problem that the use of modifiers affects the performance of laser-sensitive additives of LDS materials, affects the LDS performance of composite materials, impact resistance The strength needs to be improved and other problems to achieve the effect of reducing the defects of the finished coating, eliminating the adverse effects and improving the metal adhesion

Active Publication Date: 2020-01-07
中广核高新核材科技(苏州)有限公司
View PDF25 Cites 29 Cited by
  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

CN 107177180 A and CN 107177181 A respectively disclose a glass fiber reinforced polycarbonate resin composition for laser direct molding, and its aging resistance and degradation resistance need to be improved, and CN 109627665 A discloses a The thermoplastic resin composition and preparation method thereof, its impact strength needs to be improved, CN104497535 A and CN 104497537 A disclose a kind of polycarbonate composition for LDS and the polycarbonate composition for LDS with good thermal stability respectively, Both mechanical strength and low dielectric properties need to be improved
[0008] The 5G low dielectric constant LDS composite material is not a simple integration of low dielectric material and LDS material. Improper use of the modifier added to the low dielectric material will affect the performance of the laser sensitive additive of the LDS material.
Due to the differences in thermal expansion / shrinkage and surface polarity between the metal core and the plastic, the metal core is easily detached from the resin surface that has been ablated by the laser, and the part that is detached from the metal core will be missing in the next electroless electroless plating process. In order to provide the implanted crystal nuclei and seeds for the electroplated metal, there will be defects in the electroplated metal, and it is impossible to form a continuous electroplating line, which will eventually lead to poor metal adhesion and product defects
If the low-dielectric additive affects the dispersion of the LDS laser-sensitive additive and the absorption of the laser, if it affects the anchoring of the reduced metal core and the implantation of the metal during the electroplating process, it will eventually affect the LDS performance of the composite material, resulting in Product metal circuit defects and low yield

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
View more

Image

Smart Image Click on the blue labels to locate them in the text.
Viewing Examples
Smart Image
  • Low-dielectric laser direct structuring composite material suitable for 5G communication and preparation method thereof
  • Low-dielectric laser direct structuring composite material suitable for 5G communication and preparation method thereof
  • Low-dielectric laser direct structuring composite material suitable for 5G communication and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0048] A low-dielectric laser direct structuring LDS composite material suitable for 5G communication, the LDS composite material consists of the following components by weight:

[0049]

[0050]

[0051] Weigh 63 parts of polyimide, 10 parts of hollow glass microspheres, 20 parts of silicon dioxide, 0.5 part of melamine cyanurate, 0.5 part of aluminum phenyl hypophosphite, 5 parts of silicon-containing MBS, 1 part of HDPE, 0.5 part of PETS, 0.1 part of antioxidant 1010, 0.1 part of antioxidant 168, 30 parts of copper chromium oxide spinel, mix evenly to obtain a mixture, and add the mixture to the main feed of the twin-screw extruder In the process, after melt extrusion, it is drawn from the outlet of the die head, and after water cooling, it is pelletized to obtain LDS composite material particles suitable for 5G communication low dielectric laser direct molding.

[0052] The melt extrusion temperature of the above-mentioned twin-screw extruder is 280-360° C., and the ...

Embodiment 2

[0054] A low-dielectric laser direct structuring LDS composite material suitable for 5G communication, the LDS composite material consists of the following components by weight:

[0055]

[0056]

[0057] Weigh 75 parts of polyphenylene sulfide, 5 parts of hollow glass microspheres, 5 parts of mica powder, 3 parts of melamine, 3 parts of diethylaluminum hypophosphite, 3 parts of SEBS, 1 part of LDPE-MAH, 0.3 parts of PETS according to parts by weight After 0.3 part, 1076 parts of antioxidant, 1680.1 part of antioxidant, 15 parts of stannous thiocyanate, mix uniformly to obtain compound, add compound in the main feed of twin-screw extruder, add E glass fiber 15 One part is added to the side feed of the twin-screw extruder, and it is drawn out from the outlet of the die after being melted and extruded. After water cooling, it is pelletized to obtain LDS composite material particles suitable for 5G communication low dielectric laser direct molding.

[0058] The melt extrusi...

Embodiment 3

[0060] A low-dielectric laser direct structuring LDS composite material suitable for 5G communication, the LDS composite material consists of the following components by weight:

[0061]

[0062] Weigh 86 parts of polyphenylene ether, 5 parts of hydrotalcite, 5 parts of mica powder, 3 parts of dicyandiamide, 4 parts of aluminum phenyl hypophosphite, 5 parts of POE, 10 parts of HIPS, 0.1 part of PETS, antioxidant After 0.5 parts of 1098, 0.5 parts of antioxidant P-EPQ, and 20 parts of cobalt-nickel arene complex, mix evenly to obtain a mixture, add the mixture to the main feed of the twin-screw extruder, and add 5 parts of hollow E glass fiber , 5 parts of D glass fiber are added to the side feed of the twin-screw extruder, melted and extruded, drawn from the outlet of the die head, water-cooled and pelletized to obtain LDS composite material particles suitable for 5G communication low-dielectric laser direct molding.

[0063] The melt extrusion temperature of the above-ment...

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to view more

PUM

PropertyMeasurementUnit
diameteraaaaaaaaaa
particle diameteraaaaaaaaaa
diameteraaaaaaaaaa
Login to view more

Abstract

The invention relates to a low-dielectric laser direct structuring composite material suitable for 5G communication. The composite material is composed of the following components in parts by weight:52 to 86 parts of base resin, 0 to 30 parts of glass fibers, 10 to 30 parts of a filling agent, 1 to 9 parts of a flame retardant, 4 to 15 parts of a toughening agent, 0.1 to 1 part of a lubricating agent, 0.2 to 1 part of an antioxidant and 10 to 30 parts of a laser sensitive additive. A preparation method of the composite material comprises the steps that a twin-screw extruder is used for processing, the melt extrusion temperature is 250-380 DEG C, and the screw rotating speed is 150-300 rpm/min. The composite material has low dielectric property, so that improvement of the transmission speed of 5G communication millimeter wave signals is facilitated, the signal delay is reduced, and the signal loss is reduced; the composite material has the LDS processing capacity, can be rapidly prepared in a small size and a large number, can be subjected to batch laser etching and chemical plating to form a metal connecting circuit, and is an optimal solution of a 5G plastic antenna oscillator material.

Description

technical field [0001] The invention relates to the field of LDS composite materials, in particular to a low-dielectric laser direct molding composite material suitable for 5G communication and a preparation method thereof. Background technique [0002] Laser Direct Structuring (LDS) is a laser manufacturing technology, also known as three-dimensional (3D) three-dimensional circuit printing technology in the industry. It is a manufacturing technology that selectively forms metal circuits on plastic parts. A popular method for cell phone antennas. Traditional plastic parts need to be combined with electrical circuits, which need to be completed through processes such as welding and compounding with metals. It is not easy to achieve miniaturization and high precision of its products. The plastic parts added with LDS additives can directly have the function of electrical interconnection after the two-step process of laser engraving and electroless plating. Obviously, the trad...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to view more

Application Information

Patent Timeline
no application Login to view more
Patent Type & Authority Applications(China)
IPC IPC(8): C08L79/08C08L23/06C08K13/04C08K7/28C08K3/36C08K5/3492C08K5/5313C08K3/22C08L81/02C08L53/02C08K7/14C08K3/34C08K3/30C08L71/12C08L23/08C08L51/04C08K5/00C08L69/00C08K13/06C08K9/06C08K3/32
CPCC08L79/08C08L81/02C08L71/12C08L69/00C08K2003/2241C08L23/06C08K13/04C08K7/28C08K3/36C08K5/34928C08K5/5313C08K3/22C08L53/025C08K7/14C08K3/34C08K5/34922C08K3/30C08L23/0815C08L51/04C08K5/0091C08L53/02C08K13/06C08K9/06C08K3/32
Inventor 何晓东
Owner 中广核高新核材科技(苏州)有限公司
Who we serve
  • R&D Engineer
  • R&D Manager
  • IP Professional
Why Eureka
  • Industry Leading Data Capabilities
  • Powerful AI technology
  • Patent DNA Extraction
Social media
Try Eureka
PatSnap group products