A flame-retardant electric vehicle plastic shell
A technology for plastic shells and electric vehicles, applied in the field of flame retardant materials, can solve the problems of uneven surface, easy fire, poor flame retardant performance, etc., to prevent melting and dripping, improve mechanical properties and heat resistance, heat good stability
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[0037] The present invention also provides a kind of preparation method of polyurea resin, comprises the following steps:
[0038] (1) Mix the dehydrated siloxane polyether diol with diisocyanate and diluent evenly in a reaction kettle, and then react at 80-95°C for 2-4 hours to obtain component A;
[0039] (2) Mix the dehydrated amino-terminated polyether, the dehydrated amine chain extender with organic aluminum hypophosphite, polytetrafluoroethylene, ammonium polyphosphate, dipentaerythritol, and additives in a reactor, Stir at 120°C for 1-2 hours to obtain component B.
[0040] According to the present invention, in order to optimize the reaction efficiency, before the reaction, the present invention also dehydrates the raw materials under reduced pressure. Under the preferred conditions, the dehydration process of the siloxane polyether diol is as follows: the temperature is 100-120°C, The pressure is 0.02-0.1 MPa, and the time is 1-3 hours.
[0041]According to the pre...
Embodiment 1
[0053] The contents of each raw material in component A and component B in this embodiment are shown in Table 1.
[0054] (1) Preparation of polyurea resin:
[0055] Dehydrate 40 parts by weight of siloxane polyether diol at a temperature of 110°C and a pressure of 0.05 MPa for 2 hours, then mix the dehydrated siloxane polyether diol with 55 parts by weight of 4,4'- MDI and 5 parts by weight of DOP were mixed uniformly in the reactor, and then reacted at 90°C for 3 hours to obtain component A;
[0056] 50 parts by weight of D-2000 and 30 parts by weight of Ethacure300 were dehydrated for 1.5 hours at a temperature of 110°C and a pressure of 0.05 MPa, and then the dehydrated D-2000, dehydrated Ethacure300 and 8 parts by weight of organic hypophosphorous acid Aluminum, 1 part by weight of polytetrafluoroethylene, 8 parts by weight of ammonium polyphosphate, and 3 parts by weight of dipentaerythritol were uniformly mixed in a reactor, and stirred at 90° C. for 1.5 hours to obtai...
Embodiment 2
[0063] The contents of each raw material in component A and component B in this embodiment are shown in Table 2.
[0064] (1) Preparation of polyurea resin:
[0065] Dehydrate 50 parts by weight of siloxane polyether diol at a temperature of 110°C and a pressure of 0.02 MPa for 2 hours, then mix the dehydrated siloxane polyether diol with 45 parts by weight of 4,4'- MDI and 5 parts by weight of DBP were mixed uniformly in the reactor, and then reacted at 85°C for 3 hours to obtain component A;
[0066] 50 parts by weight of D-2000 and 30 parts by weight of Unilink4200 were dehydrated for 2 hours at a temperature of 110°C and a pressure of 0.05 MPa, and then the dehydrated D-2000, dehydrated Unilink4200 and 6 parts by weight of organic aluminum hypophosphite , 1 part by weight of polytetrafluoroethylene, 12 parts by weight of ammonium polyphosphate, and 1 part by weight of dipentaerythritol were mixed uniformly in a reaction kettle, and stirred at 100° C. for 1 hour to obtain ...
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