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A kind of hydrolysis-resistant electrospun PVA/glycerol crosslinked nanofiber membrane and preparation method thereof

A nanofiber membrane, anti-hydrolysis technology, applied in fiber processing, filament/thread forming, textiles and papermaking, etc., can solve problems such as water swelling, electrospun membrane filtration effect, etc., to increase hydrolysis resistance, mechanical High performance and improved mechanical properties

Active Publication Date: 2021-02-19
重庆中纳科技有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, water-soluble polymer nanofibers often have the problem of swelling or even hydrolysis when encountering water, and the filtration efficiency of its electrospun membrane is seriously affected by temperature and humidity. Therefore, it is necessary to cross-link and modify the nanofiber membrane to improve its hydrolysis resistance.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0025] A preparation method of an anti-hydrolysis electrospun PVA / glycerol crosslinked nanofiber membrane, comprising the steps:

[0026] The first step is to prepare the PVA aqueous solution: accurately weigh 1.0 g of PVA (molecular weight: 70,000, degree of alcoholysis 89%) and dissolve it in 9.0 g of deionized water, stir magnetically for 3 hours in a water bath at 80°C, and then in a water bath at 20°C Under the condition of magnetic stirring for 30 minutes, the stirring speed is 200r / min, and the uniform and transparent PVA aqueous solution with a mass fraction of 10% is prepared.

[0027] The second step is to add the crosslinking agent glycerin: accurately weigh 1.0 g of glycerin (analytical grade) and 9.0 g of deionized water, add it to the PVA aqueous solution described in the first step, and magnetically stir for 5 h under the condition of a water bath at 20 ° C. The magnetic stirring speed is 80r / min, and a uniform and transparent PVA / glycerol spinning solution with...

Embodiment 2

[0032] A preparation method of an anti-hydrolysis electrospun PVA / glycerol crosslinked nanofiber membrane, comprising the steps:

[0033] Step 1: Accurately weigh 1.5g of PVA (molecular weight 80,000, degree of alcoholysis 77%) and dissolve it in 8.5g of deionized water, stir magnetically for 4 hours in a water bath at 85°C, and stir magnetically for 30 minutes in a water bath at 25°C , the stirring speed is 100r / min, and the uniform transparent PVA aqueous solution with a mass fraction of 15% is prepared.

[0034] The second step is to add the crosslinking agent glycerin: accurately weigh 1.5g of glycerin (analytical grade) and 8.5g of deionized water, add it to the PVA aqueous solution described in the first step, and magnetically stir for 4 hours under the condition of 25°C water bath, The magnetic stirring speed is 100r / min, and a uniform transparent PVA / glycerol spinning solution with a total mass fraction of 15% is prepared.

[0035] Step 3: Prepare the prepared spinnin...

Embodiment 3

[0039] A preparation method of an anti-hydrolysis electrospun PVA / glycerol crosslinked nanofiber membrane, comprising the steps:

[0040] The first step is to prepare the PVA aqueous solution: accurately weigh 2g of PVA (molecular weight 74800, degree of alcoholysis 98%) and dissolve it in 8g of deionized water, stir magnetically for 4 hours in a water bath at 90°C, and stir magnetically in a water bath at 30°C For 30 minutes, the stirring speed was 300r / min, and a uniform transparent PVA aqueous solution with a mass fraction of 20% was prepared.

[0041] The second step is to add a cross-linking agent: accurately weigh 2g of glycerin (analytical grade) and 8g of deionized water, add it to the PVA aqueous solution described in the first step, and stir magnetically for 2 hours in a water bath at 30°C. The speed is 120r / min, and a uniform transparent PVA / glycerin spinning solution with a mass fraction of 20% is prepared.

[0042]The third step, electrospinning: the prepared spi...

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Abstract

The invention relates to a hydrolysis-resistant electrospun PVA / glycerol crosslinked nanofiber membrane and a preparation method thereof, wherein the preparation method comprises the following steps: (1) preparing a PVA aqueous solution with a mass fraction of 10-20%; Adding glycerin aqueous solution to the aqueous solution and mixing to obtain a PVA / glycerin spinning solution; (3) forming nanofibers from the PVA / glycerol spinning solution on an electrospinning device to obtain an electrospun membrane; (4) forming the obtained electrospun membrane Heat treatment, that is. The beneficial effect is that the obtained PVA / glycerin nanofiber membrane no longer swells and hydrolyzes in hot water at 70-90°C, effectively increases the hydrolysis resistance and improves the mechanical properties; it can be used for PM2.5 protective masks, screen windows, Indoor air filters, air purifiers, fresh air systems, tap water filtration, leukocyte blood filtration, etc., are resistant to hydrolysis and do not contain organic solvents, are non-toxic and environmentally friendly, and have stable structural properties.

Description

technical field [0001] The invention belongs to the technical field of electrospinning, and in particular relates to a hydrolysis-resistant electrospun PVA / glycerin cross-linked nanofiber membrane and a preparation method thereof, and the involved nanofiber membrane is a hydrolysis-resistant nanofiber-based filter material. Background technique [0002] In recent years, rapid urbanization and industrialization have led to severe air pollution, seriously affecting people's health and quality of life, especially dust particles (PM2. The important cause of haze weather is also one of the main factors leading to respiratory diseases and cardiovascular diseases, so effective protection against it is imminent. Traditional air filtration technology mainly adopts melt-blown electrostatic electret nonwoven technology, the initial filtration efficiency can reach 90-99%, and the resistance is relatively low, but the filtration effect changes drastically with time, temperature and humid...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): D04H1/728D04H1/545D01D5/00D01D1/06
CPCD01D1/065D01D5/0092D04H1/545D04H1/728
Inventor 刘延波杨大祥任倩
Owner 重庆中纳科技有限公司