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Water-based curing agent, water-based epoxy resin composition and its application in high-permeability waterproof and reinforced coatings

A water-based epoxy resin and water-based curing agent technology, used in epoxy resin coatings, coatings, etc., can solve the problems of high molecular weight of the curing agent, high shear force, high emulsion viscosity, etc., to achieve high worker acceptance, increase The effect of rebound strength and convenient construction

Active Publication Date: 2020-03-27
江苏丰彩建材(集团)有限公司 +2
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

For example, the document "Synthesis and Performance Research of Non-ionic Waterborne Epoxy Resin Curing Agent" ( painted Materials Industry, 2010, 40(10): 47-50. ) must use a polyether structure with a molecular weight of 4000, and the amount used has reached half of the amount of epoxy resin, so that the final synthetic curing agent has a larger molecular weight and higher viscosity, and high shear force is required when emulsifying epoxy resin. The water dilutability of the formed emulsion is relatively poor, resulting in a higher viscosity of the emulsion at the same solid content
It should be noted that although the molecular weight of the curing agent is closely related to its own viscosity, it is not the only factor determining the viscosity of the formed emulsion. That is to say, even if the molecular weight and viscosity of the curing agent are small, its water dilutability may not be sufficient Satisfactory, resulting in higher emulsion viscosity at the same solid content
In addition, due to the high surface tension of water, the wetting of water-based epoxy resin materials to the substrate is relatively poor, and the permeability is far inferior to solvent-based products.

Method used

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  • Water-based curing agent, water-based epoxy resin composition and its application in high-permeability waterproof and reinforced coatings
  • Water-based curing agent, water-based epoxy resin composition and its application in high-permeability waterproof and reinforced coatings
  • Water-based curing agent, water-based epoxy resin composition and its application in high-permeability waterproof and reinforced coatings

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0058] A preparation method of waterborne epoxy resin composition, comprises the following steps:

[0059] Put 100 parts by weight of E51 bisphenol A type epoxy resin and 10 parts by weight of butyl glycidyl ether into a stirring tank, stir evenly, and then discharge and pack to obtain component A;

[0060] Preparation of water-based curing agent: mix 1mol phenol and 0.8mol polyetheramine Put it in the reactor and raise the temperature to 45°C; after the phenol and polyetheramine are stirred evenly, add 37% formaldehyde solution in an equimolar amount to polyetheramine M1000 dropwise at a temperature of 45-80°C for 1 hour; dropwise After the addition is complete, keep it warm for 1 hour; then add 0.9 mol of ethylenediamine into the above reactor, stir evenly, and drop 1.1 mol of 37% formaldehyde solution (1.2 times the molar weight of ethylenediamine) at a temperature of 45 to 80°C ), the dropwise addition time was 1.5h; after the dropwise addition, the insulation reaction w...

Embodiment 2

[0064] A preparation method of waterborne epoxy resin composition, comprises the following steps:

[0065] Put 100 parts by weight of E44 bisphenol A type epoxy resin and 20 parts by weight of C12-14 alkyl glycidyl ether into a stirring tank, stir evenly, and then discharge and package to obtain component A.

[0066] Preparation of water-based curing agent: mix 1mol phenol and 0.9mol polyetheramine Put it in the reactor and raise the temperature to 60°C; after the phenol and polyetheramine are stirred evenly, add 37% formaldehyde solution in an equimolar amount to polyetheramine M1000 dropwise at a temperature of 60-80°C for 1 hour; dropwise After the addition is complete, keep warm for 1 hour; then add 0.8 mol of triethylenetetramine into the above-mentioned reactor, and after stirring evenly, add 1 mol of 37% formaldehyde solution dropwise at a temperature of 60-80°C for 1.5 hours; After adding, keep warm for 1 hour; finally add tap water to dilute until the solid content ...

Embodiment 3

[0070] A preparation method of waterborne epoxy resin composition, comprises the following steps:

[0071] Put 100 parts by weight of DER 354 bisphenol F type epoxy resin and 5 parts by weight of benyl glycidyl ether into a stirred tank, stir evenly, and then discharge and pack to obtain component A;

[0072] Preparation of water-based curing agent: mix 1mol phenol and 1mol polyetheramine Put it in the reactor and raise the temperature to 70°C; after the phenol and polyetheramine are stirred evenly, add 37% formaldehyde solution in an equimolar amount to polyetheramine M1000 dropwise at a temperature of 70-80°C for 1 hour; dropwise After the addition is complete, keep it warm for 1 hour; then add 1.1 mol of m-xylylenediamine into the above reactor, stir evenly, then add 1.2 mol of 37% formaldehyde solution dropwise at a temperature of 45-80°C for 1.5 hours After the dropwise addition, keep warm for 1 hour; finally add tap water to dilute until the solid content is 50% and th...

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Abstract

The invention provides an aqueous curing agent and a waterborne epoxy resin composition, and an application thereof in a high-permeability waterproof reinforcing coating. The waterborne epoxy resin composition comprises, by weight, 100 parts of epoxy resin, 5-30 parts of a reactive diluent, 130-170 parts of an aqueous curing agent and 1-5 parts of a permeation enhancer. The aqueous curing agent isprepared through a reaction of phenol, polyetheramine, polyamine and formaldehyde according to a molar ratio of the phenol to the polyetheramine to the polyamine of 1:(0.8-1):(0.8-1.5), and is obtained through the following steps: performing a primary Mannich reaction on the phenol, polyetheramine and a first part of formaldehyde same to the polyetheramine in molar weight; and performing a secondary Mannich reaction on the remaining phenol, the obtained polyetheramine-phenol reaction product, the polyamine compound and a second part of formaldehyde, wherein a molar ratio of the polyamine compound to the second part of formaldehyde is 1:(1-1.2); and the molecular weight of the polyetheramine is 1000 to 2100.

Description

technical field [0001] The invention relates to a water-based curing agent, a water-based epoxy resin composition and an application thereof in high-permeability waterproof reinforcing coatings. Background technique [0002] As we all know, ordinary concrete will have fine voids and cracks. Water will enter the interior of the concrete through these tiny gaps and cracks, causing corrosion and deterioration of the concrete. At present, pasting waterproof membranes and painting waterproof coatings on the outside of concrete can realize the waterproof and anti-seepage function of concrete and prolong the service life of concrete. However, it is not uncommon for membranes or coatings to fail waterproofing due to bonding failure, especially on highways. In interval tunnels such as railways, subways, and high-speed rails, maintenance is very difficult, which greatly wastes financial and material resources. [0003] Epoxy resin is widely used in the field of concrete waterproofin...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C09D163/02C09D7/20C08G59/62
CPCC08G59/623C09D163/00
Inventor 冉千平周进俊尹浩孙德文李波万赟刘玉亭刘娜
Owner 江苏丰彩建材(集团)有限公司
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