Preparation method of mass spectrum model for detecting insulin resistance
A technology for insulin resistance, mass spectrometry model, applied in chemical instruments and methods, measurement devices, animal/human peptides, etc., to achieve reasonable and feasible design
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Embodiment 1
[0047] Embodiment 1. Materials and methods for establishing insulin resistance model
[0048] 1. Samples and instruments:
[0049] A total of 439 cases of serum samples, 288 cases as a training group, 151 cases as a blind sample group. There were 140 cases of insulin resistance in the training group and 148 cases in the normal group. The detailed sample characteristics are shown in Table 1. The number of insulin resistance and normal groups in the blind selection sample group is temporarily unknown. All serum samples were drawn in the morning on an empty stomach, and the serum was separated and stored in a ‐80°C low-temperature refrigerator.
[0050] Matrix-assisted laser desorption time-of-flight mass spectrometry CLIN-TOF and the WCX magnetic bead kit used in the experiment were developed by Bioyong Company of China. The data analysis software Bioexplorer of Bioyong Company was used to preprocess the data, and the processed data was processed by the statistical analysis ...
Embodiment 2
[0069] Embodiment 2, screening the characteristic polypeptide of insulin resistance
Embodiment 3
[0076] Example 3, Identification of Insulin Resistance Characteristic Polypeptides
[0077] Magnetic bead enrichment method
[0078] 1. After determining the peak to be identified according to Example 2, search for the sample with the highest intensity of the peak to be identified in the pre-processed samples.
[0079] 2. Obtain peptide samples according to the magnetic bead enrichment method in Case 1. Take 15 samples from each group and mix them into one tube. Centrifuge at 3000 rpm for 5 minutes. Take the supernatant on the magnetic stand and wait for the test.
[0080] Peptide sequence identification was performed using nano‐LC‐MS / MS platforms, including Aquity UPLC (Water, MA) and LTQOrbitrap XL mass spectrometer (Thermo Fisher, MA). The ion mode is positive ion mode, and the scanning range is 400-1500m / z. Sequence analysis was performed using Mascot (2.3.2) search, the precision of primary mass spectrometry was 50ppm, and the precision of secondary mass spectrometry...
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