Polymer-coating silicon/lithium metasilicate cathode material and preparation method thereof
A lithium metasilicate and negative electrode material technology, applied in battery electrodes, electrical components, circuits, etc., can solve the problems of no very effective method and poor cycle stability of micron-scale silicon-based negative electrode, and achieve high specific capacity and easy operation. and industrial production, the effect of simple preparation method
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[0025] Example 1
[0026] The polymer-coated silicon / lithium metasilicate negative electrode material proposed in this embodiment is composed of a silicon / lithium metasilicate composite material (Si / Li 2 SiO 3 ) And a polypyrrole coating layer (P) coated on the silicon / lithium metasilicate composite material, wherein the weight percentage of the silicon / lithium metasilicate composite material is 95%, and the polypyrrole coating layer The weight percentage is 5%, and its composition is [Si / Li 2 SiO 3 ] 0.95 / P 0.05 ;
[0027] The method for preparing the polymer-coated silicon / lithium metasilicate negative electrode material proposed in this embodiment includes the following steps:
[0028] S1. Preparation of silicon / lithium metasilicate composite material Si / Li 2 SiO 3 : Mix 5.0g of silicon oxide and 0.5g of lithium metal powder in an argon atmosphere by mechanical ball milling for 1 hour to obtain a silicon / lithium metasilicate composite material Si / Li 2 SiO 3 ;
[0029] S2. Preparat...
Example Embodiment
[0033] Example 2
[0034] The polymer-coated silicon / lithium metasilicate negative electrode material proposed in this embodiment is composed of a silicon / lithium metasilicate composite material (Si / Li 2 SiO 3 ) And a polyaniline coating layer (P) coated on the silicon / lithium metasilicate composite material, wherein the weight percentage of the silicon / lithium metasilicate composite material is 95%, and the polyaniline coating layer The weight percentage is 5%, and its composition is [Si / Li 2 SiO 3 ] 0.95 / P 0.05 ;
[0035] The method for preparing the polymer-coated silicon / lithium metasilicate negative electrode material proposed in this embodiment includes the following steps:
[0036] S1. Preparation of silicon / lithium metasilicate composite material Si / Li 2 SiO 3 : Mix 5.0g of silicon oxide and 0.5g of lithium metal powder in an argon atmosphere by mechanical ball milling for 1 hour to obtain a silicon / lithium metasilicate composite material Si / Li 2 SiO 3 ;
[0037] S2. Preparat...
Example Embodiment
[0039] Example 3
[0040] The polymer-coated silicon / lithium metasilicate negative electrode material proposed in this embodiment is composed of a silicon / lithium metasilicate composite material (Si / Li 2 SiO 3 ) And a polypyrrole coating layer (P) coated on the silicon / lithium metasilicate composite material, wherein the weight percentage of the silicon / lithium metasilicate composite material is 98%, and the polypyrrole coating layer The weight percentage is 2%, and its composition is [Si / Li 2 SiO 3 ] 0.98 / P 0.02 ;
[0041] The method for preparing the polymer-coated silicon / lithium metasilicate negative electrode material proposed in this embodiment includes the following steps:
[0042] S1. Preparation of silicon / lithium metasilicate composite material Si / Li 2 SiO 3 : Mix 5.0g of silicon oxide and 0.5g of lithium metal powder in an argon atmosphere by mechanical ball milling for 0.5h to obtain a silicon / lithium metasilicate composite material Si / Li 2 SiO 3 ;
[0043] S2. Preparatio...
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