Unlock instant, AI-driven research and patent intelligence for your innovation.

Heat-resistant high-strength deformation magnesium alloy and preparation method thereof

A technology for deforming magnesium alloys and magnesium alloys, applied in the field of metallurgy, can solve the problems of reduced performance, high price of rare earth elements, rising cost of magnesium alloys, etc., and achieve the effects of cost reduction, low manufacturing cost, superior room temperature strength and high temperature strength.

Inactive Publication Date: 2018-08-21
SHANGHAI OCEAN UNIV
View PDF7 Cites 3 Cited by
  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The above wrought magnesium alloys all have good room temperature performance, but because the Mg17Al12 reinforcement phase of the Mg-Al-Zn series wrought magnesium alloy will decompose when the service temperature exceeds 150 ° C, resulting in a sharp decrease in its performance, so the AZ series wrought magnesium alloy The alloy is only suitable for the use temperature below 150°C, and in many cases in the aerospace field, the use temperature of the material is required to be as high as 200-250°C. This performance defect greatly limits the use of AZ series magnesium alloys in aerospace and other fields. Applications
[0004] In recent years, studies have found that adding rare earth elements (such as Nd, Ce, Y, Gd, Dy, Tb, etc.) to magnesium alloys can effectively improve the strength of magnesium alloys, and at the same time greatly improve the heat resistance of magnesium alloys. The relatively mature commercial magnesium alloys include WE54 and WE43, but the price of rare earth elements is extremely high and they are rare elements. After the addition, the cost of these magnesium alloys rises sharply, which also greatly limits the commercial application of the addition of rare earth deformed magnesium alloys.

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
View more

Image

Smart Image Click on the blue labels to locate them in the text.
Viewing Examples
Smart Image
  • Heat-resistant high-strength deformation magnesium alloy and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

preparation example Construction

[0024] The preparation method of the heat-resistant high-strength deformed magnesium alloy of the present invention comprises the following steps:

[0025] (1) Raise the temperature of pure magnesium to 160-250°C, keep it warm for 5-15 minutes, and then melt the pure magnesium under the protection of protective gas or flame-retardant covering;

[0026] (2) Raise the temperature of pure magnesium melt to 650-800°C, raise the temperature of magnesium-calcium alloy, magnesium-copper alloy, magnesium-tin alloy, magnesium-manganese alloy and pure zinc to 160-250°C, keep it warm for 5-15 minutes, and add Into the pure magnesium melt, the added alloy and zinc are melted to make alloy melt;

[0027] (3) Skim off the scum on the surface of the melt, stir for 3-30 minutes, then raise the temperature to 750--800°C and let stand for 20-100 minutes.

[0028] (4) Cool to the casting temperature for continuous casting to prepare Mg-Sn-Cu-Zn-Ca-Mn alloy ingots, the process parameters of cont...

Embodiment 1

[0034] (1) Configure each alloy element according to the alloy composition, wherein the weight percentages of Sn, Cu, Zn, Ca, and Mn elements are respectively 5%, 0.1%, 1%, 0.1%, and 0.1%. Pure magnesium and Zn, Mg-Ca, Mg-Cu, Mg-Sn and Mg-Mn master alloys are preheated to 200°C, and then pure magnesium is placed in a SF 6 / CO 2 (2) After the pure magnesium is completely melted, add preheated Mg-Ca, Mg-Cu, Mg-Sn, Mg-Mn master alloy and pure Zn to the magnesium melt; (3 ) Skim off the scum on the surface after all the added alloying elements are melted, then stir for 10 minutes, and finally raise the temperature of the magnesium alloy melt to 780 ° C and let it stand for 60 minutes; (4) cool the magnesium alloy melt after standing to an appropriate temperature The temperature of the continuous casting billet is prepared by continuous casting. The process parameters of continuous casting are: the continuous casting speed range is 20-2000mm / min, and the continuous casting tempera...

Embodiment 2

[0036](1) Configure each alloy element according to the alloy composition, wherein the weight percentages of Sn, Cu, Zn, Ca, and Mn elements are respectively 1%, 2%, 0.1%, 4%, and 0.5%. Pure magnesium and Zn, Mg-Ca, Mg-Cu, Mg-Sn and Mg-Mn master alloys are preheated to 200°C, and then pure magnesium is placed in a SF 6 / CO 2 (2) After the pure magnesium is completely melted, add preheated Mg-Ca, Mg-Cu, Mg-Sn, Mg-Mn master alloy and pure Zn to the magnesium melt; (3 ) Skim off the scum on the surface after all the added alloying elements are melted, then stir for 10 minutes, and finally raise the temperature of the magnesium alloy melt to 780 ° C and let it stand for 60 minutes; (4) cool the magnesium alloy melt after standing to an appropriate temperature The temperature of the continuous casting billet is prepared by continuous casting. The process parameters of continuous casting are: the continuous casting speed range is 20-2000mm / min, and the continuous casting temperatur...

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More

PUM

PropertyMeasurementUnit
Room temperature tensile strengthaaaaaaaaaa
Yield strengthaaaaaaaaaa
Tensile strengthaaaaaaaaaa
Login to View More

Abstract

The invention relates to the technical field of metallurgy, in particular to a heat-resistant high-strength deformation magnesium alloy and a preparation method thereof. The magnesium alloy is prepared from the following compositional alloying elements in percentage by weight: 1 to 5 percent of tin, 0.1 to 2 percent of copper, 0.1 to 1 percent of zinc, 0.1 to 4 percent of calcium, 0.1 to 0.5 percent of manganese, and the balance of magnesium. The preparation method of the heat-resistant high-strength deformation magnesium alloy comprises the following steps: after pure magnesium is pre-heatedand molten, respectively adding intermediate alloys, such as, Mg-Sn, Mg-Cu, Mg-Mn and Mg-Ca, and Zn; refining after the added metals are molten, then, preparing a deformation blank from a refined alloy solution by adopting a continuous casting method, and finally, performing rolling, forging and pressing, extruding or composite deforming on the pretreated continuous casting blank to prepare the heat-resistant high-strength magnesium alloy. The Mg-Sn-Cu-Ca-Zn-Mn heat-resistant high-strength deformation magnesium alloy prepared by the preparation method can serve for a long time under the usingconditions of 200 to 250 DEG C, and meets the requirements of the industries, such as aeronautics and astronautics, war industry, automobiles and the like, on weight reduction; the added elements arecommon alloying elements; the manufacturing cost is low; the heat-resistant high-strength deformation magnesium alloy is applicable to industrial application.

Description

technical field [0001] The invention relates to the technical field of metallurgy, in particular to a heat-resistant high-strength deformed magnesium alloy and a preparation method thereof. Background technique [0002] Magnesium alloy is an alloy composed of magnesium and other elements. Its characteristics are: low density (about 1.8g / cm3), high strength, large elastic modulus, good heat dissipation, good shock absorption, greater impact load capacity than aluminum alloy, good corrosion resistance of organic matter and alkali, mainly used In aviation, spaceflight, transportation, chemical industry, rocket and other industrial sectors. Under the dual pressure of the world's petrochemical energy crisis and environmental pollution, weight reduction is one of the important means to achieve energy efficiency. Countries have put forward weight reduction requirements for industrial fields such as automobiles and aerospace. The density of magnesium alloys is only that of aluminum...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More

Application Information

Patent Timeline
no application Login to View More
IPC IPC(8): C22C23/00C22C1/03C22F1/06
CPCC22C23/00C22C1/03C22F1/06
Inventor 郑兴伟王世明褚振华张丽珍梁拥成高丽庄欣袁杰
Owner SHANGHAI OCEAN UNIV