Loaded phase transition type nbzrtitaal x High-entropy alloys and their preparation methods and applications
A high-entropy alloy and phase-change technology, which is applied in the field of loaded phase-change NbZrTiTaAlx high-entropy alloys, can solve the problems that brittle materials cannot withstand high-speed flight overload, and non-brittle materials cannot be fully broken, and cannot satisfy the plasticity of materials, etc. The effect of different plasticity requirements of materials, high-density and high-strength mechanical properties, high-speed bearing and impact crushing improvement
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Embodiment 1
[0053] The NbZrTiTaAl of this embodiment x The high-entropy alloy (NbZrTiTa high-entropy alloy) is composed of Nb, Zr, Ti and Ta elements, and the molar ratio of Nb, Zr, Ti and Ta is 1:1:1:1.
[0054] The NbZrTiTaAl of this embodiment x The preparation method of high entropy alloy comprises the following steps:
[0055] (1) Remove the surface scale of Nb, Zr, Ti and Ta metallurgical raw materials by mechanical means, and then accurately weigh the ratio according to the molar ratio of 1:1:1:1 (weighing with an electronic precision balance of 1 / 10,000) , the purity of each metallurgical raw material is higher than 99.9%, and then ultrasonically cleaned in industrial ethanol for 30 minutes for use in smelting alloys. The alloy composition is shown in Table 1.
[0056] (2) Use a conventional non-consumable vacuum electric arc furnace to smelt the alloy. When smelting, put the prepared metallurgical raw materials into the water-cooled copper crucible in order of melting point fro...
Embodiment 2
[0062] The NbZrTiTaAl of this embodiment x High entropy alloys (NbZrTiTaAl 0.1 ) preparation method is basically the same as the steps of Example 1, the only difference is that in step (1), the molar ratio of Ti, Zr, Nb, Ta and Al elements is 1:1:1:1:0.1, the alloy composition See Table 1. In step (2), the smelting current is 250A-650A, the current is gradually controlled to increase to 500A during smelting, and the current is increased to 650A after melting. Repeat the alloy melting process 8 times.
Embodiment 3
[0064] The NbZrTiTaAl of this embodiment x High entropy alloys (NbZrTiTaAl 0.2 ) preparation method is basically the same as the steps of Example 1, the only difference is that in step (1), the molar ratio of Ti, Zr, Nb, Ta and Al elements is 1:1:1:1:0.2, and the alloy composition See Table 1. In step (2), the smelting current is 250A-620A, the current is gradually controlled to increase to 500A during smelting, and the current is increased to 620A after melting. Repeat the alloy melting process 9 times.
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