The invention discloses titaniferous stainless steel electroslag remelting casting powder which is prepared from the raw materials in parts by weight as follows: 46.0-50.0 parts of fluorite, 20.0-24.0 parts of alumina powder, 18.5-22.5 parts of lime, 3.5-5.5 parts of fused magnesite, 2.0-4.0 parts of titanium dioxide as well as other components: 0.0-0.6 part of SiO2, 18.0-22.0 parts of CaO, 20.0-24.0 parts of Al2O3, 4.2-5.8 parts of MgO, 2.0-4.0 parts of TiO2, 45.0-51.0 parts of CaF2, less than 0.03 part of S and less than 0.03 part of C. Slag is formed by the casting powder according to strict quality control standard so as to ensure that the impurity content is low, the purity is high and the slag is dry and free from moisture. In the electroslag remelting process, desulfuration and deoxygenation effects are enhanced, the resistivity is improved, and the casting powder is free from cutoff in arcing, good in lubrication and relatively easy to popularize and apply.