A kind of water-changing and non-diffusion ink and its preparation method and application
A technology that changes color and ink when it encounters water. It is applied in the field of ink, which can solve the problems of user injury, environmental pollution, discoloration, etc., and achieve the effect of reducing the amount of use.
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Embodiment 1
[0039] An ink that changes color when exposed to water and does not spread, comprising the following raw materials in parts by weight:
[0040] 40 parts of water-based film-forming resin
[0041] Strong acid and weak alkali metal salt 0.5 parts
[0042] Charged pH indicator 0.5 parts
[0043] Polymer adsorption resin 0.5 parts
[0044] 25 parts of solvent;
[0045] Wherein, the solvent is water or a mixture of water and an organic solvent.
[0046] The water-based film-forming resin is water-based acrylate.
[0047] The metal ion of the strong acid and weak alkali metal salt is aluminum ion, specifically the strong acid and weak alkali salt is aluminum chloride.
[0048] The charged pH indicator is methyl yellow.
[0049] The polymer adsorption resin is ethylene-vinyl acetate copolymer, and the mass percentage of vinyl acetate in the ethylene-vinyl acetate copolymer is 15%.
[0050] The solvent is compounded by water and an organic solvent at a volume ratio of 4:1, and ...
Embodiment 2
[0056] The difference between this embodiment and embodiment 1 is: a kind of ink that changes color when exposed to water and does not spread, including the following raw materials in parts by weight:
[0057] 60 parts of water-based film-forming resin
[0058] Strong acid and weak alkali metal salt 5 parts
[0059] Charged pH indicator 5 parts
[0060] Polymer adsorption resin 5 parts
[0061] 45 parts of solvent;
[0062] Wherein, the solvent is water or a mixture of water and an organic solvent.
[0063] The water-based film-forming resin is water-based polyurethane resin.
[0064] The metal ion of the strong acid and weak alkali metal salt is aluminum ion, specifically aluminum sulfate.
[0065] The charged pH indicator is bromophenol blue.
[0066] The polymer adsorption resin is polyvinyl alcohol.
[0067] The solvent is compounded from water and an organic solvent at a volume ratio of 6:1, and the organic solvent is ether.
Embodiment 3
[0069] The difference between this embodiment and Embodiment 1-2 is: an ink that changes color when exposed to water and does not spread, including the following raw materials in parts by weight:
[0070] 50 parts of water-based film-forming resin
[0071] Strong acid and weak alkali metal salt 3 parts
[0072] Charged pH indicator 2.5 parts
[0073] 4 parts of polymer adsorption resin
[0074] 35 parts of solvent;
[0075] Wherein, the solvent is water or a mixture of water and an organic solvent.
[0076] The water-based film-forming resin is water-based epoxy resin.
[0077] The metal ion of the strong acid and weak alkali metal salt is aluminum ion, specifically aluminum chloride and aluminum sulfate compounded according to the molar ratio of 1:1.
[0078] The charged pH indicator is compounded by bromophenol blue and bromothymol blue according to the mass ratio of 1:1.
[0079] The polymer adsorption resin is compounded by ethylene-vinyl acetate copolymer and polyvi...
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