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Carbon fiber and glass fiber reinforced epoxy resin composite material and preparation method thereof

A composite material and glass fiber technology, applied in the direction of chemical instruments and methods, synthetic resin layered products, glass/slag layered products, etc., can solve the problem that the improvement is not large, cannot be completely replaced, and the mechanical properties of carbon fiber and glass fiber are different and other issues to achieve the effect of improving the tensile strength

Active Publication Date: 2018-09-14
JIANGSU AOSHENG COMPOSITE MATERIALS HI TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

However, there is a large difference in the mechanical properties of carbon fiber and glass fiber, resulting in uneven internal stress of the carbon fiber and glass fiber hybrid reinforced composite material, and its mechanical properties cannot meet the design requirements.
For example, patent CN201310466774.9 proposes a method for preparing a reinforced composite material using carbon fiber and glass fiber together with glass fiber. The mechanical properties of the carbon fiber and glass fiber reinforced composite material prepared by this method are comparable to those of pure glass fiber. The improvement, but the increase is not large, there is still a certain gap with pure carbon fiber reinforced materials, and it cannot completely replace the role of carbon fiber reinforced materials

Method used

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  • Carbon fiber and glass fiber reinforced epoxy resin composite material and preparation method thereof
  • Carbon fiber and glass fiber reinforced epoxy resin composite material and preparation method thereof
  • Carbon fiber and glass fiber reinforced epoxy resin composite material and preparation method thereof

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Embodiment 1~12

[0067] According to the raw materials and proportions of the bonding layer shown in Table 1, the composite material was prepared by referring to the following preparation method.

[0068] a) Fully impregnate carbon fiber C into a mixture of epoxy resin A and curing agent B with a mass ratio of 2:1 for 10 minutes, take it out, pre-cure it at 100°C and 1 MPa for 10 hours, and prepare a prepreg laminate with a thickness of 2 mm Carbon fiber reinforcement.

[0069] b) Immerse the glass fiber cloth D into the mixture of epoxy resin A and curing agent B with a mass ratio of 2:1 for 10 minutes, take it out, and pre-cure it at 100°C and 1MPa for 10 hours to prepare a prepreg laminate. 2mm thick glass fiber reinforced layer.

[0070] c) Add the inorganic microspheres corresponding to each example in Table 1 to the molten polymer liquid with a melting point of less than 110°C, stir and mix evenly so that the surface of the inorganic microspheres is covered with a layer of polymer, take...

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Abstract

The invention relates to a composite material, comprising M carbon fiber reinforcement layers, N glass fiber reinforcement layers, and bonding layer(s) arranged between the carbon fiber reinforcementlayers and the glass fiber reinforcement layers, wherein M is more than or equal to 1, N is more than or equal to 1; epoxy resin is used as matrix resin of the carbon fiber reinforcement layers and the glass fiber reinforcement layers; the bonding layer(s) is / are prepared from a polymer, polymeric microspheres and organic-inorganic composite microspheres, wherein the weight of the polymer in the bonding layer(s) accounts for 50% or above of the weight of the bonding layer(s); the polymer is a cross-linked polymer with a melting point lower than 110 DEG C; the matrix resin of the carbon fiber reinforcement layers and the glass fiber reinforcement layers is epoxy resin. The bonding layer(s) in the composite material provided by the invention improve(s) the adhesion of the carbon fiber reinforcement epoxy resin and the glass fiber reinforcement epoxy resin, so that glass fibers and carbon fibers can effectively apportion the stress when the composite material is stressed, and the tensilestrength of the carbon fiber and glass fiber hybrid reinforced material is further effectively improved.

Description

technical field [0001] The invention relates to the technical field of composite materials, in particular to a carbon fiber and glass fiber reinforced epoxy resin composite material and a preparation method. technical background [0002] Fiber materials have the characteristics of low density, high strength and modulus, high temperature resistance, and chemical corrosion resistance. They are often filled into matrix resin as reinforcing materials to prepare fiber reinforced materials, which can greatly improve the tensile strength, bending strength and impact of plastics. Strength and other mechanical properties are widely used in aerospace, transportation, sports, wind power and other fields. [0003] Among them, carbon fiber and glass fiber are mostly used. Compared with glass fiber, carbon fiber has lower density, higher strength and modulus. Carbon fiber reinforced composite materials have better performance and a wider range of applications. However, the price of carb...

Claims

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Application Information

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IPC IPC(8): C08L63/00C08K7/06C08K7/14C08J5/24C09J123/08C09J11/04C09J11/06C09J11/08C09J7/10C09J7/30B32B9/00B32B9/04B32B17/02B32B17/12B32B7/10B32B27/04B32B37/12B32B37/10B32B38/00B32B38/08
CPCB32B5/02B32B5/26B32B7/10B32B37/10B32B37/1284B32B38/00B32B38/08B32B2038/0076B32B2250/20B32B2260/023B32B2260/046B32B2262/101B32B2262/106B32B2307/54C08J5/24C08J2363/00C08K7/06C08K7/14C08L2205/18C09J11/04C09J11/06C09J11/08C09J123/0853C09J123/0869C09J7/10C09J7/30C08L63/00C08L79/08C08K7/18C08K5/14C08L25/06C08K3/36
Inventor 赵清新严兵郎鸣华何定军张林强刘成刘圣强刘腾达
Owner JIANGSU AOSHENG COMPOSITE MATERIALS HI TECH