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Establishing method of fitting model for extracting soil heavy mental by low-molecular-weight organic acid

A low-molecular-weight, method-established technology, applied in the field of agricultural biological environment, can solve problems such as unclear relationships, and achieve the effects of good controllability, low cost, and short experiment cycle

Active Publication Date: 2018-09-25
ANQING NORMAL UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, the relationship between the concentration of organic acids and the content of extracted heavy metals is still unclear.

Method used

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  • Establishing method of fitting model for extracting soil heavy mental by low-molecular-weight organic acid
  • Establishing method of fitting model for extracting soil heavy mental by low-molecular-weight organic acid
  • Establishing method of fitting model for extracting soil heavy mental by low-molecular-weight organic acid

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0040]The surface soil (0-20cm) was randomly collected from the field and placed in marked cloth bags. The soil in 10 areas was collected and marked as S1, S2, S3, S4, S5, S6, S7, S8, S9, and S10. The indoor ventilation area is naturally air-dried, and the roots and debris are picked out. After rolling with wooden sticks, they pass through a 100-mesh soil sieve, and then continue to grind them finely with an agate mortar, making them all pass through a 200-mesh sieve, and mix well. Then use the quartering method to sample and save;

[0041] The preparation of formic acid standard solution: formic acid is selected analytically pure (A.R.) reagent, and preparation concentration is 0-100mmol / L (being respectively 0mmol / L, 1mmol / L, 2mmol / L, 5mmol / L, 10mmol / L, 20mmol / L, 50mmol / L, 100mmol / L, a single formic acid standard solution with 8 concentration gradients in total), after the preparation is completed, mark for subsequent use;

[0042] Extraction and detection of formic acid to...

Embodiment 2

[0049] The surface soil (0-20cm) was randomly collected from the field and placed in marked cloth bags. The soil in 10 areas was collected and marked as S1, S2, S3, S4, S5, S6, S7, S8, S9, and S10. The indoor ventilation area is naturally air-dried, and the roots and debris are picked out. After rolling with wooden sticks, they pass through a 100-mesh soil sieve, and then continue to grind them finely with an agate mortar, making them all pass through a 200-mesh sieve, and mix well. Then use the quartering method to sample and save;

[0050] The preparation of formic acid standard solution: formic acid is selected analytically pure (A.R.) reagent, and preparation concentration is 0-100mmol / L (being respectively 0mmol / L, 1mmol / L, 2mmol / L, 5mmol / L, 10mmol / L, 20mmol / L, 50mmol / L, 100mmol / L, a single formic acid standard solution with 8 concentration gradients in total), after the preparation is completed, mark for subsequent use;

[0051] Extraction and detection of formic acid t...

Embodiment 3

[0058] The surface soil (0-20cm) was randomly collected from the field and placed in marked cloth bags. The soil in 10 areas was collected and marked as S1, S2, S3, S4, S5, S6, S7, S8, S9, and S10. The indoor ventilation area is naturally air-dried, and the roots and debris are picked out. After rolling with wooden sticks, they pass through a 100-mesh soil sieve, and then continue to grind them finely with an agate mortar, making them all pass through a 200-mesh sieve, and mix well. Then use the quartering method to sample and save;

[0059] The preparation of formic acid standard solution: formic acid is selected analytically pure (A.R.) reagent, and preparation concentration is 0-100mmol / L (being respectively 0mmol / L, 1mmol / L, 2mmol / L, 5mmol / L, 10mmol / L, 20mmol / L, 50mmol / L, 100mmol / L, a single formic acid standard solution with 8 concentration gradients in total), after the preparation is completed, mark for subsequent use;

[0060] Extraction and detection of formic acid t...

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Abstract

The invention discloses an establishing method of a fitting model for extracting soil heavy mental by low-molecular-weight organic acid, comprising the steps of collecting a soil sample, air drying and sieving; preparing a low-molecular-weight organic acid standard solution; extracting the soil heavy mental by the low-molecular-weight organic acid and detecting; establishing a model for extractingthe soil heavy mental by the low-molecular-weight organic acid; determining an organic acid concentration threshold value at the maximum extracting amount of the soil heavy mental. The establishing method can quantitatively characterize the extracting capability of the low-molecular-weight organic acid to the soil heavy mental, and extraction results of different soil have comparability; the experimental period is short, the cost is low, and the popularization is facilitated; the method provided by the invention can be used for detecting in a laboratory without being limited by any conditionsof time and place, and the controllability is better; the method provided by the invention can be used for determining the organic acid concentration threshold value for extracting the soil heavy mental, and when being applied to repair of farmland heavy metal contaminated soil, better operability can be realized, the cost is low, and great promotional value is achieved.

Description

technical field [0001] The invention relates to the technical field of agricultural biological environment, in particular to a method for establishing a fitting model for extracting soil heavy metals with low-molecular-weight organic acids. Background technique [0002] Low-molecular-weight organic acids refer to carbon-chain aliphatic organic compounds that mainly contain carbon, hydrogen, and oxygen elements, have a relative molecular mass below 200, and contain at least one carboxyl group (-COOH), such as formic acid, acetic acid, malic acid, citric acid, Oxalic acid, etc., these organic acids are synthesized, transported, transformed and secreted at the plant-soil interface, absorb plant nutrients and activate soil nutrients, absorb and desorb heavy metals, and form soil, and many other plant-soil interface processes It is an adaptive response of plants to environmental stress. [0003] Heavy metals refer to relative density greater than 5g / cm 3 elements above. There ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): G01N21/31G01N1/28
CPCG01N1/28G01N21/3103
Inventor 赵宽周葆华金宝石操璟璟寇乐勇安乐生王强张小茜陈茜张群
Owner ANQING NORMAL UNIV