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Oil-based polyurethane polishing agent used for leather and preparation method of polishing agent

A technology of oily polyurethane and polishing agent, which is applied in the direction of polishing composition, leather surface treatment, chemical instruments and methods, etc. It can solve the problems of poor polishing ability, inability to undergo embossing treatment, whitening of leather surface, etc., and achieve strong polishing ability , Improve production speed and output, and improve oil penetration

Pending Publication Date: 2018-09-28
QINGYUAN BANGTAI NEW MATERIAL CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The polishing agent based on nitrocellulose in the market cannot withstand high temperature, so it cannot be embossed at all, and after being wiped with white electric oil or water softening treatment, the surface will lose gloss, fade, and the color will turn gray. The surface of the leather treated with nitrocellulose polishing agent appears whitening and top whitening
At present, there are polyurethane polishing agents on the market, but their oil penetration is worse than that of nitrocellulose polishing agents, and polyurethane polishing agents have poor polishing ability because of their strong coating powder performance.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0026] The method for preparing oily polyurethane polishing agent of the present invention:

[0027] (1) Stir 10 parts by weight of dimethylformamide, 6 parts by weight of polycaprolactone with a molecular weight of 2000, 6 parts by weight of neopentyl glycol, 0.05 parts by weight of antioxidant and 1 part by weight of ethylene glycol at 30°C React for 30 minutes;

[0028] (2) First add 3.2 parts by weight of diphenylmethane diisocyanate, stir and react at 80°C for 1.5 hours, then add 0.8 parts by weight of diphenylmethane diisocyanate, stir and react at 80°C for 1 hour, and then lower the temperature;

[0029] (3) Add 2 parts by weight of dimethylformamide, continue to stir and cool down;

[0030] (4) Add 0.05 parts by weight of diphenylmethane diisocyanate and stir for reaction, and take an appropriate amount of sample to detect a viscosity of 1.8W Pa.s;

[0031] (5) Add 8 parts by weight of cyclohexanone and 2 parts by weight of benzyl silicone oil, and keep stirring to c...

Embodiment 2

[0037] The method for preparing oily polyurethane polishing agent of the present invention:

[0038] (1) 10.331 parts by weight of dimethylformamide, 5.657 parts by weight of polycaprolactone of 2000 molecular weight, 5,879 parts by weight of neopentyl glycol, 0.037 parts by weight of antioxidant and 0.67 parts by weight of ethylene glycol at 40 ° C Stirring reaction was carried out for 30 minutes;

[0039] (2) First add 3.542 parts by weight of diphenylmethane diisocyanate, stir and react at 80°C for 1.5 hours, then add 0.885 parts by weight of diphenylmethane diisocyanate, stir and react at 80°C for 1 hour, and then lower the temperature;

[0040] (3) Add 2.459 parts by weight of dimethylformamide, and keep stirring to cool down;

[0041] (4) Add 0.061 parts by weight of diphenylmethane diisocyanate in sections and stir for reaction, take an appropriate amount of sample to detect a viscosity of 1.9W Pa.s;

[0042] (5) Add 7.379 parts by weight of cyclohexanone and 2.459 pa...

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PUM

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Abstract

The invention belongs to the technical field of leather treatment agents, and particularly relates to an oil-based polyurethane polishing agent used for leather. The polishing agent is composed of dimethylformamide, polycaprolactone, neopentyl glycol, an antioxidant, ethylene glycol, diphenyl methane diisocyanate, cyclohexanone, phenylmethyl silicone oil, butanone, diacetone alcohol and white carbon black. The invention also discloses a preparation method of the oil-based polyurethane polishing agent used for the leather. The oil-based polyurethane polishing agent used for the leather providedby the invention overcomes the problems that a nitrocotton polishing agent on a current market cannot be embossed, the surface loses a gloss after being wiped by n-hexane or rubbed by water, and theleather surface has a white crease and a white top, and has better oil permeability and stronger polishing ability

Description

technical field [0001] The invention belongs to the technical field of leather treatment agents, and in particular relates to an oily polyurethane polishing agent for leather and a preparation method thereof. Background technique [0002] At present, the surface treatment methods of leather products including bags, clothing, shoes, etc. are various, and the effect styles are varied. No matter in surface effect or in feel, the imitation leather effect is still pursued. Before the leather is used, its surface needs to be polished to remove stains, scratches, etc. on the surface, and to make the surface look brighter. The use of polishing agent can improve the quality of leather products by leaps and bounds. As a leather top coating material, leather polishing agent has a vital impact on the appearance, hygienic performance and physical and mechanical properties of leather. The polishing agent based on nitrocellulose in the market cannot withstand high temperature, so it canno...

Claims

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Application Information

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IPC IPC(8): C09G1/16C14C11/00
CPCC09G1/16C14C11/006
Inventor 王延冰刘武勤黄望柱
Owner QINGYUAN BANGTAI NEW MATERIAL CO LTD
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