Metal antirust agent meeting spraying adhesion and preparation method of metal antirust agent
A metal rust inhibitor and adhesion technology, applied in the direction of metal material coating process, coating, anti-corrosion coating, etc., can solve the problems of great environmental hazards, affecting the performance and quality of workpieces, and hazards to the health of operators, and achieve safety performance guarantee, good resistance to corrosive media, and the effect of increasing rust resistance
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Embodiment 1
[0033]In this embodiment, the metal antirust agent that meets the spraying adhesion is prepared from raw materials including the following components and parts by weight: 24 parts of polyquaternium-hyperbranched benzimidazole block polymer, 15 parts of polyacrylate , 6 parts of surfactant, 1 part of organic phosphonic acid compound, 6 parts of ferrocene, 6 parts of defoamer, 4 parts of hydroxypropyl methylcellulose, 1 part of pH regulator and 82 parts of deionized water.
[0034] Wherein, the preparation method of polyquaternium-hyperbranched benzimidazole block polymer comprises the following steps:
[0035] Step (A): Add 0.06 mol of 1,12-dibromododecane, 0.084 mol of 1,4-dimethylpiperazine and 75 ml of dimethyl sulfoxide into a 1000 ml dry three-necked flask. After reacting for 3 hours, add 0.002mol of N-methylimidazole and 0.002mol of N-methylmorpholine, react at 55°C for 3 hours, and distill off the solvent under reduced pressure to obtain polyquaternium salt;
[0036] St...
Embodiment 2
[0045] This embodiment satisfies the metal antirust agent of spraying adhesion, prepared from the raw materials comprising the following components and parts by weight: polyquaternium salt-hyperbranched benzimidazole block polymer 26 parts, polyacrylate 12 parts , 7 parts of surfactant, 1.2 parts of organic phosphonic acid compound, 5.8 parts of ferrocene, 7 parts of defoamer, 5 parts of hydroxypropyl methylcellulose, 0.8 part of pH regulator and 78 parts of deionized water.
[0046] Wherein, the preparation method of polyquaternium-hyperbranched benzimidazole block polymer comprises the following steps:
[0047] Step (A): Add 0.1 mol of 1,12-dibromododecane, 0.092 mol of 1,4-dimethylpiperazine and 85 ml of dimethyl sulfoxide into a 1000 ml dry three-neck flask. After reacting for 6 hours, add 0.0022mol of N-methylimidazole and 0.0022mol of N-methylmorpholine, react at 45°C for 6 hours, and distill the solvent under reduced pressure to obtain polyquaternium salt;
[0048] Ste...
Embodiment 3
[0057] In this embodiment, the metal antirust agent that meets the spraying adhesion is prepared from raw materials including the following components and parts by weight: 21 parts of polyquaternium-hyperbranched benzimidazole block polymer, 13 parts of polyacrylate , 5 parts of surfactant, 0.6 part of organic phosphonic acid compound, 4.4 parts of ferrocene, 5 parts of defoamer, 4 parts of hydroxypropyl methylcellulose, 0.5 part of pH regulator and 74 parts of deionized water.
[0058] Wherein, the preparation method of polyquaternium-hyperbranched benzimidazole block polymer comprises the following steps:
[0059] Step (A): Add 0.08 mol of 1,12-dibromododecane, 0.09 mol of 1,4-dimethylpiperazine and 90 ml of dimethyl sulfoxide into a 1000 ml dry three-necked flask. After reacting for 5 hours, add 0.0025mol of N-methylimidazole and 0.0025mol of N-methylmorpholine, react at 52°C for 5 hours, and distill the solvent under reduced pressure to obtain polyquaternium salt;
[0060...
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