Flame-retarded lubricating grease and preparation method thereof

A grease, flame-retardant technology, applied in the field of flame-retardant grease and its preparation, can solve the problems of easy blockage of pipelines, inability to solve the problems of self-ignition of grease by heat, lack of oil lubrication in machinery, etc., and achieves long service life and excellent mechanical properties. Stable, low cost effect

Active Publication Date: 2010-01-06
无锡中石油润滑脂有限责任公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0005] In Japanese Patent No. 29999533, No. 4-202497, it is disclosed that solid powder and other flame retardant compounds are added to the grease, but it is easy to block the pipeline during use and cause mechanical oil shortage lubrication
my country's patent ZL200610198455, 3 (applied by Japan Collaborative Grease) discloses adding extreme pressure additives to lithium-based grease to make it a self-extinguishing grease composition, but it still cannot solve the problem of spontaneous combustion of grease when heated, and it is stipulated that within 300 seconds Turn off the flame, if once the grease catches fire, it will spread quickly, causing the surrounding items to burn

Method used

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  • Flame-retarded lubricating grease and preparation method thereof
  • Flame-retarded lubricating grease and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0029] Embodiment 1: The preparation method of a kind of flame-retardant lubricating grease of the present invention adopts the following process steps:

[0030] 1. Fatty acid calcium soap is formed by the reaction of lauryl hydroxystearic acid, calcium hydroxide and water:

[0031] Heat 180g of water to 90°C, add 16.8g of dodecyl hydroxystearic acid, add 2.1g of calcium hydroxide after the lauryl hydroxystearic acid is melted, saponify for 1 hour, stir evenly, take a sample and measure it with a phenolphthalein indicator to show a reddish color It is alkaline, keep it warm for 0.8 hours at 95°C, put it in a container to dry, and set it aside.

[0032] 2. Lithium fatty acid soap is generated by the reaction of lauryl hydroxystearic acid, lithium hydroxide and water:

[0033] Heat 650g of water to 90°C, add 100.8g of lauryl hydroxystearic acid, add 8.4g of lithium hydroxide after the lauryl hydroxystearic acid is melted, saponify for 1 hour, stir evenly, take samples and measu...

Embodiment 2

[0037] Embodiment two: the preparation method of a kind of flame-retardant lubricating grease of the present invention adopts following process step:

[0038] 1. Fatty acid calcium soap is formed by the reaction of lauryl hydroxystearic acid, calcium hydroxide and water:

[0039] Heat 118g of water to 95°C, add 10.5g of dodecyl hydroxystearic acid, add 1.3g of calcium hydroxide after the lauryl hydroxystearic acid is melted, saponify for 1.25 hours, stir evenly, take a sample and measure it with a phenolphthalein indicator to show a reddish color It is alkaline, keep it warm for 1 hour at a temperature of 100°C, put it in a container to dry, and set it aside.

[0040] 2. Lithium fatty acid soap is generated by the reaction of lauryl hydroxystearic acid, lithium hydroxide and water:

[0041] Heat 450g of water to 95°C, add 62.4g of dodecyl hydroxystearic acid, add 5.2g of lithium hydroxide after the lauryl hydroxystearic acid is melted, saponify for 1.25 hours, stir evenly, take...

example 3

[0045] Example three: the preparation method of a kind of flame-retardant lubricating grease of the present invention, adopts following process steps:

[0046] 1. Fatty acid calcium soap is formed by the reaction of lauryl hydroxystearic acid, calcium hydroxide and water:

[0047] Heat 75g of water to 100°C, add 7.6g of dodecyl hydroxystearic acid, add 0.95g of calcium hydroxide after the dodecyl hydroxystearic acid is melted, saponify for 1.5 hours, stir evenly, take a sample and measure it with a phenolphthalein indicator to show a reddish color It is alkaline, keep it warm for 1.2 hours at 105°C, put it in a container to dry, and set it aside.

[0048] 2. Lithium fatty acid soap is generated by the reaction of lauryl hydroxystearic acid, lithium hydroxide and water:

[0049] Heat 110g of water to 100°C, add 11.4g of lauryl hydroxystearic acid, add 3.8g of lithium hydroxide after the lauryl hydroxystearic acid is melted, saponify for 1.5 hours, stir evenly, and take samples...

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PUM

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Abstract

The invention relates to flame-retarded lubricating grease and a preparation method thereof. The preparation method comprises the following technical steps: firstly, putting base oil and an inorganic thickening agent in an open reaction kettle for stirring and mixing, adding a dispersant after heating and heating again to take the mixture out of the kettle for use; secondly, mixing fatty acid calcium soap with the base oil, adding fatty acid lithium soap after heating, keeping heat, dehydrating and refining; finally, removing the materials to a middle kettle, lowering the temperature by cooling, stirring the materials with lubricating grease prepared by the inorganic thickening agent, adding an antioxidant, a flame retardant and an anti-rusting agent for homogenization and filtering to obtain finished products. The lubricating grease not only keeps various excellent properties of original general lithium grease, but also specially enhances the incombustible flame retardance of a 600 DGE C hot plate. Assessment of the properties of the flame-retarded lubricating grease shows that the flame-retarded grease lubricant has excellent mechanical stability, water resistance, lubricating property, anti-rusting property and flame retardance, long service life and low cost, and can replace general lithium grease used in coal mine, subway, metallurgy and other industries at present.

Description

technical field [0001] The invention relates to a flame-retardant lubricating grease and a preparation method thereof, which is a semi-solid lubricant, in particular to a flame-retardant general-purpose lithium-based lubricating grease. Background technique [0002] The use of flame-retardant materials to prevent and reduce fires has attracted more and more attention from our country, especially in underground coal mines, subways, metallurgy and other industries. Others such as mining wire and cable, transport tape, and belt conveyor rollers for coal mines are gradually required to use flame-retardant materials, and technical standards have been formulated. my country's coal industry formulated the standard for belt conveyor rollers in 2006. , The non-metallic idler cylinder and buffer idler apron stipulate the technical conditions for flame retardant performance, but the grease used has not yet stipulated the flame retardant requirements. However, it is understood that my co...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C10M169/06C10M141/10C10M129/44C10M113/10C10N30/06C10N30/12
Inventor 蒋和清安华瑞刘谋
Owner 无锡中石油润滑脂有限责任公司
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