Soft high-elasticity wear-resisting electrostatic-discharge EVA (ethylene-vinyl acetate) composite foam material and preparation method thereof

An electrostatic discharge and composite foaming technology, applied in the field of sports shoe sole materials, can solve the problems of poor cushioning and rebound performance of materials, affecting the wearer's wearing comfort, affecting the wearer's experience, etc., to achieve resilience Good, improved physical and mechanical properties, good rebound performance

Inactive Publication Date: 2018-10-26
ANTA CHINA
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

In winter, due to the relatively dry weather, it is easy to generate static electricity, which seriously affects the wearer's sense of experience. In order to solve this problem, electrostatic discharge and wear-resistant EVA foam materials are usually used as the midsole and outsole of sports shoes to solve the above problems, but the current In order to meet certain wear-resisting requirements, the EVA foam material used for shoe soles is generally made of higher hardness, higher density, and poor cushioning and rebound performance.
At present, the wear-resistant EVA foam materials that are common in the market are hard in texture, the rebound is generally about 40%, and the fatigue resistance is poor. After wearing for a period of time, there will be problems such as poor recovery such as collapse. The material has good electrostatic discharge performance and a large amount of conductive carbon black is added, which significantly increases the weight of the sole, and at the same time, also significantly increases the hardness, which affects the wearing comfort of the wearer.

Method used

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  • Soft high-elasticity wear-resisting electrostatic-discharge EVA (ethylene-vinyl acetate) composite foam material and preparation method thereof

Examples

Experimental program
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Effect test

Embodiment 1

[0053] In the embodiment of the present invention, the mass ratio of the materials contained in the soft, high-elastic and electrostatically releasable EVA composite foam material is as follows:

[0054] Ethylene-vinyl acetate copolymer: 35 parts by mass

[0055] Polyolefin thermoplastic elastomer: 25 parts by mass

[0056] EPDM rubber: 20 parts by mass

[0057] Polyolefin block copolymer: 15 parts by mass

[0058] Anti-wear agent: 5 parts by mass

[0059] Graphene oxide: 1.2 parts by mass

[0060] Filler: 5 mass

[0061] Zinc oxide ZnO: 2 parts by mass

[0062] Stearic acid St: 0.5 parts by mass

[0063] Zinc stearate ZnSt: 1.0 parts by mass

[0064] Cross-linking auxiliary agent: 0.1 parts by mass

[0065] Crosslinking agent: 1.0 parts by mass

[0066] Foaming agent: 3.1 parts by mass

[0067] Among them, the model of ethylene-vinyl acetate copolymer is EVA7470M, produced by Formosa Plastics; the model of polyolefin thermoplastic elastomer is polystyrene elastomer,...

Embodiment 2

[0073] In the embodiment of the present invention, the mass ratio of the materials contained in the soft, high-elastic and electrostatically releasable EVA composite foam material is as follows:

[0074] Ethylene-vinyl acetate copolymer: 35 parts by mass

[0075] Polyolefin thermoplastic elastomer: 20 parts by mass

[0076] EPDM rubber: 18 parts by mass

[0077] Polyolefin block copolymer: 12 parts by mass

[0078] Wear-resistant agent: 6 parts by mass

[0079] Graphene oxide: 2 parts by mass

[0080] Filler: 5 parts by mass

[0081] Zinc oxide ZnO: 2 parts by mass

[0082] Stearic acid St: 0.5 parts by mass

[0083] Zinc stearate ZnSt: 0.8 parts by mass

[0084] Cross-linking auxiliary agent: 0.17 parts by mass

[0085] Crosslinking agent: 1.0 parts by mass

[0086] Foaming agent: 3.0 parts by mass

[0087] Among them, the model of ethylene-vinyl acetate copolymer is EVA265, produced by DuPont; the model of polyolefin thermoplastic elastomer is 6058, produced by Qua...

Embodiment 3

[0093] The foamed product obtained in the above implementation case is tested for physical properties, and the following comparative examples are tested: Comparative Example 1: Compared with the formula in Example 1, the use of graphene oxide is canceled, and other components and parts by mass remain unchanged , to test the physical properties of the prepared EVA composite foam material; Comparative Example 2: Using the same mass parts of conductive carbon black as the electrostatic discharge carrier to replace the graphene oxide in the formula of Example 1, other components and mass parts unchanged, test the physical properties of the prepared EVA composite foam material; the test results are shown in Table 1.

[0094] The physical property test is carried out to the EVA composite foam material obtained in the above embodiment one and embodiment two and comparative example one and comparative example two, the results are shown in Table 1, and table 1 shows two kinds of embodim...

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Abstract

The invention discloses soft high-elasticity wear-resisting electrostatic-discharge EVA (ethylene-vinyl acetate) composite foam material and a preparation method thereof. The soft high-elasticity wear-resisting electrostatic-discharge EVA composite foam material is made by material mixing, granulating and foaming; materials include, by weight, 25-50 parts of ethylene-vinyl acetate copolymer, 15-35parts of polyolefin thermoplastic elastomer, 15-25 parts of ethylene propylene diene monomer rubber, 10-20 parts of polyolefin block copolymer, 1-3 parts of graphene oxide, 3-8 parts of a wear resistant, 4-6 parts of a filling agent, 0.4-0.6 part of an activator, 0.7-1.2 parts of a crosslinking agent, 2.5-3.5 parts of a foaming agent, and 2.1-4.3 parts of aids, wherein vinyl acetate accounts for26-40% by mass of the ethylene-vinyl acetate copolymer. The soft high-elasticity wear-resisting electrostatic-discharge EVA composite foam material has good softness and comfort, excellent elasticityand excellent wear resistance, and has good electrostatic discharge performance; the preparation method of the soft high-elasticity wear-resisting electrostatic-discharge EVA composite foam material is simple and easily operable.

Description

technical field [0001] The invention relates to the field of materials for sports shoe soles, in particular to a soft, highly elastic, wear-resistant, electrostatically releasable EVA composite foaming material and a preparation method thereof. Background technique [0002] With the rapid development of the sports shoes market, people have higher and higher requirements for the wearing experience of the soles. Good functionality, softness and comfort have become a development trend. In winter, due to the relatively dry weather, it is easy to generate static electricity, which seriously affects the wearer's experience. In order to solve this problem, electrostatic discharge and wear-resistant EVA foam materials are usually used as the midsole and outsole of sports shoes to solve the above problems, but the current In order to meet certain wear-resistant requirements, the EVA foam material used for shoe soles is generally made of higher hardness, higher density, and poor cushi...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L23/08C08L53/02C08L23/16C08L53/00C08K13/02C08K3/04C08K3/22C08K5/09C08K5/098C08J9/10
CPCC08J9/0023C08J9/0061C08J9/0066C08J9/0095C08J9/103C08J2203/04C08J2323/08C08J2423/16C08J2453/00C08J2453/02
Inventor 王有承刘超苏加明
Owner ANTA CHINA
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