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Biodegradable modified polylactic acid membrane and preparation method thereof

A technology of lactic acid film and polylactic acid, applied in the field of biodegradable modified polylactic acid film and its preparation, can solve problems such as poor impact resistance, and achieve the effects of improving mechanical properties, rapid crystallization and strong processing performance

Inactive Publication Date: 2018-10-26
宁波金领新材料科技有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] Based on the above prior art, the object of the present invention is to provide a biodegradable modified polylactic acid film and its preparation method, by adding organic crystal nucleating agent, inorganic filler and soft degradable polyester to polylactic acid The biodegradable modified polylactic acid film is obtained by mixing, extruding, and film blowing, which solves the technical problems of existing polylactic acid products such as hard and brittle, poor impact resistance, etc.

Method used

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  • Biodegradable modified polylactic acid membrane and preparation method thereof

Examples

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Comparison scheme
Effect test

Embodiment 1

[0020] A biodegradable modified polylactic acid film, its raw material composition includes 50 parts of semi-crystalline L-lactic acid, 5 parts of aromatic bisamide compound, 1 part of montmorillonite, soft degradable polyester 20 parts, 0.2 parts of heat stabilizer, 1 part of plasticizer, 0.5 parts of antioxidant, 1 part of aluminum stearate and 0.5 parts of nanocellulose.

[0021] Put polylactic acid, aromatic bisamide compound, inorganic filler, soft degradable polyester, heat stabilizer, plasticizer, antioxidant, aluminum stearate and nanocellulose in a high-speed mixer according to the ratio of parts by mass. In the feeder, after uniform mixing, it is extruded and granulated by an extruder, and then blown to obtain a biodegradable modified polylactic acid film.

Embodiment 2

[0023] A biodegradable modified polylactic acid film, its raw material composition includes 60 parts of semi-crystalline L-lactic acid, 1 part of aromatic bisamide compound, TiO 2 2 parts, 1 part of soft degradable polyester, 1 part of heat stabilizer, 0.2 parts of plasticizer, 1.2 parts of antioxidant, 0.2 parts of calcium stearate and 5 parts of nanocellulose.

[0024] Put polylactic acid, aromatic bisamide compound, inorganic filler, soft degradable polyester, heat stabilizer, plasticizer, antioxidant, aluminum stearate and nanocellulose in a high-speed mixer according to the ratio of parts by mass. In the feeder, after uniform mixing, it is extruded and granulated by an extruder, and then blown to obtain a biodegradable modified polylactic acid film.

Embodiment 3

[0026] A biodegradable modified polylactic acid film, the raw material composition of which includes 55 parts of semi-crystalline L-lactic acid, 2 parts of aromatic bisamide compound, 1.5 parts of CaO, and 10 parts of soft degradable polyester according to the ratio of parts by mass , 0.5 part of heat stabilizer, 0.5 part of plasticizer, 0.8 part of antioxidant, 0.5 part of calcium stearate and 2 parts of nanocellulose.

[0027] Put polylactic acid, aromatic bisamide compound, inorganic filler, soft degradable polyester, heat stabilizer, plasticizer, antioxidant, aluminum stearate and nanocellulose in a high-speed mixer according to the ratio of parts by mass. In the feeder, after uniform mixing, it is extruded and granulated by an extruder, and then blown to obtain a biodegradable modified polylactic acid film.

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Abstract

The invention provides a biodegradable modified polylactic acid membrane, comprising, by weight, 50-60 parts of polylactic acid, 1-5 parts of an organic crystallizing nucleating agent, 1-2 parts of aninorganic filler, 1-20 parts of soft degradable polyester, 0.2-1 part of a thermal stabilizer, 0.2-1 part of a plasticizer, 0.5-1.2 parts of an antioxidant, 0.2-1 part of a lubricant, and 0.5-5 partsof nano cellulose. The above materials are added in a high-speed mixer according to the parts ratio by weight; after uniform mixing, extrusion granulating is performed with an extruder; film blowingis performed to produce the biodegradable modified polylactic acid membrane. The polylactic acid molecules in the biodegradable modified polylactic acid components can be bound quickly around the nucleating agent to allow quick crystallization; the nucleating agent and the polylactic acid molecules are well compatible during quick crystallization, so that mechanical properties of the membrane areimproved in the whole. In addition, a preparation method of the biodegradable modified polylactic acid membrane is simple, and the biodegradable modified polylactic acid membrane is good in processibility, low in cost and suitable for large-scale industrial production.

Description

technical field [0001] The invention belongs to the technical field of biological materials, and in particular relates to a biodegradable modified polylactic acid film and a preparation method thereof. Background technique [0002] In recent years, with the depletion of fossil energy, the massive discharge of industrial toxic and harmful gases, and the excessive use of non-degradable materials, the global environment has been severely damaged. Researchers all over the world are seeking new degradable materials to deal with resource and environmental crises. . Polylactic acid products are green and environmentally friendly. More importantly, they can be degraded by microorganisms when they lose their value. They have excellent biodegradability, biocompatibility and good plasticity. They are currently the most promising polymer materials. However, under normal conditions, polylactic acid products are hard and brittle, and their impact resistance is poor, which greatly restric...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L67/04C08L67/00C08L1/02C08K13/02C08K5/098C08K3/34C08J5/18
CPCC08J5/18C08J2367/04C08J2401/02C08J2467/00C08K3/346C08K5/098C08K13/02
Inventor 郑杨春庞晓峰
Owner 宁波金领新材料科技有限公司