Looking for breakthrough ideas for innovation challenges? Try Patsnap Eureka!

Hydrophobic and oil-absorption modified sponge composite material and preparation method thereof

A composite material and oil modification technology, which is applied in the field of composite materials, can solve the problems of unsuitable oil absorption, etc., and achieve the effect of improving hydrophobicity and oil absorption performance

Inactive Publication Date: 2018-11-23
李忠
View PDF7 Cites 6 Cited by
  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, most of the existing sponges are hydrophilic and not suitable for oil absorption, so it is urgent to modify them for hydrophobic and oil absorption.

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
View more

Image

Smart Image Click on the blue labels to locate them in the text.
Viewing Examples
Smart Image
  • Hydrophobic and oil-absorption modified sponge composite material and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0030] A method for preparing a hydrophobic and oil-absorbing modified sponge composite material, the specific steps are as follows:

[0031] (1) Add polyvinyl alcohol hollow microspheres to the graphene oxide aqueous solution, stir evenly, add tetraethyl orthosilicate and sodium polyacrylate, ultrasonically oscillate, add sponge to make it soak, let it stand for 20 minutes, take it out Solidification causes multiple membranes to form inside and outside the sponge;

[0032] (2) Reduction, washing, and then heating to 1300°C to remove the polyvinyl alcohol hollow microspheres, forming holes in the membrane to obtain a graphene composite sponge;

[0033] (3) Mix and stir tetrapropoxysilane, vinyltriethoxysilane and monophenylenedioctyl phosphite to make an impregnation solution, add the graphene composite sponge into the impregnation solution, immerse at 120°C for 20 minutes, take out Drain to obtain a hydrophobic and oil-absorbing modified sponge composite material.

[0034] ...

Embodiment 2

[0043] A method for preparing a hydrophobic and oil-absorbing modified sponge composite material, the specific steps are as follows:

[0044] (1) Add polyvinyl alcohol hollow microspheres to the graphene oxide aqueous solution, stir evenly, add tetraethyl orthosilicate and sodium polyacrylate, ultrasonically oscillate, add sponge to make it soak, let it stand for 30 minutes, take it out Solidification causes multiple membranes to form inside and outside the sponge;

[0045] (2) Reduction, washing, and then heating to 1400°C to remove the polyvinyl alcohol hollow microspheres, forming holes in the membrane to obtain a graphene composite sponge;

[0046] (3) Mix and stir tetrapropoxysilane, vinyltriethoxysilane and monophenylenedioctyl phosphite to make an impregnation liquid, add the graphene composite sponge into the impregnation liquid, immerse at 140°C for 30 minutes, take out Drain to obtain a hydrophobic and oil-absorbing modified sponge composite material.

[0047] Wher...

Embodiment 3

[0056] A method for preparing a hydrophobic and oil-absorbing modified sponge composite material, the specific steps are as follows:

[0057] (1) Add polyvinyl alcohol hollow microspheres to the graphene oxide aqueous solution, stir evenly, add tetraethyl orthosilicate and sodium polyacrylate, ultrasonically oscillate, add sponge to make it soak, let it stand for 20 minutes, take it out Solidification causes multiple membranes to form inside and outside the sponge;

[0058] (2) Reduction, washing, and then heating to 1400°C to remove the polyvinyl alcohol hollow microspheres, forming holes in the membrane to obtain a graphene composite sponge;

[0059] (3) Mix and stir tetrapropoxysilane, vinyltriethoxysilane and monophenylenedioctyl phosphite to make an impregnation solution, add the graphene composite sponge into the impregnation solution, immerse at 120°C for 30 minutes, take out Drain to obtain a hydrophobic and oil-absorbing modified sponge composite material.

[0060] ...

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More

PUM

No PUM Login to View More

Abstract

The invention provides a hydrophobic and oil-absorption modified sponge composite material and a preparation method thereof. The preparation method comprises the following steps of impregnating a sponge by an aqueous solution of graphene oxide added with polyvinyl alcohol hollow microspheres and a mixed solution of, tetraethoxysilane and sodium polyacrylate for the first time; enabling the tetraethoxysilane and sodium polyacrylate to react with water to form a gel matter; after condensing, forming a graphene oxide film matter with random and undetermined shapes inside and outside the sponge; reducing and heating, removing the polyvinyl alcohol hollow microspheres, and forming a plurality of pores in the film matter, so as to obtain the hydrophobic and oil-absorption modified sponge composite material; treating by an impregnating solution, so as to further improve the hydrophobic and oil-absorption properties of the product.

Description

technical field [0001] The invention relates to the technical field of composite materials, in particular to a hydrophobic and oil-absorbing modified sponge composite material and a preparation method thereof. Background technique [0002] With the development of marine transportation of crude oil, the pollution of ocean and other water resources caused by oil spills has become one of the main environmental problems that people face. Petroleum will also bring a lot of organic solvents, which not only have safety hazards such as fire and explosion, but also cause irreversible and serious harm to the environment and human health, which urgently need to be effectively contained and resolved. [0003] Using oil-absorbing materials to absorb and recover is a simple and quick sewage treatment method. Traditional oil-absorbing materials include inorganic materials, natural organic materials, and organic synthetic materials. However, the existing oil-absorbing materials generally ha...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More

Application Information

Patent Timeline
no application Login to View More
IPC IPC(8): B01J20/22B01J20/28B01J20/32C02F1/40C02F103/08
CPCB01J20/103B01J20/20B01J20/223B01J20/28045B01J20/3242C02F1/40C02F2103/08
Inventor 李忠
Owner 李忠
Who we serve
  • R&D Engineer
  • R&D Manager
  • IP Professional
Why Patsnap Eureka
  • Industry Leading Data Capabilities
  • Powerful AI technology
  • Patent DNA Extraction
Social media
Patsnap Eureka Blog
Learn More
PatSnap group products

Browse by: Latest US Patents, China's latest patents, Technical Efficacy Thesaurus, Application Domain, Technology Topic, Popular Technical Reports.

© 2024 PatSnap. All rights reserved.Legal|Privacy policy|Modern Slavery Act Transparency Statement|Sitemap|About US| Contact US: help@patsnap.com