Composite hydrogel, impermeable coiled material as well as preparation method and application of composite hydrogel, impermeable coiled material

A composite hydrogel, hydrogel technology, applied in protection devices, gaskets, buildings, etc., can solve problems such as erosion

Active Publication Date: 2018-12-11
LIAONING BENTENAI TECH DEV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] Aiming at the problem that bentonite may have erosion risk as a buffer layer material, the present invention innovatively proposes a concept of an anti-erosion isolation layer, and provides a composite hydrogel anti-seepage membrane for nuclear waste disposal isolation layer and its preparation method , aims to improve the anti-erosion ability of the buffer material of the high-level radioactive waste repository through the introduction of the isolation layer, and further improve the safety and long-term effectiveness of the high-level radioactive waste repository

Method used

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  • Composite hydrogel, impermeable coiled material as well as preparation method and application of composite hydrogel, impermeable coiled material
  • Composite hydrogel, impermeable coiled material as well as preparation method and application of composite hydrogel, impermeable coiled material

Examples

Experimental program
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Effect test

Embodiment 1

[0086] The carbon fiber with a mass fraction of 1% and the polyacrylamide with a mass fraction of 20% are fully stirred in a dry-mixing mixer to form a uniform dry-mixed polyacrylamide / carbon fiber for use. Fully mix 30% diatomaceous earth, 2% fumed silica, and 6% sodium carbonate in the reaction kettle, add 35% water, and stir and react at 60°C for 5- 6h, then add coupling agent KH-560 with a mass fraction of 1% and a mildew inhibitor sodium benzoate with a mass fraction of 0.5% in turn, stir in the reaction kettle for 1-2 hours, and mix into a uniform slurry. Add dry-mixed polyacrylamide / carbon fiber to the above uniform slurry, add 4.5% water, and then vigorously stir and shear to form a uniform hydrogel mud with a certain toughness and moderate hardness; mix the above hydrogel with moderate hardness The mud is fed into the hopper of the press, the gap between the two rollers of the press is adjusted to make the molding thickness 5mm, and the hydrogel mud is tightly pressed...

Embodiment 2

[0091] The mass fraction of 0.5% ceramic fiber and 22% mass fraction of N-methylol polyacrylamide modified condensed polyacrylamide are fully stirred in a dry mixing mixer to form a uniform dry mixing modified polyacrylamide / Ceramic fiber, spare. In the reaction kettle, 35% of bentonite and 5% of chitosan were fully mixed, 33% of water was added, and the reaction was stirred at 50 ° C for about 8 hours. The coupling agent DL602 and the antifungal agent sodium pentachlorophenate in mass fraction of 0.5% are stirred in the reaction kettle for 1-2 hours and mixed into a uniform slurry. Add dry-mixed modified polyacrylamide / ceramic fiber to the above uniform slurry, add 3.5% water, and then vigorously stir and shear to form a uniform hydrogel mud with a certain toughness and moderate hardness; The hydrogel mud is fed into the hopper of the press, and the gap between the two pressing rollers of the press is adjusted to make the molding thickness 8mm, and the hydrogel mud is tight...

Embodiment 3

[0096] Mix 1% glass fiber with mass fraction of 15% hydroxymethyl cellulose and 2% polypropylene alcohol in a dry-mixing mixer to form a uniform dry-mixed hydrogel / glass fiber, spare. In the reaction kettle, mix 45% diatomite and 2% chitosan thoroughly, add 30% water, stir and react at room temperature for 3 hours, and then add 1% coupling agent KH-550 and 0.5% antifungal agent benzoic acid in mass fraction, stir in the reaction kettle for 1-2 hours, and mix into a uniform slurry. Add uniform dry-mixed hydrogel / glass fiber to the above uniform slurry, add 3.5% water, and then vigorously stir and shear to form uniform hydrogel mud with moderate hardness with certain toughness; The hydrogel mud is fed into the hopper of the press, and the gap between the two pressing rollers of the press is adjusted to make the molding thickness 6mm, and the hydrogel mud is tightly pressed by the press to a carbon fiber braid with a thickness of 0.3mm at a uniform speed of 5m / min. Between the ...

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Abstract

The invention provides a composite hydrogel, impermeable coiled material as well as preparation method and application of composite hydrogel, impermeable coiled material, and specifically relates to acomposite hydrogel impermeable coiled materials which can be used for a nuclear waste disposal isolation layer. The impermeable coiled material is composed of a surface protective layer, the composite hydrogel, and a bottom support layer, the composite hydrogel is located between the surface protective layer and bottom support layer, the preparation method comprises the following steps: pressingfiber-reinforced hydrogel prepared from fiber, hydrogel, filler, a modification agent, a coupling agent, a mildew preventive and water between the surface protective layer and the bottom support layer, obtaining a composite hydrogel impermeable coiled material product. The impermeable coiled material prepared by the invention mainly used for coating the isolation layer of a waste liquid tank in anuclear waste disposal repository, and an isolation layer laid between a buffer layer and surrounding rock, the erosion of buffer layer material under the long-term action of groundwater can be effectively prevented, and further the radioactive nuclide is solidified, the safety and long-term effectiveness of nuclear waste disposal repositories are improved.

Description

technical field [0001] The invention belongs to the technical field of nuclear waste disposal and protection, and in particular relates to a composite hydrogel, an anti-seepage coil material and a preparation method and application thereof. Background technique [0002] As a clean, efficient and environmentally friendly energy, nuclear energy has been applied in more and more fields. While human beings enjoy the benefits of nuclear energy and vigorously develop and apply nuclear technology, the amount of nuclear waste is increasing year by year, and the safe disposal of nuclear waste has become an urgent problem to be solved. In 2011, the Fukushima nuclear accident caused by the earthquake and tsunami in Japan once again aroused the global attention to the disposal of nuclear waste. According to the classification of radioactivity level, nuclear waste is divided into low level, intermediate level and high level waste. At present, the technology for the safe disposal of low...

Claims

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Application Information

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IPC IPC(8): C08L33/26C08L97/02C08L1/28C08L29/02C08L3/02C08L5/08C08K13/04C08K7/06C08K7/26C08K3/36C08K7/04C08K7/14C08J3/075E02D31/02
CPCC08J3/075C08J2301/28C08J2329/02C08J2333/26C08J2401/28C08J2403/02C08J2405/08C08J2429/02C08J2497/02C08K3/36C08K7/04C08K7/06C08K7/14C08K7/26C08K13/04E02D31/025E02D2300/0045E02D2450/106
Inventor 张艳玲袁仁勇齐文戚丁文
Owner LIAONING BENTENAI TECH DEV
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