The invention belongs to the technical field of high
radioactive waste treatment, and relates to a high-entropy ferrite
rare earth based
perovskite ceramic solidified body and a preparation method and application thereof.The general formula of the solidified body is A1 / n (FexBy) O3, n represents the number of element types of the A lattice site of the high-entropy A1 / n (FexBy) O3 ferrite
rare earth based
perovskite ceramic solidified body, n is an integer and is larger than or equal to 3 and smaller than or equal to 7, and the A element types include Bi, Sc, La, Ce, Pr, Nd, Pm, Sm, Eu, Gd, Tb, Dy, Y, Ho, Er, Tm, Yb and Lu; m is at least three of
transition metal elements including Cr, Mn, Co, Ni, Al, Ti, Zr, Hf, Nb, Ta and Ce, x is equal to 0.01 to 1.00, and x is equal to 0 to 0.99. According to the method, a high-entropy strategy is introduced into the ferrite
rare earth perovskite ceramic solidified body, the ceramic solidified body not only can solidify various key high-radionuclides, but also has excellent
chemical stability, low
leaching rate and low preparation temperature, and the
disadvantage that ceramic solidified nuclides are high in selectivity and single is effectively avoided. Due to the excellent performance of the ceramic solidified body, the ceramic solidified body has great application potential in the field of solidification treatment of high-radioactivity nuclear waste of a spent
fuel reprocessing plant.