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A kind of electrical response dimming device and its preparation method

An electrical response and device technology, applied in instruments, optics, nonlinear optics, etc., can solve the problem of high threshold voltage of dimming glass, and achieve the effect of reducing the threshold voltage

Active Publication Date: 2022-02-18
SOUTH CHINA NORMAL UNIVERSITY +2
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, in these current technologies, especially for dimming glass with a polymer network, the network structure of the regulating region makes the dimming glass have a problem of high threshold voltage

Method used

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  • A kind of electrical response dimming device and its preparation method
  • A kind of electrical response dimming device and its preparation method
  • A kind of electrical response dimming device and its preparation method

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0036] figure 1 It is a structural schematic diagram of an electrical response light adjustment device according to an embodiment of the present invention. Such as figure 1 As shown, it includes a first light-transmitting conductive substrate 21, a second light-transmitting conductive substrate 22 and a power supply assembly 1 which are arranged oppositely. sexual connection. The sealing plastic frame 4 between the first light-transmitting conductive substrate 21 and the second light-transmitting conductive substrate 22 seals between the two light-transmitting conductive substrates to form an adjustment area 3, and the adjustment area 3 is filled with a liquid crystal mixture.

[0037] The detailed preparation steps of the electro-responsive dimming device are as follows:

[0038] (1) Prepare two light-transmitting conductive substrates. The two light-transmitting conductive substrates are composed of glass and an ITO electrode coated on one of the surfaces of the glass. On...

Embodiment 2

[0054] Comparative experiments of monoester liquid crystal monomers with different contents

[0055] Dimming devices were prepared according to the following liquid crystal monomers with different ratios. The difference in each scheme is only the internal ratio of the liquid crystal monomers, and the contents of other components are the same as those in Example 1. The specific formula is shown in the table below, where the numerical values ​​represent the percentage of each component in the total mass of the liquid crystal mixture. After the preparation is completed, parameters such as threshold voltage, saturation voltage, light transmittance, and response time of the dimming device are measured.

[0056] Table 1. Liquid crystal monomer ratio table

[0057]

[0058] Figure 5 It is a comparison diagram of the threshold voltage and saturation voltage of the dimming device in the comparative experiment of another embodiment of the present invention, the upper part is the s...

Embodiment 3

[0062] A dimming device, the difference from Example 1 is that the specific formula and ratio of the liquid crystal mixture are:

[0063] 95.8wt% negative liquid crystal, choose HNG30400-200 produced by Jiangsu Hecheng Display Technology Co., Ltd.;

[0064] 1.9wt% monoacrylate liquid crystal monomer, choose HCM-020 produced by Jiangsu Hecheng Display Technology Co., Ltd., and its structural formula is as follows:

[0065] 2wt% diacrylate liquid crystal monomer, choose HCM-009 produced by Jiangsu Hecheng Display Technology Co., Ltd., and its structural formula is as follows:

[0066]

[0067] 0.3wt% photoinitiator, select Irgacure-651 (CAS: 24650-42-8), its structural formula is as follows:

[0068] HCM-020 in this example also has only one double bond that can be opened, and polymerization reaction occurs between HCM-009 and HCM-009 under ultraviolet light irradiation, but cannot be cross-linked, and thus cannot form a continuous network. HCM-020, which cannot be cros...

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Abstract

The invention discloses an electric response dimming device with a lower threshold voltage and a preparation method thereof. An electric response dimming device, comprising two light-transmitting conductive substrates arranged oppositely, the light-transmitting conductive substrates are packaged to form an adjustment area, and the adjustment area is filled with a liquid crystal mixture, and the liquid crystal mixture includes negative liquid crystals, liquid crystal monomers and light-induced Liquid crystal monomers include diester liquid crystal monomers and monoester liquid crystal monomers. In the present invention, after the monoester liquid crystal monomer is added to the liquid crystal mixture, the formed polymer network softens, and part of the structure in the polymer network cannot form a continuous network, thereby reducing the threshold voltage.

Description

technical field [0001] The invention relates to the field of construction and household life materials, in particular to an electric response light adjustment device and a preparation method thereof. Background technique [0002] Most of the dimming glass adopts the method of coating on the glass surface. According to different reflection and light transmission requirements, films of different materials are used to reflect or transmit light of a certain band, so as to realize transmission and reflection lighting. the goal of. However, after the structure of most coating-based switchable glass is formed, its optical properties cannot be reversibly adjusted according to environmental changes or personal preferences, so it is difficult to meet the needs of the public to change the light and dark environment in the car or indoor at any time. In addition, most of the reflective materials used in coated glass are based on ion crystals doped with metal or metal oxides. Such reflec...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): G02F1/137G02F1/1333G02F1/1334
CPCG02F1/1333G02F1/1334G02F1/137G02F1/13712
Inventor 袁冬周勇赵威胡小文周国富
Owner SOUTH CHINA NORMAL UNIVERSITY