The invention relates to a piezoelectric ceramic material with high voltage electric response and a high Curie temperature and a preparation method thereof. A stoichiometric ratio accords with a chemical general formula (1-x)(K0.48Na0.52)(Nb1-ySby)O3-xBi0.5(Na0.8K0.2)0.5ZrO3; wherein x is more than or equal to 0.02 and less than or equal to 0.04, and y is more than or equal to 0.02 and less than or equal to 0.04. The preparation method comprises the following steps of: (1), preparing a base material according to the stoichiometric ratio and a sodium niobate (NaNbO3) sheet template for texturegrowth of crystal grains; (2), weighing the base material, the template and a MnO2 sintering aid according to the stoichiometric ratio, placing the weighed base material, template and MnO2 sintering aid in a nylon tank, adding a solvent, a dispersant and a binder, and uniformly stirring the mixture to obtain casting slurry with good fluidity; (3) casting the slurry to obtain a strip-shaped thick film, cutting the thick film after the thick film is dried, laminating and hot pressing the thick film into a ceramic blank body; (4) removing the blank body from the adhesive, and sintering the blankbody by using a two-step sintering process to obtain lead-free textured piezoelectric ceramic, wherein the lead-free textured piezoelectric ceramic has high piezoelectric performance and a high Curietemperature. The environment-friendly lead-free piezoelectric ceramic material has higher practical value in the fields of low and medium temperature sensors, transducers, drivers and the like.