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Physical foaming method of high polymer material and foaming product

A polymer material and physical foaming technology, applied in the field of polymer material physical foaming method and foamed products, can solve the problems of cumbersome and time-consuming process, high specific gravity, low elasticity, etc., and achieve smooth surface appearance, excellent elasticity, Energy Saving Effect

Inactive Publication Date: 2019-01-04
DONGGUAN HAILEX HIGH POLYMER MATERIAL SCI & TECH CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The traditional production of low specific gravity polyolefin chemical foaming materials requires the use of chemical foaming agents, which usually have the following disadvantages: they do not meet environmental protection requirements; there are harmful substances in the decomposition substances of foaming agents, which do not comply with relevant safety regulations
[0003] The above method of making special-shaped physical foaming materials usually has the following disadvantages: high specific gravity (about 0.4 or more), low elasticity, poor touch, and air marks on the surface that are not smooth enough, so it is not suitable for making shoe materials and those with cushioning effects. Products such as floor mats or sports equipment
In addition, the traditional production of polyolefin physical or chemical foaming products is foamed outside the mold, and then placed in the finished mold for secondary processing, the process is cumbersome and time-consuming

Method used

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Examples

Experimental program
Comparison scheme
Effect test

preparation example Construction

[0021] -Preparation of special-shaped embryos-

[0022] In the polymer material physical foaming method of the present invention, the above-mentioned raw material (thermoplastic elastomer or polyolefin material) is made into a special-shaped parison by using an injection machine, an extruder or a molding machine.

[0023] The preparation of the profiled parison can be carried out under suitable conditions. For example, for polyolefin materials that need to undergo cross-linking reaction, molding can be performed at a mold temperature of 160-180° C. and a suitable mold clamping pressure such as 10 MPa for 400-550 seconds.

[0024] The present invention has no special limitation on the shape of the special-shaped parison, and generally, the special-shaped parison can be in the shape of sheet, particle or the like.

[0025] After the shaped parison is formed, in order to increase the molecular chain strength of the polyolefin material, a crosslinking reaction can be performed on ...

Embodiment 1

[0047]With the EVA of 100phr (Formosa Plastics EVA7470, the molar content of vinyl acetate is 26%), the calcium carbonate of 1phr, the paraffin of 0.5phr and the DCP of 0.5phr in the ST-75L internal mixer of three Thai Machinery Company, in 100 ℃ and 0.75Mpa pressure conditions to mix for 12min. After unloading, the above-mentioned mixture is extruded and granulated (colloidal granules) with the extrusion granulator supporting the ST-75L internal mixer of Santai Machinery Company. The colloidal particles were molded and cross-linked at a mold temperature of 180° C. in an EVA injection machine of Jumin Machinery Co., Ltd. KM-E308L3.

[0048] Put the cross-linked polyolefin parison into an autoclave of Deyang Sichuang Company, inject carbon dioxide supercritical fluid, and maintain it at a temperature of 50°C and a pressure of 40Mpa for 2 hours. Then, release the pressure to normal pressure within 30 minutes to obtain a supercritical fluid-infiltrated parison (pre-expansion rat...

Embodiment 2

[0053] Except that the EVA / POE mixture (the molar content of the vinyl acetate of EVA is 26% wherein, and POE is the POE of Dow Chemical Company's 8150 model) that is 60 / 40 with blending ratio replaces EVA, adopts and embodiment 1. The same procedure is used to obtain the finished foamed product.

[0054] The specific gravity, cell diameter and resilience performance of the foamed product of the finished product are respectively 0.13, 0.5-1.5mm and 60%.

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Abstract

The invention relates to a physical foaming method of a high polymer material and a foaming product. The physical foaming method of the high polymer material comprises the steps that 1, a thermoplastic elastomer or a polyolefin material is prepared into special-shaped parison by using an injection molding machine, an extruding machine or a molding press; 2, the polyolefin parison is heated to produce cross-linking reaction, and the cross-linked polyolefin parison is obtained; 2, the thermoplastic elastomer parison or the cross-linked polyolefin parison is subjected to high-pressure infiltration in a pressure kettle with a supercritical fluid, then pressure relief is performed to normal pressure, and the supercritical fluid infiltrated parison is obtained; 4, the supercritical fluid infiltrated parison is arranged in a finished product mold, and in-mold foaming is performed according to the ratio of 1:1 to obtain the finished product foaming product. The supercritical fluid is utilizedas a physical foaming agent, and the low-specific-gravity, environment-friendly and non-toxic foaming material having excellent elasticity is obtained through a simple in-mold foaming process.

Description

technical field [0001] The invention relates to the field of polymer materials, in particular to a physical foaming method for polymer materials and foamed products. Background technique [0002] The foaming process is one of the commonly used processes for making low specific gravity materials. The foaming process can be divided into chemical foaming process and physical foaming process according to the foaming agent used. The traditional production of low specific gravity polyolefin chemical foaming materials requires the use of chemical foaming agents, which usually have the following disadvantages: they do not meet environmental protection requirements; there are harmful substances in the decomposition substances of foaming agents, which do not comply with relevant safety regulations. Traditionally, the main methods of making polyolefin physical foaming materials are gas-assisted injection molding, extrusion molding, etc., using alkane gases, low-volatile point compound...

Claims

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Application Information

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IPC IPC(8): C08L23/08C08L91/06C08L75/04C08K3/26C08K5/14C08J9/12
CPCC08J9/0023C08J9/0061C08J9/0066C08J9/122C08J2203/06C08J2203/08C08J2323/08C08J2375/04C08J2423/08C08J2491/06B29C44/3453B29C44/348B29C44/3488B29C44/44B29K2023/0633B29K2023/083C08J2201/026C08J2201/03C08J2300/22C08J2300/26C08J2323/02C08J2323/04C08J2323/06C08J2367/00C08J2377/00C08K3/013C08K3/26C08K5/14C08K2003/265C08L23/0853C08L71/02B29B11/06B29C44/02B29K2509/02C08J3/24C08J2205/10C08J2423/00
Inventor 罗振寰刘伏奇
Owner DONGGUAN HAILEX HIGH POLYMER MATERIAL SCI & TECH CO LTD
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