Physical foaming method of high polymer material and foaming product
A polymer material and physical foaming technology, applied in the field of polymer material physical foaming method and foamed products, can solve the problems of cumbersome and time-consuming process, high specific gravity, low elasticity, etc., and achieve smooth surface appearance, excellent elasticity, Energy Saving Effect
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[0021] -Preparation of special-shaped embryos-
[0022] In the polymer material physical foaming method of the present invention, the above-mentioned raw material (thermoplastic elastomer or polyolefin material) is made into a special-shaped parison by using an injection machine, an extruder or a molding machine.
[0023] The preparation of the profiled parison can be carried out under suitable conditions. For example, for polyolefin materials that need to undergo cross-linking reaction, molding can be performed at a mold temperature of 160-180° C. and a suitable mold clamping pressure such as 10 MPa for 400-550 seconds.
[0024] The present invention has no special limitation on the shape of the special-shaped parison, and generally, the special-shaped parison can be in the shape of sheet, particle or the like.
[0025] After the shaped parison is formed, in order to increase the molecular chain strength of the polyolefin material, a crosslinking reaction can be performed on ...
Embodiment 1
[0047]With the EVA of 100phr (Formosa Plastics EVA7470, the molar content of vinyl acetate is 26%), the calcium carbonate of 1phr, the paraffin of 0.5phr and the DCP of 0.5phr in the ST-75L internal mixer of three Thai Machinery Company, in 100 ℃ and 0.75Mpa pressure conditions to mix for 12min. After unloading, the above-mentioned mixture is extruded and granulated (colloidal granules) with the extrusion granulator supporting the ST-75L internal mixer of Santai Machinery Company. The colloidal particles were molded and cross-linked at a mold temperature of 180° C. in an EVA injection machine of Jumin Machinery Co., Ltd. KM-E308L3.
[0048] Put the cross-linked polyolefin parison into an autoclave of Deyang Sichuang Company, inject carbon dioxide supercritical fluid, and maintain it at a temperature of 50°C and a pressure of 40Mpa for 2 hours. Then, release the pressure to normal pressure within 30 minutes to obtain a supercritical fluid-infiltrated parison (pre-expansion rat...
Embodiment 2
[0053] Except that the EVA / POE mixture (the molar content of the vinyl acetate of EVA is 26% wherein, and POE is the POE of Dow Chemical Company's 8150 model) that is 60 / 40 with blending ratio replaces EVA, adopts and embodiment 1. The same procedure is used to obtain the finished foamed product.
[0054] The specific gravity, cell diameter and resilience performance of the foamed product of the finished product are respectively 0.13, 0.5-1.5mm and 60%.
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Abstract
Description
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Application Information

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